1,4,7-trimethyl-1,4,7-triazacyclodecane | 133256-58-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,4,7-trimethyl-1,4,7-triazacyclodecane
• 英文别名: 1,4,7-Trimethyl-1,4,7-triazecane
• CAS: 133256-58-3
• 化学式: C₁₀H₂₃N₃
• 分子量: 185.313
• InChiKey: DEKIYHATMYCZIN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0
• 重原子数：
  13
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1,4,7-trimethyl-1,4,7-triazacyclodecane 以 二氯甲烷 、 乙腈 为溶剂， 生成 [(1,4,7-trimethyl-1,4,7-triazacyclodecane)2Cu2(μ-O)2](ClO4)2
  参考文献：
  名称：

  配体大环结构对铜-二氧反应性的影响。

  摘要：

  为了了解三齿大环支撑配体的性质如何影响异构的mu-eta 2：eta 2-过氧-和双（mu-oxo）二铜配合物的相对稳定性，进行了对O2反应性的比较研究。由10和12元大环，1,4,7-R3-1、4,7-三氮杂环癸烷（R3TACD; R = Me，Bn，iPr）和1,5,9-三异丙基支撑的Cu（I）化合物-1,5,9-三氮杂环十二烷（iPr3TACDD）。尽管三坐标配合物[（iPr3TACDD）Cu] SbF6与O2不反应，但[-（R3TACD）Cu（CH3CN）] X（R = Me或Bn； X = ClO4-或SbF6-）在-80摄氏度下氧化紫外-可见光谱和共振拉曼光谱表明，生成了双（mu-oxo）物质[（R3TACD）2Cu2（mu O）2] X2。有趣的是，与先前报道的1,4,7-三异丙基-1,4,7-三氮杂环壬烷（iPr3TACN）支持的系统不同，产生过氧化合物和双（mu-oxo）化合物的互变混合物（Cahoy，J

  DOI：

  10.1021/ic000248p
• 作为产物：
  描述：

  碘甲烷 、 1,4,7-三氮杂环癸烷 在 正丁基锂 作用下， 生成 1,4,7-trimethyl-1,4,7-triazacyclodecane
  参考文献：
  名称：

  Geraldes, Carlos F. G. C.; Sherry, A. Dean; Marques, M. Paula M., Journal of the Chemical Society. Perkin transactions II, 1991, # 1, p. 137 - 146

  摘要：

  DOI：

文献信息

• PROCESS FOR PRODUCING ORGANOLITHIUM COMPOUND AND PROCESS FOR PRODUCING SUBSTITUTED AROMATIC COMPOUND
  申请人：Inoue Hiroki

  公开号：US20110224457A1

  公开（公告）日：2011-09-15

  A method for producing an organolithium compound includes the step of reacting an aromatic compound or a halogenated unsaturated aliphatic compound and a lithiating agent in the presence of a coordinating compound containing three or more elements having a coordinating ability in a molecule, at least one thereof being a nitrogen element, or a coordinating compound containing three or more oxygen elements having a coordinating ability in a molecule, at least one of the groups containing the oxygen elements having a coordinating ability being a tertiary alkoxy group, at a temperature of −40° C. to 40° C.

  生产有机锂化合物的方法包括以下步骤：在含有一个或多个具有分子中配位能力的三个或更多元素的协调化合物的存在下，将芳香化合物或卤代不饱和脂肪化合物和锂试剂反应，其中至少一个元素是氮元素；或者在含有一个或多个具有分子中配位能力的三个或更多氧元素的协调化合物的存在下，其中至少一个含有配位能力的氧元素的基团是三级烷氧基团，反应温度为-40°C至40°C。
• PROCESS FOR PRODUCTION OF POLYMERS WITH IRON COMPLEX CATALYST
  申请人：Kai Hidetomo

  公开号：US20110105703A1

  公开（公告）日：2011-05-05

  The invention relates to a novel iron complex bearing a cyclic amine as ligand; and a process for the production of polymers by polymerizing a radical-polymerizable monomer in the presence of the iron complex and a radical generator. The invention aims at providing a process by which a polymer having a chemically convertible functional group at the end can be produced from a radical-polymerizable monomer and which permits the production of a block copolymer and a process for recovering, after polymerization, an iron complex into a solvent at a high recovery ratio. The aim can be solved by providing a novel iron complex, a process for producing a polymer in the presence of a radical polymerization initiator by using the iron complex as the polymerization catalyst, a process for the production of a block copolymer which is subsequent to the polymerization for producing the above polymer, and a process for recovering the iron complex easily and simply. The invention provides an iron complex useful in producing a polymer by polymerizing a radical-polymerizable monomer; and a process for the production of polymers with the iron catalyst.

  该发明涉及一种具有环胺作为配体的新型铁配合物；以及通过在铁配合物和自由基发生剂的存在下聚合自由基可聚合单体来生产聚合物的方法。该发明旨在提供一种通过在自由基可聚合单体中生产具有化学可转化官能团末端的聚合物的方法，并且允许生产嵌段共聚物以及在聚合后将铁配合物以高回收率回收到溶剂中的方法。该目的可以通过提供一种新型铁配合物、在自由基聚合引发剂的存在下使用铁配合物作为聚合催化剂生产聚合物的方法、在上述聚合物生产后用于生产嵌段共聚物的方法以及轻松简便地回收铁配合物的方法来实现。该发明提供了一种有用的铁配合物，用于通过聚合自由基可聚合单体来生产聚合物；以及使用铁催化剂生产聚合物的方法。
• Compositions for accelerated tooth-whitening
  申请人：Cameron B. Ryan

  公开号：US20050249679A1

  公开（公告）日：2005-11-10

  Dual-component tooth-whitening systems are disclosed comprising a peroxygen whitening agent in the first component and a transition metal catalyst along with an alkaline compound in the second component. Also disclosed are tooth-whitening methods based upon the systems.

  本发明公开了双组分牙齿美白系统，第一组分包含一种过氧化物美白剂，第二组分则包含一种过渡金属催化剂和一种碱性化合物。同时也公开了基于该系统的牙齿美白方法。
• Process for preparing manganese complexes
  申请人：UNILEVER PLC

  公开号：EP0522817A1

  公开（公告）日：1993-01-13

  A process for preparing a dinuclear manganese complex of formula (A) wherein:- Mn represents manganese in the III or IV oxidation state, each X is independently a co-ordinating or bridging species selected from H₂O, O₂⁻, O²⁻, OH⁻, SH⁻, S²⁻, 〉S=O, Cl⁻, N₃⁻, SCN⁻, N³⁻, RCOO⁻, NH₂⁻ and NR₃ where R is hydrogen, alkyl or aryl (optionally substituted); L is a ligand which is an organic molecule containing at least three nitrogen atoms which coordinate to a manganese centre; Z represents the charge of the complex and is an integer which may be positive or negative; Y is a monovalent or multivalent counter-ion leading to charge neutrality, which is dependent upon the charge Z of the complex; and q = z/[charge Y], the process comprising the steps of:- (i) reacting an Mn(II) salt with at least an equivalent amount of a compound comprising the ligand L to form said manganese complex characterised in that the reaction is carried out in a non-aqueous solvent; and (ii) optionally, oxidising the manganese complex formed in step (i) with an oxidising agent.

  一种制备式（A）二核锰络合物的工艺 其中 Mn 代表处于 III 或 IV 氧化态的锰，每个 X 都是独立的配位或桥接物种，选自 H₂O 选自 H₂O、O₂-、O²-、OH-、SH-、S²-、〉S=O、 Cl-、N₃-、SCN-、N³-、RCOO-、NH₂- 和 NR₃，其中 R 是氢、烷基或芳基（任选取代）； L 是配体，是至少含有三个氮原子的有机分子，与锰中心配位； Z 代表络合物的电荷，是一个可正可负的整数； Y 是导致电荷中性的一价或多价反离子，取决于络合物的电荷 Z；以及 q = z/[电荷 Y]，该过程包括以下步骤 (i) 将锰（II）盐与至少等量的包含配体 L 的化合物反应，形成所述锰络合物，其特征在于该反应在非水溶剂中进行；以及 (ii) 可选地，用氧化剂氧化步骤(i)中形成的锰络合物。
• Detergent bleach compositions
  申请人：UNILEVER PLC

  公开号：EP0544490A1

  公开（公告）日：1993-06-02

  Detergent bleach compositions are disclosed comprising a surface active material, a peroxide bleaching agent and a dinuclear manganese complex as the bleach catalyst, characterised in that the composition comprises from 0-25% by weight of anionic surfactant and from 7.5-55% by weight of nonionic surfactant, the weight ratio of nonionic surfactant to anionic surfactant being at least 0.75 if the composition contains not more than 7.5% by weight of a carbonate, expressed as sodium carbonate, and at least 2.2. if the composition contains more than 7.5% by weight of a carbonate.

  本发明公开了由表面活性材料、过氧化物漂白剂和作为漂白催化剂的二核锰络合物组成的洗涤剂漂白组合物，其特征在于该组合物包括 0-25% （重量）的阴离子表面活性剂和 7.5-55%(重量)的非离子表面活性剂，如果组合物中碳酸盐(以碳酸钠表示)的含量不超过 7.5%(重量)，则非离子表面活性剂与阴离子表面活性剂的重量比至少为 0.75，如果组合物中碳酸盐的含量超过 7.5%(重量)，则非离子表面活性剂与阴离子表面活性剂的重量比至少为 2.2。