2-(4-bromophenyl)-4, 6-bis(1-naphthyl)-1,3,5-triazine | 927898-23-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-(4-bromophenyl)-4, 6-bis(1-naphthyl)-1,3,5-triazine
• 英文别名: 2-(4-Bromophenyl)-4,6-bis(1-naphthyl)-1,3,5-triazine；2-(4-bromophenyl)-4,6-dinaphthalen-1-yl-1,3,5-triazine
• CAS: 927898-23-5
• 化学式: C₂₉H₁₈BrN₃
• 分子量: 488.386
• InChiKey: HJMVGLYGWVBAND-UHFFFAOYSA-N

物化性质

• 沸点：
  716.8±62.0 °C(Predicted)
• 密度：
  1.397±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  33
• 可旋转键数：
  3
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-(4-bromophenyl)-4, 6-bis(1-naphthyl)-1,3,5-triazine 、 4-溴代联苯 在 四(三苯基膦)钯 正丁基锂 、 二氯(N,N,N',N'-四甲基乙二胺)锌(II) 作用下， 以 四氢呋喃 、 正己烷 为溶剂， 反应 15.42h， 以71%的产率得到2,4-bis(1-naphthyl)-6-[1,1':4',1'']terphenyl-4-yl-1,3,5-triazine
  参考文献：
  名称：

  1,3,5-TRIAZINE DERIVATIVE, METHOD FOR PRODUCING SAME, AND ORGANIC ELECTROLUMINESCENT DEVICE CONTAINING SAME AS COMPONENT

  摘要：

  公开号：

  EP1930329B1
• 作为产物：
  描述：

  2-(4-bromophenyl)-4,6-bis(1-naphthyl)-1,3,5-oxadiazinyl-1-ium hexachloroantimonate 在 氨 作用下， 以 水 为溶剂， 反应 1.0h， 生成 2-(4-bromophenyl)-4, 6-bis(1-naphthyl)-1,3,5-triazine
  参考文献：
  名称：

  1,3,5-TRIAZINE DERIVATIVE, METHOD FOR PRODUCING SAME, AND ORGANIC ELECTROLUMINESCENT DEVICE CONTAINING SAME AS COMPONENT

  摘要：

  公开号：

  EP1930329B1

文献信息

• 1,3,5-TRIAZINE DERIVATIVE, PRODUCTION METHOD THEREOF AND ORGANIC ELECTROLUMINESCENCE DEVICE COMPRISING THIS AS A COMPOSING COMPONENT
  申请人：Yamakawa Tetsu

  公开号：US20090281311A1

  公开（公告）日：2009-11-12

  Since the conventional electron transporters have low thermal stability, the organic electroluminescent devices using them are not sufficient in terms of the compatibility of their luminance and luminous efficiency with device lifetime. A 1,3,5-triazine derivative of formula (1) is obtained by a metal catalyst-aided coupling reaction of a compound of formula (2) with a compound of formula (3), and this is used as a composing component of an organic electroluminescent device. [In the formulae, Ar 1 and Ar 2 represent phenyl group or the like, R 1 and R 2 represent hydrogen atom or the like, R 3 represents methyl or the like, m is an integer of 0 to 2, X represents 2,4-pyridylene or the like, p is 1 or 2, a and b are 1 or 2, a+b is 3, q is 0 or an integer of p or less, M represents —MgR 4 group or the like, R 4 represents chlorine atom or the like, r is p-q, and Y represents a leaving group.]

  由于传统的电子传输体具有低热稳定性，使用它们的有机电致发光器件在亮度和发光效率与器件寿命的兼容性方面不足。通过化合物（2）和化合物（3）的金属催化偶联反应获得式（1）的1,3,5-三嗪衍生物，并将其用作有机电致发光器件的组成部分。[在公式中，Ar1和Ar2代表苯基或类似基团，R1和R2代表氢原子或类似原子团，R3代表甲基或类似基团，m为0至2的整数，X代表2,4-吡啶基或类似基团，p为1或2，a和b为1或2，a+b为3，q为0或小于等于p的整数，M代表-MgR4基团或类似基团，R4代表氯原子或类似原子团，r为p-q，Y代表离去基团。]
• 1,3,5-triazine derivative, production method thereof and organic electroluminescence device comprising this as a composing component
  申请人：Tosoh Corporation

  公开号：US07994316B2

  公开（公告）日：2011-08-09

  Since the conventional electron transporters have low thermal stability, the organic electroluminescent devices using them are not sufficient in terms of the compatibility of their luminance and luminous efficiency with device lifetime. A 1,3,5-triazine derivative of formula (1) is obtained by a metal catalyst-aided coupling reaction of a compound of formula (2) with a compound of formula (3), and this is used as a composing component of an organic electroluminescent device. [In the formulae, Ar1 and Ar2 represent phenyl group or the like, R1 and R2 represent hydrogen atom or the like, R3 represents methyl or the like, m is an integer of 0 to 2, X represents 2,4-pyridylene or the like, p is 1 or 2, a and b are 1 or 2, a+b is 3, q is 0 or an integer of p or less, M represents —MgR4 group or the like, R4 represents chlorine atom or the like, r is p-q, and Y represents a leaving group.]

  由于传统的电子传输体的热稳定性较低，使用它们的有机电致发光器件在亮度和发光效率与器件寿命的兼容性方面不足。式（1）的1,3,5-三嗪衍生物是通过式（2）的化合物与式（3）的化合物的金属催化偶联反应获得的，并用作有机电致发光器件的组成部分。【在式中，Ar1和Ar2代表苯基或类似基团，R1和R2代表氢原子或类似基团，R3代表甲基或类似基团，m是0到2的整数，X代表2,4-吡啶基或类似基团，p是1或2，a和b为1或2，a+b为3，q为0或小于等于p的整数，M代表—MgR4基团或类似基团，R4代表氯原子或类似基团，r为p-q，Y代表离去基团。】
• 신규한 화합물 및 이를 이용한 유기 발광 소자
  申请人：LG CHEM, LTD. 주식회사 엘지화학(120010134563) Corp. No ▼ 110111-2207995BRN ▼107-81-98139

  公开号：KR20210125411A

  公开（公告）日：2021-10-18

  본 발명은 신규한 화합물 및 이를 이용한 유기 발광 소자를 제공한다.

  这项发明提供了一种新的化合物及其用于有机发光器件的应用。
• US7994316B2
  申请人：——

  公开号：US7994316B2

  公开（公告）日：2011-08-09
• [EN] COMPOUND FOR ORGANIC ELECTRONIC ELEMENT, ORGANIC ELECTRONIC ELEMENT USING SAME, AND ELECTRONIC DEVICE THEREOF<br/>[FR] COMPOSÉ POUR ÉLÉMENT ÉLECTRONIQUE ORGANIQUE, ÉLÉMENT ÉLECTRONIQUE ORGANIQUE L'UTILISANT ET DISPOSITIF ÉLECTRONIQUE ASSOCIÉ<br/>[KO] 유기전기 소자용 화합물, 이를 이용한 유기전기소자 및 그 전자 장치
  申请人：DUK SAN NEOLUX CO LTD

  公开号：WO2017043797A1

  公开（公告）日：2017-03-16

  화학식 1로 표시되는 화합물과, 제1전극, 제2전극 및 제1전극과 제2전극 사이의 유기물층을 포함하는 유기전기소자 및 이를 포함하는 전자장치가 개시되며, 유기물층에 화학식 1로 표시되는 화합물을 포함하므로써, 유기전기소자의 구동전압을 낮출 수 있고, 발광효율 및 수명을 향상시킬 수 있다.