1-<2-Dimethyl-amino-acetyl>-naphthalin | 805181-84-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-<2-Dimethyl-amino-acetyl>-naphthalin
• 英文别名: 1-(2-Dimethyl-amino-acetyl)-naphthalin；2-(Dimethylamino)-1-(1-naphthalenyl)ethanone；2-(dimethylamino)-1-naphthalen-1-ylethanone
• CAS: 805181-84-4
• 化学式: C₁₄H₁₅NO
• 分子量: 213.279
• InChiKey: KFXDMWQLCGNZMM-UHFFFAOYSA-N

物化性质

• 熔点：
  62-63 °C
• 沸点：
  350.5±25.0 °C(Predicted)
• 密度：
  1.091±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  20.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-<2-Dimethyl-amino-acetyl>-naphthalin 、 三氟甲烷磺酸甲酯 以 正己烷 、 二氯甲烷 为溶剂， 生成
  参考文献：
  名称：

  Requirements for Selective Hydrophobic Acceleration in the Reduction of Ketones

  摘要：

  Reductions of various quaternized hydrophobic beta-keto amines were performed in water and in methanol using borohydride anions carrying hydrophobic groups. The most important requirement of the substrate to permit hydrophobically accelerated selective reductions is the ability of the hydrophobic group of the substrate and its attached keto group to attain a coplanar relationship. Some derivatives of naturally occurring steroid diones have also been employed as substrates to probe the mechanism and utility of these hydrophobically accelerated selective reductions further.

  DOI：

  10.1021/ol0481481
• 作为产物：
  描述：

  二甲胺 、 2-溴-1-萘-1-乙酮 以 四氢呋喃 为溶剂， 反应 0.75h， 生成 1-<2-Dimethyl-amino-acetyl>-naphthalin
  参考文献：
  名称：

  Requirements for Selective Hydrophobic Acceleration in the Reduction of Ketones

  摘要：

  Reductions of various quaternized hydrophobic beta-keto amines were performed in water and in methanol using borohydride anions carrying hydrophobic groups. The most important requirement of the substrate to permit hydrophobically accelerated selective reductions is the ability of the hydrophobic group of the substrate and its attached keto group to attain a coplanar relationship. Some derivatives of naturally occurring steroid diones have also been employed as substrates to probe the mechanism and utility of these hydrophobically accelerated selective reductions further.

  DOI：

  10.1021/ol0481481

文献信息

• THERMOELECTRIC CONVERSION MATERIAL AND THERMOELECTRIC CONVERSION ELEMENT
  申请人：FUJI-FILM Corporation

  公开号：EP2763200A1

  公开（公告）日：2014-08-06

  A thermoelectric conversion material containing an electrically conductive polymer and a thermal excitation assist agent, wherein the thermal excitation assist agent is a compound that does not form a doping level in the electrically conductive polymer, an energy level of LUMO (lowest unoccupied molecular orbital) of the thermal excitation assist agent and an energy level of HOMO (highest occupied molecular orbital) of the electrically conductive polymer satisfy following numerical expression (I): Numerical expression (I); 0.1⁢eV≤HOMO of an electrically conductive polymer-LUMO of a thermal excitation assistant agent≤1.9eV wherein, in numerical expression (I), |HOMO of an electrically conductive polymer| represents an absolute value of an energy level of HOMO of the electrically conductive polymer, and |LUMO of a thermal excitation assist agent| represents an absolute value of an energy level of LUMO of the thermal excitation assist agent, respectively.

  一种包含导电聚合物和热激发辅助剂的热电转换材料，其中热激发辅助剂为不在导电聚合物中形成掺杂水平的化合物，热激发辅助剂的 LUMO（最低未占据分子轨道）能级和导电聚合物的 HOMO（最高占据分子轨道）能级满足以下数值表达式（I）：数值表达式（I）；0.1eV≤导电聚合物的 HOMO-热激发辅助剂的 LUMO≤1.9eV 其中，在数值表达式（I）中，|导电聚合物的 HOMO|分别表示导电聚合物 HOMO 能级的绝对值，|热激发辅助剂的 LUMO|分别表示热激发辅助剂 LUMO 能级的绝对值。
• Requirements for Selective Hydrophobic Acceleration in the Reduction of Ketones
  作者：Mark R. Biscoe、Christopher Uyeda、Ronald Breslow

  DOI：10.1021/ol0481481

  日期：2004.11.1

  Reductions of various quaternized hydrophobic beta-keto amines were performed in water and in methanol using borohydride anions carrying hydrophobic groups. The most important requirement of the substrate to permit hydrophobically accelerated selective reductions is the ability of the hydrophobic group of the substrate and its attached keto group to attain a coplanar relationship. Some derivatives of naturally occurring steroid diones have also been employed as substrates to probe the mechanism and utility of these hydrophobically accelerated selective reductions further.