1,2-bis(3-(phenanthren-9-yl)phenyl)ethane | 1437383-67-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1,2-bis(3-(phenanthren-9-yl)phenyl)ethane
• 英文别名: 9-[3-[2-(3-Phenanthren-9-ylphenyl)ethyl]phenyl]phenanthrene
• CAS: 1437383-67-9
• 化学式: C₄₂H₃₀
• 分子量: 534.7
• InChiKey: GCLJCNXBEVGSDE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  12.4
• 重原子数：
  42
• 可旋转键数：
  5
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  3-溴苄溴 在 bis(triphenylphosphine)nickel(II) chloride 、 Ni(PPh₃)₂(1-naphthyl)Cl 、 potassium carbonate 、 三苯基膦 、 锌 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 36.0h， 生成 1,2-bis(3-(phenanthren-9-yl)phenyl)ethane
  参考文献：
  名称：

  Straightforward synthesis of substituted dibenzyl derivatives

  摘要：

  The C-C bond formation by homogeneous catalysis is a powerful tool in organic synthesis. The replacement of noble metal by cheaper one for already reported methodologies is of interest for an economical purpose. The attractivity of such replacement is also enhanced if a first raw transition metal is found to be active in several processes.This work demonstrates that a common nickel complex can be used for a two-step cross-coupling procedure, namely a homocoupling reaction of benzyl derivatives and a subsequent Suzuki reaction. These consecutive reactions permit the synthesis of new polyfunctionalized dibenzyl compounds. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.04.073