2,7-Dioxa-19,24-diazapentacyclo[24.8.0.08,17.011,16.027,32]tetratriaconta-1(26),8(17),9,11,13,15,27,29,31,33-decaene | 1314773-97-1

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2,7-Dioxa-19,24-diazapentacyclo[24.8.0.08,17.011,16.027,32]tetratriaconta-1(26),8(17),9,11,13,15,27,29,31,33-decaene
• CAS: 1314773-97-1
• 化学式: C₃₀H₃₄N₂O₂
• 分子量: 454.612
• InChiKey: ZYSSCCKXQDHELG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6
• 重原子数：
  34
• 可旋转键数：
  0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  42.5
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-[4-(2-formylnaphthoxy)butoxy]naphthaldehyde 在 sodium tetrahydroborate 、 乙醇 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 5.0h， 生成 2,7-Dioxa-19,24-diazapentacyclo[24.8.0.08,17.011,16.027,32]tetratriaconta-1(26),8(17),9,11,13,15,27,29,31,33-decaene
  参考文献：
  名称：

  Efficient synthesis of naphthodiazacrown ethers

  摘要：

  A benign and efficient synthesis of naphthodiazacrown ethers has been described. Reaction of simple dialdehyde precursor with alpha,omega-diamines followed by sodium borohydride reduction leads to 16-27 membered naphthodiazacrown ethers in 80-90% yields. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.05.057

文献信息

• Preparation of a new fluorescence nanochemosensor for Sn(II) ions by a modified nanoprecipitation method
  作者：Reza Azadbakht、Mohammad Hakimi、Javad Khanabadi

  DOI：10.1016/j.saa.2020.119236

  日期：2021.4

  A new dialdehyde was designed and synthesized containing naphthalene groups, and then its macrocycle was prepared with 1,4-diaminobuthan. A modified nanoprecipitation method has been reported for the preparation of the nanoparticles. In this method, to obtain nanoparticles with small particle sizes, the nucleation rate was increased with decreasing of the mixing time. The organic nanoparticles were

  设计并合成了一个新的含萘基的二醛，然后用1，4-二氨基丁烷制备了其大环。已经报道了用于制备纳米颗粒的改进的纳米沉淀方法。在该方法中，为了获得小粒径的纳米颗粒，成核速率随着混合时间的减少而增加。有机纳米粒子用于关闭低浓度的Sn 2+离子对Cs +，K +，Na +，Ba 2 +，Ca 2 +，Mg 2 +，Al 3+，Pb 2等阳离子的荧光响应。+， Zn 2 +，Cu 2 +，Ni缓冲水溶液中的2 +，Co 2 +，Fe 2 +，Mn 2 +，Ag +，Cd 2+和Hg 2+和离子。检测限为5.4 nM。
• Efficient synthesis of naphthodiazacrown ethers
  作者：Pallavi Singh、Rajiv K. Verma、Maya Shankar Singh

  DOI：10.1016/j.tetlet.2011.05.057

  日期：2011.7

  A benign and efficient synthesis of naphthodiazacrown ethers has been described. Reaction of simple dialdehyde precursor with alpha,omega-diamines followed by sodium borohydride reduction leads to 16-27 membered naphthodiazacrown ethers in 80-90% yields. (C) 2011 Elsevier Ltd. All rights reserved.