3,3',3'',3'''-(1,3,2,4-dithiadistannetane-2,2,4,4-tetrayl)tetrakis(N,N-dimethylpropan-1-amine) | 146024-28-4

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3,3',3'',3'''-(1,3,2,4-dithiadistannetane-2,2,4,4-tetrayl)tetrakis(N,N-dimethylpropan-1-amine)
• CAS: 146024-28-4
• 化学式: C₂₀H₄₈N₄S₂Sn₂
• 分子量: 646.18
• InChiKey: MJCYLULMKVGRLX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.16
• 重原子数：
  28.0
• 可旋转键数：
  16.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12.96
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  3,3',3'',3'''-(1,3,2,4-dithiadistannetane-2,2,4,4-tetrayl)tetrakis(N,N-dimethylpropan-1-amine) 、 (t-Bu2SnS)2 以 二氯甲烷 为溶剂， 以85%的产率得到3,3'-(4,4-di-tert-butyl-1,3,2,4-dithiadistannetane-2,2-diyl)bis(N,N-dimethylpropan-1-amine)
  参考文献：
  名称：

  Ring size control in diorganotin sulphides by intramolecular SnN coordination

  摘要：

  The synthesis of intramolecularly coordinated organotin sulphides, [(Me2NCH2CH2CH2)2SnS]n (1) and [Me2NCH2CH2CH2Sn(Ph)S]n (2), is described. Compounds 1 and 2 are dimers in chloroform solution (n = 2). Compound 1 forms a centrosymmetric dimer with a planar rectangular Sn2S2 four-membered ring in its centre. The tin atoms show a distorted trans-cis-cis octahedral coordination by 2C, 2N and 2S. The tin-nitrogen distances are 2.810(3) and 3.158(5) angstrom. Compound 1 can be regarded as a model substance for nucleophilic attack at penta-coordinate tin centres. Although the degree of intramolecular coordination of nitrogen to tin is temperature dependent, the four-membered Sn2Sn2 ring remains inert in solution. The existence of the asymmetric tin compound (Me2NCH2CH2CH2)2SnS2SnBut2 (1a) has been characterized in solution.

  DOI：

  10.1016/s0277-5387(00)83631-1
• 作为产物：
  描述：

  sodiumsulfide nonahydrate 、 bis(3-(dimethylamino)propyl)dichlorostannane 以 水 、 丙酮 为溶剂， 以84%的产率得到3,3',3'',3'''-(1,3,2,4-dithiadistannetane-2,2,4,4-tetrayl)tetrakis(N,N-dimethylpropan-1-amine)
  参考文献：
  名称：

  Ring size control in diorganotin sulphides by intramolecular SnN coordination

  摘要：

  The synthesis of intramolecularly coordinated organotin sulphides, [(Me2NCH2CH2CH2)2SnS]n (1) and [Me2NCH2CH2CH2Sn(Ph)S]n (2), is described. Compounds 1 and 2 are dimers in chloroform solution (n = 2). Compound 1 forms a centrosymmetric dimer with a planar rectangular Sn2S2 four-membered ring in its centre. The tin atoms show a distorted trans-cis-cis octahedral coordination by 2C, 2N and 2S. The tin-nitrogen distances are 2.810(3) and 3.158(5) angstrom. Compound 1 can be regarded as a model substance for nucleophilic attack at penta-coordinate tin centres. Although the degree of intramolecular coordination of nitrogen to tin is temperature dependent, the four-membered Sn2Sn2 ring remains inert in solution. The existence of the asymmetric tin compound (Me2NCH2CH2CH2)2SnS2SnBut2 (1a) has been characterized in solution.

  DOI：

  10.1016/s0277-5387(00)83631-1