(E)-1-(2'-Hydroxy-5'-nonylphenyl)-1-ethanone oxime | 93913-80-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: (E)-1-(2'-Hydroxy-5'-nonylphenyl)-1-ethanone oxime
• 英文别名: 2-[(E)-N-hydroxy-C-methylcarbonimidoyl]-4-nonylphenol
• CAS: 93913-80-5
• 化学式: C₁₇H₂₇NO₂
• 分子量: 277.407
• InChiKey: JWLRQNQOJOZVOX-NBVRZTHBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.1
• 重原子数：
  20
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  52.8
• 氢给体数：
  2
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  对壬基酚 在 吡啶 、 三氯化铝 、 盐酸羟胺 作用下， 以 甲醇 、 1,2-二氯乙烷 为溶剂， 反应 13.0h， 生成 (E)-1-(2'-Hydroxy-5'-nonylphenyl)-1-ethanone oxime
  参考文献：
  名称：

  Krzyzanowska, Ewa; Olszanowski, A.; Juskowiak, M., Journal fur praktische Chemie (Leipzig 1954), 1989, vol. 331, # 4, p. 617 - 630

  摘要：

  DOI：

文献信息

• Mass spectra of 1-(2′-hydroxy-5′-alkylphenyl)-1-alkanone (E)-oximes
  作者：Marek Łozyński、Ewa Krzyzanowska

  DOI：10.1002/oms.1210210108

  日期：1986.1

  AbstractThe mass spectra of 1‐(2′‐hydroxy‐5′‐alkylphenyl)‐1‐ethanone (E)‐oximes 1–6 and 1‐(2′‐hydroxy‐5′‐methylphenyl)‐1‐alkanone (E)‐oximes 7–12 are given and the major fragmentation pathways discussed. The simultaneous loss of water and alkyl moieties from the molecular ion indicates that a skeletal rearrangement take place and a cycloheptatrienyloheterocyclic system is formed. The McLafferty rearrangement, γ‐fission in the side aliphatic chain and oxygen expulsion are discussed with evidence being drawn from accurate mass measurements, metastable ions and comparison with mass spectral data of related compounds.
• Stripping Process
  申请人：Fujifilm Electronic Materials U.S.A., Inc.

  公开号：US20180136563A1

  公开（公告）日：2018-05-17

  This disclosure relates to a process for stripping an organic film on a patterned semiconductor substrate. The process includes treating the organic film with an aqueous stripper composition to remove the organic film in one step. The organic film includes at least a first layer and a second layer, the first layer has a dissolution rate of at most about 0.01 μ/min in a developer at 25° C., and the second layer has a dissolution rate of greater than about 0.01 μ/min in the developer at 25° C.
• US8945490B2
  申请人：——

  公开号：US8945490B2

  公开（公告）日：2015-02-03
• [EN] CLEANING COMPOSITION<br/>[FR] COMPOSITION DE NETTOYAGE
  申请人：FUJIFILM ELECTRONIC MAT USA INC

  公开号：WO2017023677A1

  公开（公告）日：2017-02-09

  This disclosure relates to a composition (e.g., a cleaning and/or stripping composition) containing (a) 0.5 - 25 percent by weight an alkaline compound; (b) 1 - 25 percent by weight an alcohol amine compound; (c) 0.1 - 20 percent by weight a hydroxylammonium compound; (d) 5 - 95 percent by weight an organic solvent; (e) 0.1 - 5 percent by weight a corrosion inhibitor compound; and (f) 2 -25 percent by weight water.
• Krzyzanowska, Ewa; Olszanowski, A.; Juskowiak, M., Journal fur praktische Chemie (Leipzig 1954), 1989, vol. 331, # 4, p. 617 - 630
  作者：Krzyzanowska, Ewa、Olszanowski, A.、Juskowiak, M.

  DOI：——

  日期：——