2-{(E)-[(2E)-(phenylmethylidene)hydrazono]methyl}phenol | 41097-41-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-{(E)-[(2E)-(phenylmethylidene)hydrazono]methyl}phenol
• 英文别名: 2-((E)-((E)-benzylidenehydrazono)methyl)phenol；2-{(E)-[(2E)-benzylidenehydrazinylidene]methyl}phenol；2-[(E)-[(E)-benzylidenehydrazinylidene]methyl]phenol
• CAS: 41097-41-0
• 化学式: C₁₄H₁₂N₂O
• 分子量: 224.262
• InChiKey: GUVKXRKDJAEWRO-RWPWKDLBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  45
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  4-硝基邻苯二甲腈 、 2-{(E)-[(2E)-(phenylmethylidene)hydrazono]methyl}phenol 在 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 120.0h， 以69%的产率得到4-(2-{(E)-[(2E)-(phenylmethylidene)hydrazono]methyl}phenoxy)phthalonitrile
  参考文献：
  名称：

  Synthesis, characterization and electrical properties of peripherally tetra-aldazine substituted novel metal free phthalocyanine and its zinc(II) and nickel(II) complexes

  摘要：

  The novel phthalonitrile containing azine segment and its corresponding tetra aldazine substituted metal free- and metallo-phthalocyanines (Zn(II) and Ni(II)) were synthesized and characterized by IR, (1)H NMR, Mass, UV-Vis spectroscopy and elemental analysis and addition to these techniques for substituted phthalonitrile (13)C NMR have been used. In addition, dc and ac electrical properties of the films of these novel phthalocyanines were investigated as a function of temperature (295-523 K) and frequency (40-10(5)Hz). Activation energy values of the films of the phthalocyanines were calculated from straight portions of the Arrhenius plot (lnσ(dc)-1/T curves) as 0.70 eV, 0.93 eV and 0.91 eV for the films of metal free, nickel- and zinc-phthalocyanines, respectively. From impedance spectroscopy measurements, it is observed that bulk resistance decreases with increasing temperature indicating semiconductor property.

  DOI：

  10.1016/j.saa.2012.12.058

文献信息

• Non-toxic corrosion-protection pigments based on rare earth elements
  申请人：——

  公开号：US20040104377A1

  公开（公告）日：2004-06-03

  A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.

  一种缓蚀颜料，由稀土元素和价态稳定剂结合形成稀土/价态稳定剂复合物。稀土元素选自铈、铽、镨或它们的组合，至少有一种稀土元素处于四价氧化态。使用无机或有机材料来稳定四价稀土离子，以形成稀溶于水的化合物。选择特定的稳定剂是为了控制四价铈、铽或镨在遇水时的释放率，并调整粉末在所选粘合剂体系中用作颜料时的相容性。稳定剂还可以改变成型粉末的加工和处理特性。本文介绍了许多稀土-价稳定剂组合，其性能可与传统的六价铬体系媲美。
• FLAVOR COMPOSITIONS AND PET FOOD PRODUCTS CONTAINING THE SAME
  申请人：Mars, Incorporated

  公开号：EP3229610B1

  公开（公告）日：2021-06-09
• NON-TOXIC CORROSION-PROTECTION PIGMENTS BASED ON COBALT
  申请人：Sturgill Jeffrey Allen

  公开号：US20090163628A1

  公开（公告）日：2009-06-25

  Corrosion-inhibiting pigments based on cobalt are described that contain a trivalent or tetravalent cobalt/valence stabilizer complex. An inorganic or organic material is used to stabilize the trivalent or tetravalent cobalt ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of trivalent or tetravalent cobalt during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Cobalt/valence stabilizer combinations are chosen based on the well-founded principles of cobalt coordination chemistry. Many cobalt-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.
• US7291217B2
  申请人：——

  公开号：US7291217B2

  公开（公告）日：2007-11-06
• US7833331B2
  申请人：——

  公开号：US7833331B2

  公开（公告）日：2010-11-16