biphenyl-2-ylbiphenyl-4-yl-(9,9-dimethyl-9H-fluoren-2-yl)amine

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: biphenyl-2-ylbiphenyl-4-yl-(9,9-dimethyl-9H-fluoren-2-yl)amine
• 英文别名: 9,9-dimethyl-N-(2-phenylphenyl)-N-(4-phenylphenyl)fluoren-2-amine
• 化学式: C₃₉H₃₁N
• 分子量: 513.682
• InChiKey: VSZOYZWTMMLPOA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.9
• 重原子数：
  40
• 可旋转键数：
  5
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  N-[1,1’-联苯]-2-基-9,9-二甲基-9H-芴-2-胺 、 4-氯联苯 在 2-双环己基膦-2',6'-二甲氧基联苯 、 tris-(dibenzylideneacetone)dipalladium(0) 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 反应 12.0h， 以68%的产率得到biphenyl-2-ylbiphenyl-4-yl-(9,9-dimethyl-9H-fluoren-2-yl)amine
  参考文献：
  名称：

  ORGANIC COMPOUND AND ORGANIC ELECTROLUMINESCENT ELEMENT COMPRISING SAME

  摘要：

  本发明涉及一种金刚烷衍生物化合物和包括该化合物的有机发光二极管（OLED），更具体地，涉及一种金刚烷衍生物化合物，可用于OLED，并且使用该化合物具有低电压和高效率等优良性能的OLED。

  公开号：

  US20190016666A1

文献信息

• DERIVATIVES OF 2-DIARYLAMINOFLUORENE AND ORGANIC ELECTRONIC COMPOUNDS CONTAINING THEM
  申请人：Merck Patent GmbH

  公开号：US20150207075A1

  公开（公告）日：2015-07-23

  The present invention relates to certain fluorenes, to the use of the compounds in an electronic device, and to an electronic device comprising at least one of these compounds. The present invention furthermore relates to a process for the preparation of the compounds and to a formulation and composition comprising one or more of the compounds.

  本发明涉及某些芴类化合物，以及将这些化合物用于电子设备和包含至少其中一种化合物的电子设备。本发明还涉及一种制备这些化合物的方法，以及包含一种或多种这些化合物的配方和组合物。
• Electronic device having an amine containing layer processed from solution
  申请人：Merck Patent GmbH

  公开号：US10381576B2

  公开（公告）日：2019-08-13

  The present application relates to an organic electroluminescent device (OLED) comprising an emitting layer, where the emitting layer includes a compound having a small difference between the energies of the S1 and T1 states, and further comprising a layer which has been applied from solution between the emitting layer and anode and comprises an amine compound. The present application further relates to a process for producing such an OLED.

  本申请涉及一种有机电致发光器件（OLED），该器件包括一个发光层，其中发光层包括一种S1态和T1态能量差很小的化合物，还包括一层从溶液中涂敷在发光层和阳极之间的层，该层包括一种胺化合物。本申请还涉及生产这种有机发光二极管的工艺。
• Materials for electronic devices
  申请人：Merck Patent Gmbh

  公开号：US10396297B2

  公开（公告）日：2019-08-27

  The present application relates to a material comprising a monoarylamine of a defined formula and a p-dopant of a defined formula. The present application further relates to the use of said material in an organic layer of an electronic device, the device preferably being an organic electroluminescent device (OLED).

  本申请涉及一种由定义式的单芳基胺和定义式的对掺杂剂组成的材料。本申请还涉及在电子设备的有机层中使用所述材料，该设备最好是有机电致发光设备（OLED）。
• Organic light-emitting device
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US10756274B2

  公开（公告）日：2020-08-25

  An organic light-emitting device including a first electrode; a second electrode; emission units stacked between the first electrode and the second electrode and including at least one emission layer; and charge generation layers between two adjacent emission units, the charge generation layers each including an n-type charge generation layer and p-type charge generation layer, a maximum emission wavelength of light emitted by at least one of the emission units is different from that of another emission unit, one n-type charge generation layer includes a first compound and a metal-containing material, the first compound being represented by Formula 1, the p-type charge generation layers include an amino group-free compound, at least one of the emission units further includes a hole transporting (HT)-emission auxiliary layer on a first electrode side thereof, and the HT-emission auxiliary layer includes at least one second compound, the second compound being represented by Formula 2:

  一种有机发光器件，包括第一电极；第二电极；堆叠在第一电极和第二电极之间并包括至少一个发射层的发射单元；相邻两个发射单元之间的电荷发生层，电荷发生层各包括一个 n 型电荷发生层和一个 p 型电荷发生层，至少一个发射单元发出的光的最大发射波长不同于另一个发射单元，其中一个 n 型电荷发生层包括一个第一化合物和一个含金属材料、第一化合物由式 1 表示，p 型电荷发生层包括不含氨基的化合物，至少一个发射单元进一步包括位于其第一电极侧的空穴传输（HT）发射辅助层，HT-发射辅助层包括至少一种第二化合物，第二化合物由式 2 表示：
• Organic compound and organic electroluminescent element comprising same
  申请人：MATERIAL SCIENCE CO., LTD.

  公开号：US10941108B2

  公开（公告）日：2021-03-09

  The present invention relates to an adamantane derivative compound and an organic light-emitting diode (OLED) including the same, and more particularly, to an adamantane derivative compound capable of being used in an OLED and an OLED having excellent properties such as low voltage and high efficiency using the compound.

  本发明涉及一种金刚烷衍生物化合物和包括该化合物的有机发光二极管（OLED），更具体地说，涉及一种可用于 OLED 的金刚烷衍生物化合物和一种使用该化合物且具有低电压和高效率等优异性能的 OLED。