N-ditert-butylphosphinoselenoylpropan-2-amine | 167314-13-8

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N-ditert-butylphosphinoselenoylpropan-2-amine
• CAS: 167314-13-8
• 化学式: C₁₁H₂₆NPSe
• 分子量: 282.268
• InChiKey: GUSANWQJARMJFZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.6
• 重原子数：
  14
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  12
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  N-ditert-butylphosphinoselenoylpropan-2-amine 以 二氯甲烷 为溶剂， 反应 2.5h， 生成 {[(di-tert-butylphosphoroselenoyl)(isopropyl)amino]methylene}-diisopropylammonium Trifluoromethanesulfonate
  参考文献：
  名称：

  N-(二叔丁基膦酰基)-和N-(二叔丁基磷硒酰)甲脒盐的简便方法：卡宾前体

  摘要：

  研究了(二叔丁基膦酰基)胺和P,P-二叔丁基膦硒酸酰胺与Alder's二聚体的反应。对于二叔丁基膦酰胺，反应通过 Alder 二聚体在磷原子上的初级亲电攻击进行，以提供双阳离子盐 3。3 的去质子化导致 N-膦酰甲脒5（“磷酰胺”）。烷基（二叔丁基膦酰基）胺与阿尔德氏二聚体以 2:1 的摩尔比反应，得到 N-膦酰基甲脒盐；第二当量的（烷基氨基）膦作为碱。(芳氨基)膦与Alder的二聚体反应得到苯氮杂磷衍生物。为了指导阿尔德二聚体在氮原子上的亲电攻击，使用了膦硒酸酰胺。他们与阿尔德反应 硒原子上的二聚体，然后是硒-磷位移，得到 N-（二叔丁基磷硒酰）甲脒盐。具有庞大取代基（金刚烷基，tBu）的膦亚硒酰胺经历了 N-烷基键的断裂，得到了磷酰胺。分离和表征了各种关键中间体，例如 3 和 22b。开发了一种合成卡宾前体 PIII 和 PV N-取代甲脒盐的简便方法。

  DOI：

  10.1002/ejic.201301365
• 作为产物：
  描述：

  N-ditert-butylphosphanylpropan-2-amine 在 selenium 作用下， 以 乙醚 、 正己烷 、 甲苯 为溶剂， 反应 2.0h， 生成 N-ditert-butylphosphinoselenoylpropan-2-amine
  参考文献：
  名称：

  Synthesis of selenophosphinic and tellurophosphinic amides and amidato complexes. Crystal structures of Bu^t₂P(Te)NH(C₆H₁₁), [Ti(η-C₅H₅)Cl₂{Bu^t₂P(Se)NPrⁱ}] and [TiCl₂{Bu^t₂P(Se)N(C₆H₁₁)}₂]·C₇H₈

  摘要：

  The reaction of Bu(2)(t)PNHR' with selenium or tellurium affords the chalcogenophosphinic amides Bu(2)(t)P(E)NHR' (E = Se or Te; R' = Pr-i or cyclo-C6H11). The compounds [Bu(2)(t)P(E)NHCH2](2) were prepared similarly. The crystal structure of Bu(2)(t)P(Te)NH(C6H11) was determined; it shows a short P-Te bond of 2.371(1) Angstrom and a rather long P-N bond of 1.781(4) Angstrom. The lithium salts Li[Bu(2)(t)P(Se)NR'] react with [TiCl3(cp)] (cp = eta-C5H5) to give [TiCl2(cp){Bu(2)(t)P(Se)NR'}]. The reaction of Li[Bu(2)(t)P(Se)NPri] with [TiCl4(thf)(2)] (thf = tetrahydrofuran) affords [TiCl3{Bu(2)(t)P(Se)NPri)]. while a similar reaction with Li[Bu(2)(t)P(Se)N(C6H11)] leads to the isolation of [TiCl2{Bu(2)(t)P(Se)N(C6H11}(2)]. The structures of [TiCl2(cp){Bu(2)(t)P(Se)NPri}] and [TiCl2{Bu(2)(t)P(Se)N(C6H11)}(2)]. C7H8 have been determined by X-ray crystallography. The selenophosphinic amidato ligands are bidentate in ail cases. The former complex adopts a distorted square-pyramidal geometry with apical cp, while the latter is octahedral with cis-CI ligands and trans stereochemistry for the nitrogen donors.

  DOI：

  10.1039/dt9950001887

文献信息

• Synthesis of phosphinochalcogenoic amidato complexes of divalent transition metals and their thermolysis to metal selenide and telluride phases
  作者：Xuejing Song、Manfred Bochmann

  DOI：10.1039/a702460f

  日期：——

  Protolysis of the transition-metal diamides [MN(SiMe 3 ) 2 } 2 (thf) n ] (M = Cr, Mn, Fe or Co) with 2 equivalents of phosphinochalcogenoic amides Bu t 2 P(E)NHR (E = Se or Te, R = Pr i or cyclo-C 6 H 11 ) gave a series of thermally stable metal–selenium and –tellurium complexes [MBu t 2 P(E)NR} 2 ]. The complex [NiBu t 2 P(Se)NR} 2 ] was obtained from Li[Bu t 2 (Se)NR] and [NiCl 2 (PMe 3 ) 2 ]. The compounds sublime readily under reduced pressure and are suitable for the gas-phase deposition of metal chalcogenide films. The selenium precursors lead to MSe (M = Cr, Mn, Fe or Ni), while tellurium complexes afford MTe 2 (M = Fe, Mn or Co). By contrast, [CoBu t 2 P(Se)NR} 2 ] gives Co 3 Se 4 , while [NiBu t 2 P(Se)NR} 2 ] generates NiSe or Ni 6 Se 5 , depending on the deposition conditions.

  过渡金属二酰胺的原解离反应 [MN(SiMe₃)₂}₂(thf)ₙ]（M = Cr, Mn, Fe 或 Co）与两个当量的磷氟硫氨基化合物 Bu₂P(E)NHR（E = Se 或 Te，R = Pr₁ 或环己烷）反应，生成了一系列热稳定的金属-硒和-碲配合物 [MBu₂P(E)NR}₂]。配合物 [NiBu₂P(Se)NR}₂] 是由 Li[Bu₂(Se)NR] 和 [NiCl₂(PMe₃)₂] 反应获得的。这些化合物在减压下易于升华，并适合用于金属硫族化物薄膜的气相沉积。硒前体导致 MSe（M = Cr, Mn, Fe 或 Ni），而碲配合物则提供 MTe₂（M = Fe, Mn 或 Co）。相反，[CoBu₂P(Se)NR}₂] 生成 Co₃Se₄，而 [NiBu₂P(Se)NR}₂] 则根据沉积条件生成 NiSe 或 Ni₆Se₅。
• Synthesis of phosphinochalcogenoic amidato complexes of zinc and cadmium. The crystal and molecular structure of [Zn{But 2P(Se)NPri}2]
  作者：Manfred Bochmann、Gabriel C. Bwembya、Michael B. Hursthouse、Simon J. Coles

  DOI：10.1039/dt9950002813

  日期：——

  The protolysis of zinc and cadmium amides [MN(SiMe(3))(2)}(2)] with 2 equivalents of phosphinochalcogenoic amides Bu(2)(t)P(E)NHR (E = Se or Te, R = Pr-i or C6H11) gave the complexes [MBu(2)(t)P(E)NR}(2)] (M = Zn or Cd). The thermally stable compounds are monomeric and sublime readily. If the protolysis reaction is carried out in a molar ratio of 1:1, the mixed-ligand compounds [ZnN(SiMe(3))(2)}Bu(2)(t)P(E)NR}] can be isolated for zinc but not for cadmium. The crystal structure of [ZnBu(2)(t)P(Se)NPri}(2)] has been determined. The complex possesses a distorted tetrahedral structure. The ligands are bidentate, with short [1.981(3) Angstrom] Zn-N and comparatively long [2.5375(9) Angstrom] Zn-Se bonds.