N,N'-bis(salicylidene)-1,10-decanediamine

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: N,N'-bis(salicylidene)-1,10-decanediamine
• 英文别名: bis(salicylidene)-decamethylene-diamine；n,n'-Bis(salicylidene)-1,10-decanediamine；2-[10-[(2-hydroxyphenyl)methylideneamino]decyliminomethyl]phenol
• 化学式: C₂₄H₃₂N₂O₂
• 分子量: 380.53
• InChiKey: AYGYQQHLAQAPKH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.7
• 重原子数：
  28
• 可旋转键数：
  13
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  65.2
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  N,N'-bis(salicylidene)-1,10-decanediamine 在 sodium tetrahydroborate 作用下， 反应 2.0h， 生成 N,N-decamethylenediaminebis(o-hydroxybenzylamine)
  参考文献：
  名称：

  PROCESS FOR PRODUCING A POLYBENZOXAZINE MONOMER

  摘要：

  制造聚苯并噁嗪单体的工艺，交联后使用交联产物形成喷嘴或大气再入体的烧蚀热防护系统。

  公开号：

  US20220153712A1
• 作为产物：
  描述：

  癸二胺 、 水杨醛 以 甲醇 为溶剂， 反应 2.0h， 生成 N,N'-bis(salicylidene)-1,10-decanediamine
  参考文献：
  名称：

  PROCESS FOR PRODUCING A POLYBENZOXAZINE MONOMER

  摘要：

  制造聚苯并噁嗪单体的工艺，交联后使用交联产物形成喷嘴或大气再入体的烧蚀热防护系统。

  公开号：

  US20220153712A1

文献信息

• Vaulted<i>trans</i>-Bis(salicylaldiminato)platinum(II) Crystals: Heat-Resistant, Chromatically Sensitive Platforms for Solid-State Phosphorescence at Ambient Temperature
  作者：Naruyoshi Komiya、Minoru Okada、Kanako Fukumoto、Kenji Kaneta、Atsushi Yoshida、Takeshi Naota

  DOI：10.1002/chem.201203669

  日期：2013.4.8

  hydrogen‐bonding interactions and/or Pt⋅⋅⋅Pt contacts, whereas heat‐quenchable crystals 4 a, 4 b, 5 c, 5 e, 6 c, 6 e, and 9 b are poorly bound with limited interactions, such as non‐, one‐, or two‐dimensional hydrogen‐bonding networks. These results lead to the conclusion that Pt⋅⋅⋅Pt contacts are an important factor in the heat resistance of solid‐state phosphorescence at ambient temperature, although

  描述了拱形反式双-（水杨基铝二氨基）铂（II）配合物的合成，结构和固态发射。一系列的聚亚甲基（1：n = 8; 2：n = 9; 3：n = 10; 4：n = 11; 5：n = 12; 6：n = 13）和聚氧乙烯（7：m = 2; 8：m = 3; 9：m = 4）拱形复合体（R = H（a），3-MeO（b），4-MeO（c），5-MeO（d），6-MeO（e），4-CF 3 O（f），5-CF 3 O（g））是通过用[PtCl 2（CH 3 CN）2 ]处理相应的N，N'-双（水杨基）-1，ω-烷二胺。的反式协调，拱形结构和的晶体堆积1 - 9X射线衍射研究已明确确立了这一点。在环境温度下，在紫外线激发下，观察到配合物的晶体具有不可预测的，依赖于结构的磷光发射，而在相同条件下，这些配合物在溶液状态下完全不发光。长连接的复合物的晶体4 - 6，8，和9表现出强烈的发射（Φ 77K =
• The stereochemistry of oxovanadium(IV) complexes derived from salicylaldehyde and polymethylenediamines
  作者：Gabriel A. Kolawole、Kantilal S. Patel

  DOI：10.1039/dt9810001241

  日期：——

  Several Schiff-base complexes of oxovanadium(IV), [VOOC6H4CHN-CR1R2(CH2)n– 1–NCHC6H4O}] where n= 2 (R1 and R2= H or CH3) and n= 3–10 (R1= R2= H), have been isolated and their spectroscopic and magnetic properties have been investigated. The ν(VO) stretching vibration frequencies fall in the range 861–994 cm–1. Minimum and maximum dπ–pπ overlaps in VO were observed in (4; R1= R2= H, n= 3) and (7; R1=

  氧钒（IV）[[VO OC 6 H 4 CH N-CR 1 R 2（CH 2）n – 1 –N CHC 6 H 4 O}]的几种席夫碱络合物，其中n = 2（R 1和R 2 = H或CH 3）和n = 3-10（R 1 = R 2 = H）已被分离出来，并对其光谱和磁性进行了研究。在ν（V O）的伸缩振动的频率落入范围861-994厘米-1。最小和最大d π - p π以V重叠;○是在观察到（4 R 1 = R 2 = H，Ñ ;（R 7 = 3）和1 = R 2 = H，Ñ分别= 6）。在氯仿和吡啶，并在固态电子光谱指示的能量的顺序的反转的可能性Ë π *和b 1*水平；因此，随着亚甲基链长度的增加，观察到几何形状的多样性。配合物在室温下的有效磁矩在1.64到1.81 BM之间。但是，θ值相对较小。
• Diehl, H.; Liggett, L. M.; Hach, C. C., Iowa State College Journal of Science, 1947, vol. 22, p. 110 - 125
  作者：Diehl, H.、Liggett, L. M.、Hach, C. C.、Harrison, G. C.、Henselmeier, L.、et al.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Co: SVol.B1, 110, page 241 - 243
  作者：

  DOI：——

  日期：——
• Synthesis, structure, and chromogenic properties of polymethylene-vaulted trans-bis(salicylaldiminato)palladium(II) complexes
  作者：Takatoshi Maeda、Soichiro Kawamorita、Takeshi Naota

  DOI：10.1016/j.poly.2016.05.004

  日期：2016.10

  The synthesis, structure, and chromogenic properties of polymethylene-vaulted trans-bis(salicylaldiminato)palladium(II) complexes are described. A series of the Pd complexes incorporating nona-, deca-, undeca-and dodecamethylene bridges (1a: n = 9; 1b: n = 10; 1c: n = 11; 1d: n = 12) was prepared by the treatment of Pd(OAc)(2) with the corresponding N,N'-bis(salicylidene)-1,omega-alkanediamines. The trans-coordination, vaulted structures, and crystal packing of 1a-d have been unequivocally established from X-ray diffraction studies. Complexes 1a-d exhibit linker-dependent chromatic properties in 2-methyl-2,3,4,5-tetrahydrofuran, where the absorption wavelengths at around 400 nm are shifted hypsochromically with a decrease in the linker length, which is in contrast to the structure-independence of the absorption properties for the corresponding polymethylene-vaulted Pt analogues 2a-d observed under the same conditions. Density functional theory and time-dependent DFT calculations revealed that the present specific linker dependence in the chromism of 1 is ascribed to specific alteration of the d-pi conjugation on the flexible trans-bis(salicylaldiminato)palladium coordination platforms by variation of the coordination planarity. (C) 2016 Elsevier Ltd. All rights reserved.