2-Methoxy-1-[[3,4,5-tris(phenylmethoxy)phenyl]methoxymethyl]naphthalene | 862806-05-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2-Methoxy-1-[[3,4,5-tris(phenylmethoxy)phenyl]methoxymethyl]naphthalene
• 英文别名: 2-methoxy-1-[[3,4,5-tris(phenylmethoxy)phenyl]methoxymethyl]naphthalene
• CAS: 862806-05-1
• 化学式: C₄₀H₃₆O₅
• 分子量: 596.723
• InChiKey: RHDBVCDLFHWNHZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  45
• 可旋转键数：
  14
• 环数：
  6.0
• sp3杂化的碳原子比例：
  0.15
• 拓扑面积：
  46.2
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2-Methoxy-1-[[3,4,5-tris(phenylmethoxy)phenyl]methoxymethyl]naphthalene 以 苯 为溶剂， 以100%的产率得到
  参考文献：
  名称：

  Photochemical generation of benzene–naphthalene biplanemers

  摘要：

  A direct biplanemer synthesis could be achieved by a quantitative [4 pi+4 pi]photocycloaddition of benzyloxy substituted benzene and naphthalene rings (3d,e reversible arrow 4d,e). Since the products do not show a thermal Cope rearrangernent-in contrast to the related longicyclic conjugated 9,10-benzotricyclo[4.2. 2.2(2.5)]docleca-3,7,9-trienes- but a quantitative reverse reaction, they are interesting systems for an optical switching. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.05.092
• 作为产物：
  描述：

  以100%的产率得到2-Methoxy-1-[[3,4,5-tris(phenylmethoxy)phenyl]methoxymethyl]naphthalene
  参考文献：
  名称：

  Photochemical generation of benzene–naphthalene biplanemers

  摘要：

  A direct biplanemer synthesis could be achieved by a quantitative [4 pi+4 pi]photocycloaddition of benzyloxy substituted benzene and naphthalene rings (3d,e reversible arrow 4d,e). Since the products do not show a thermal Cope rearrangernent-in contrast to the related longicyclic conjugated 9,10-benzotricyclo[4.2. 2.2(2.5)]docleca-3,7,9-trienes- but a quantitative reverse reaction, they are interesting systems for an optical switching. (c) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.05.092

文献信息

• Photochemical generation of benzene–naphthalene biplanemers
  作者：Derong Cao、Herbert Meier

  DOI：10.1016/j.tetlet.2005.05.092

  日期：2005.7

  A direct biplanemer synthesis could be achieved by a quantitative [4 pi+4 pi]photocycloaddition of benzyloxy substituted benzene and naphthalene rings (3d,e reversible arrow 4d,e). Since the products do not show a thermal Cope rearrangernent-in contrast to the related longicyclic conjugated 9,10-benzotricyclo[4.2. 2.2(2.5)]docleca-3,7,9-trienes- but a quantitative reverse reaction, they are interesting systems for an optical switching. (c) 2005 Elsevier Ltd. All rights reserved.