5-bromosalicylaldehyde 6-methyl-4-hydroxypyrimidinyl hydrazone | 220164-57-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 5-bromosalicylaldehyde 6-methyl-4-hydroxypyrimidinyl hydrazone
• 英文别名: 2-[2-[(5-bromo-2-hydroxyphenyl)methylidene]hydrazinyl]-4-methyl-1H-pyrimidin-6-one
• CAS: 220164-57-8
• 化学式: C₁₂H₁₁BrN₄O₂
• 分子量: 323.149
• InChiKey: FUEYAMPVHZVECP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  19
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  86.1
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  5-bromosalicylaldehyde 6-methyl-4-hydroxypyrimidinyl hydrazone 、 五氯化铌 以 氯仿 为溶剂， 以55%的产率得到
  参考文献：
  名称：

  SYNTHESIS AND CHARACTERIZATION OF NIOBIUM(V) COMPLEXES WITH 6-METHYL-4-HYDROXYPYRIMIDINYL HYDRAZONES

  摘要：

  Niobium(V) complexes with 6-methyl-4-hydroxypyrimidinyl hydrazones have been synthesised and characterised by elemental analyses, conductivity measurements, spectral (IR, UV-Vis,H-1 NMR) and TG studies. The complexes have the composition [NbCl3L]. The ligand behaves as dibasic tridentate ONN donor.

  DOI：

  10.1081/sim-100002051

文献信息

• Synthesis and photoluminescence properties of zinc(II) complexes with salicylaldehyde hetarylhydrazones
  作者：S. A. Melkozerov、I. G. Pervova、G. N. Lipunova、V. A. Barachevskii、I. N. Lipunov、E. A. Dvoskin

  DOI：10.1134/s1070363213040063

  日期：2013.4

  New zinc complexes of the salicylaldehyde benzazolyl- and pyrimidinylhydrazones were synthesized. Study of photophysical properties of the hydrazones and their complexes in solution showed that their structure and the luminescence intensities depend on the nature of the heterocyclic fragment included to the molecule.
• SYNTHESIS AND CHARACTERIZATION OF NIOBIUM(V) COMPLEXES WITH 6-METHYL-4-HYDROXYPYRIMIDINYL HYDRAZONES
  作者：H. S. Chabanur、V. K. Revankar、V. B. Mahale

  DOI：10.1081/sim-100002051

  日期：2001.2.28

  Niobium(V) complexes with 6-methyl-4-hydroxypyrimidinyl hydrazones have been synthesised and characterised by elemental analyses, conductivity measurements, spectral (IR, UV-Vis,H-1 NMR) and TG studies. The complexes have the composition [NbCl3L]. The ligand behaves as dibasic tridentate ONN donor.