bicyclohexyl-4,4'-diyldiamine | 6492-07-5

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: bicyclohexyl-4,4'-diyldiamine
• 英文别名: Bicyclohexyl-4,4'-diyldiamin；4.4'-Diamino-bicyclohexyl；Bis-<4-amino-cyclohexyl>；4,4'-Diaminobi(cyclohexyl)；4,4'-Dicyclohexyldiamin；[1,1'-Bicyclohexyl]-4,4'-diamine；4-(4-aminocyclohexyl)cyclohexan-1-amine
• CAS: 6492-07-5；37942-64-6
• 化学式: C₁₂H₂₄N₂
• 分子量: 196.336
• InChiKey: CSIVUWBDBJMXDY-UHFFFAOYSA-N

物化性质

• 沸点：
  312.9±10.0 °C(Predicted)
• 密度：
  0.973±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  bicyclohexyl-4,4'-diyldiamine 、 碘甲烷 在 丙酮 、 silver(l) oxide 作用下， 生成 hexa-N-methyl-N,N'-bicyclohexyl-4,4'-diyl-di-ammonium; diiodide
  参考文献：
  名称：

  US2697728

  摘要：

  公开号：
• 作为产物：
  描述：

  联苯胺 在 1,4-二氧六环 、 钌 作用下， 115.0~125.0 ℃ 、14.71 MPa 条件下， 生成 bicyclohexyl-4,4'-diyldiamine
  参考文献：
  名称：

  Polyamides and method for obtaining same

  摘要：

  将至少有4个碳原子在羧基之间的二羧酸与具有一般公式<;FORM:0619707/IV(a)/1>;的二环二胺加热，其中X为零或1到6的整数，R1、R2、R3、R4为氢原子或甲基基团，直到所得的聚酰胺的固有粘度至少为0.4。这两种成分中的任一种或两种都可以被相应的聚酰胺形成衍生物取代，或者通过混合相应成分的乙醇溶液制备的盐可以使用。由这种聚酰胺制成的丝具有高弹性，可以通过从弯曲中恢复时恢复的功率来测量，或者从拉伸中恢复。当二胺为一般公式的立体异构体混合物且在25摄氏度时为液体时，所得产品在大量形式下是清澈透明的，并且可以溶解在氯仿/甲醇混合物中。二环胺包括双-(对氨基环己基)；双-(对氨基环己基)甲烷；2:21-二甲基-4:41-二氨基二环己基甲烷；2:2-二-(对-氨基环己基)丙烷；1:2-二-(对-氨基环己基)乙烷；1:6-二-(对-氨基环己基)己烷；1:6-二-(2-甲基-4-氨基环己基)1:1:2:2:3:3:4:4:5:5:6:6-十二甲基己烷及其立体异构体的混合物；二羧酸包括己二酸；琥珀酸；癸二酸；癸二酸；4:41-联苯二羧酸。在示例中：(1)双-(对氨基环己基)甲烷和癸二酸的盐在氮气下在大气压下加热，然后在2毫米压力下加热；(2)和(3)相同的盐在不同条件下加热；(4)双-(对氨基环己基)和癸二酸的盐；(5)1:2-(对-氨基环己基)乙烷和癸二酸的盐；(6)双-(对氨基环己基)甲烷和己二酸的盐被加热以产生聚酰胺。二环二胺可以通过氢化适当的二芳基二胺的液体有机溶剂溶液制备，如规格书619,706中所述。还参考规格书461,237。

  公开号：

  US02512606A1

文献信息

• PROCESS FOR PREPARING SUBSTITUTED PYRIDONE COMPOUNDS
  申请人：Xerox Corporation

  公开号：US20040006234A1

  公开（公告）日：2004-01-08

  Disclosed is a process for preparing substituted pyridone compounds which comprises (a) admixing in the absence of a solvent (1) an amine of the formula R 1 —NH 2 wherein R 1 is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group, and (2) a first ester of the formula 1 wherein R 2 is an electron withdrawing group and R 3 is an alkyl group; (b) heating the mixture containing the amine and the first ester to form an intermediate compound of the formula 2 (c) admixing the intermediate compound with (1) a base and (2) a second ester of the formula 3 wherein R 4 is an alkyl group, an aryl group, an arylalkyl group, or an alkylaryl group and R 5 is an alkyl group, said second ester being present in a molar excess relative to the intermediate compound, said base being present in a molar excess relative to the intermediate compound, and (d) heating the mixture containing the intermediate compound, the second ester, and the base to form a pyridone compound of the formula 4 or a salt thereof. Also disclosed is a process for preparing diazopyridone colorants which comprises preparing a pyridone compound by the above process and reacting the pyridone compound with a diazonium salt to form a diazopyridone compound.

  揭示了一种制备取代吡啶酮化合物的过程，包括(a)在无溶剂的情况下混合（1）具有R1—NH2式的胺，其中R1是烷基、芳基、芳基烷基或烷基芳基，以及（2）具有R2为电子吸引基团和R3为烷基的第一酯的混合；（b）加热含有胺和第一酯的混合物以形成具有式2的中间化合物；（c）将中间化合物与（1）碱和（2）具有R4为烷基、芳基、芳基烷基或烷基芳基以及R5为烷基的第二酯混合，其中所述第二酯相对于中间化合物存在摩尔过量，所述碱相对于中间化合物存在摩尔过量，并且（d）加热含有中间化合物、第二酯和碱的混合物以形成具有式4的吡啶酮化合物或其盐。还揭示了一种制备重氮吡啶酮染料的过程，包括通过上述过程制备吡啶酮化合物，并将吡啶酮化合物与重氮盐反应以形成重氮吡啶酮化合物。
• [EN] IRIDIUM COMPLEX AND ORGANIC LIGHT-EMITTING DEVICE INCLUDING THE SAME<br/>[FR] COMPLEXE D'IRIDIUM ET DISPOSITIF PHOTOÉMETTEUR ORGANIQUE L'INCLUANT
  申请人：CANON KK

  公开号：WO2014115528A1

  公开（公告）日：2014-07-31

  The present invention provides a novel iridium complex and an organic light-emitting device including the novel iridium complex. The novel iridium complex includes three ligands, and two of them have a phenyl-naphtho[2,1-f]isoquinoline skeleton. The present invention also provides a display apparatus including the organic light-emitting device and an electrophotographic image-forming apparatus including a light source including the organic light-emitting device and including a photosensitive member.

  本发明提供了一种新型铱配合物和包括该新型铱配合物的有机发光器件。该新型铱配合物包括三个配体，其中两个具有苯基-萘并[2,1-f]异喹啉骨架。本发明还提供了包括该有机发光器件的显示装置，以及包括包括该有机发光器件的光源和包括感光成员的静电成像形成装置。
• 지방족 고리식 디아민 화합물의 개선된 합성 방법
  申请人：Kyung-In Synthetic Corporation (주)경인양행(119981070884) Corp. No ▼ 120111-0005703BRN ▼137-81-00562

  公开号：KR20180103613A

  公开（公告）日：2018-09-19

  본 발명은 지방족 고리식 디아민 화합물의 합성방법에 대한 것으로서, 방향족 부산물 생성을 억제하면서 바이사이클로헥산 디아민류를 보다 높은 수율로 제조할 수 있는 방법을 제공한다.

  本发明涉及一种合成环状二胺化合物的方法，提供了一种可以在抑制芳香族副产物的同时更高产率地制备双环己烷二胺的方法。
• [EN] PHOSPHINYL AMIDINE COMPOUNDS, METAL COMPLEXES, CATALYST SYSTEMS, AND THEIR USE TO OLIGOMERIZE OR POLYMERIZE OLEFINS<br/>[FR] COMPOSÉS DE PHOSPHINYLAMIDINE, COMPLEXES DE MÉTAL, SYSTÈMES DE CATALYSEUR, ET LEUR UTILISATION POUR OLIGOMÉRISER OU POLYMÉRISER DES OLÉFINES
  申请人：CHEVRON PHILLIPS CHEMICAL CO

  公开号：WO2011082192A1

  公开（公告）日：2011-07-07

  N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, N2-phosphinyl amidinate metal salt complexes are described. Methods for making N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes are also disclosed. Catalyst systems utilizing the N2-phosphinyl amidine metal salt complexes and N2-phosphinyl amidinate metal salt complexes are also disclosed along with the use of the N2-phosphinyl amidine compounds, N2-phosphinyl amidinates, N2-phosphinyl amidine metal salt complexes, and N2-phosphinyl amidinate metal salt complexes for the oligomerization and/or polymerization of olefins.

  描述了N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物、N2-膦胺酸盐金属盐络合物。还公开了制备N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的方法。还公开了利用N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物的催化剂系统，以及利用N2-膦胺化合物、N2-膦胺酸盐、N2-膦胺金属盐络合物和N2-膦胺酸盐金属盐络合物进行烯烃的寡聚和/或聚合的用途。
• Polyamides and method for obtaining same
  申请人：DU PONT

  公开号：US02512606A1

  公开（公告）日：1950-06-27

  A dicarboxylic acid having at least 4 carbon atoms between the carboxyl groups, is heated with a dialicyclic diamine having the general formula <;FORM:0619707/IV(a)/1>; where X is zero or an integer from 1 to 6 and R1, R2, R3, R4 are hydrogen atoms or methyl radicals, until the resultant polyamide has an intrinsic viscosity of at least 0.4. Either or both ingredients may be replaced by the corresponding polyamide-forming derivative or the salt-prepared as by mixing ethanol solutions of the corresponding ingredients-may be used. Filaments made from such polyamides have a high resilience, which may be measured by the work recovered when a filament recovers from bending-flexor value-or from stretching. The products obtained when the diamine is a mixture of stereoisomers of the general formula and is liquid at 25 DEG C., are clear and transparent in massive form and soluble in chloroform/methanol mixture. Dialicyclic amines include bi-(p-aminocyclohexyl); di-(p-aminocyclohexyl) methane; 2 : 21-dimethyl-4 : 41-diaminodicyclohexylmethane; 2 : 2 - di - (p - aminocyclohexyl) propane; 1 : 2 - di - (p - aminocyclohexyl) ethane; 1 : 6 - di - (p - aminocyclohexyl) hexane; 1 : 6 - di - (2-methyl-4-aminocyclohexyl) 1 : 1 : 2 : 2 : 3 : 3 : 4 : 4 : 5 : 5 : 6 : 6-dodecamethylhexane and mixtures of stereoisomers thereof; dicarboxylic acids include adipic; suberic; azelaic; sebacic; 4 : 41-biphenylenedicarboxylic acids. In examples: (1) the salt of di-(p-aminocyclohexyl) methane and sebacic acid was heated at atmospheric pressure under nitrogen and then at 2 mm. pressure; (2) and (3) the same salt was heated under different conditions; (4) the salt of bi-(p-aminocyclohexyl) and sebacic acid; (5) the salt of 1 : 2-(p-aminocyclohexyl) ethane and sebacic acid; and (6) the salt of di-(p-aminocyclohexyl) methane and adipic acid was heated to produce a polyamide. The dialicyclic diamines may be prepared by hydrogenating a liquid organic solvent solution of the appropriate diaryl diamines as in Specification 619,706. Specification 461,237 also is referred to.

  将至少有4个碳原子在羧基之间的二羧酸与具有一般公式<;FORM:0619707/IV(a)/1>;的二环二胺加热，其中X为零或1到6的整数，R1、R2、R3、R4为氢原子或甲基基团，直到所得的聚酰胺的固有粘度至少为0.4。这两种成分中的任一种或两种都可以被相应的聚酰胺形成衍生物取代，或者通过混合相应成分的乙醇溶液制备的盐可以使用。由这种聚酰胺制成的丝具有高弹性，可以通过从弯曲中恢复时恢复的功率来测量，或者从拉伸中恢复。当二胺为一般公式的立体异构体混合物且在25摄氏度时为液体时，所得产品在大量形式下是清澈透明的，并且可以溶解在氯仿/甲醇混合物中。二环胺包括双-(对氨基环己基)；双-(对氨基环己基)甲烷；2:21-二甲基-4:41-二氨基二环己基甲烷；2:2-二-(对-氨基环己基)丙烷；1:2-二-(对-氨基环己基)乙烷；1:6-二-(对-氨基环己基)己烷；1:6-二-(2-甲基-4-氨基环己基)1:1:2:2:3:3:4:4:5:5:6:6-十二甲基己烷及其立体异构体的混合物；二羧酸包括己二酸；琥珀酸；癸二酸；癸二酸；4:41-联苯二羧酸。在示例中：(1)双-(对氨基环己基)甲烷和癸二酸的盐在氮气下在大气压下加热，然后在2毫米压力下加热；(2)和(3)相同的盐在不同条件下加热；(4)双-(对氨基环己基)和癸二酸的盐；(5)1:2-(对-氨基环己基)乙烷和癸二酸的盐；(6)双-(对氨基环己基)甲烷和己二酸的盐被加热以产生聚酰胺。二环二胺可以通过氢化适当的二芳基二胺的液体有机溶剂溶液制备，如规格书619,706中所述。还参考规格书461,237。