2,4,6-trichlorodibenzothiophene

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并噻吩类
• 英文名称: 2,4,6-trichlorodibenzothiophene
• 英文别名: 2,4,6-Trichloro-dibenzothiophene
• 化学式: C₁₂H₅Cl₃S
• 分子量: 287.597
• InChiKey: AUGAFQWPVQOZLG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.2
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  28.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2,6-二氯苯硫酚 以 环己烷 、 乙酸乙酯 为溶剂， 反应 7.0h， 生成 2,4,6-trichlorodibenzothiophene
  参考文献：
  名称：

  Synthesis of Cl2- to Cl4-diphenylsulfides and Cl1- to Cl3-dibenzothiophenes

  摘要：

  The synthesis of eleven environmentally relevant mono-, di- and trichlorodibenzothiophenes (2) by photochemical ring-closure of polychlorodiphenylsulfides (1) is described. Ail monochlorodibenzothiophenes were additionally synthesized starting with a chlorothiophenol in a three-step reaction adapted from the synthesis of methyldibenzothiophenes. (C) 1999 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0045-6535(98)00582-7

文献信息

• Synthesis of Cl2- to Cl4-diphenylsulfides and Cl1- to Cl3-dibenzothiophenes
  作者：Klaus Sielex、Jan T. Andersson

  DOI：10.1016/s0045-6535(98)00582-7

  日期：1999.6

  The synthesis of eleven environmentally relevant mono-, di- and trichlorodibenzothiophenes (2) by photochemical ring-closure of polychlorodiphenylsulfides (1) is described. Ail monochlorodibenzothiophenes were additionally synthesized starting with a chlorothiophenol in a three-step reaction adapted from the synthesis of methyldibenzothiophenes. (C) 1999 Elsevier Science Ltd All rights reserved.