tetramethoxypentiptycene quinone

• 分子结构分类: 有机化合物 - 苯类化合物 - 并四苯
• 英文名称: tetramethoxypentiptycene quinone
• 英文别名: (1R,5S,12R,16S)-7,10,18,21-tetramethoxynonacyclo[14.6.6.65,12.02,15.04,13.06,11.017,22.023,28.029,34]tetratriaconta-2(15),4(13),6,8,10,17,19,21,23,25,27,29,31,33-tetradecaene-3,14-dione
• 化学式: C₃₈H₂₈O₆
• 分子量: 580.637
• InChiKey: IZKDZDVTRXJQRI-KXSOJQAOSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.8
• 重原子数：
  44
• 可旋转键数：
  4
• 环数：
  11.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  71.1
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为产物：
  描述：

  dimethoxytriptycene chloroquinone 在 sodium methylate 、 溶剂黄146 作用下， 生成 tetramethoxypentiptycene quinone
  参考文献：
  名称：

  The reaction of triptycene haloquinones with alkoxides. An unusual route to pentiptycene quinones

  摘要：

  Triptycene haloquinones 3 react with sodium alkoxides in refluxing alcohol to afford, besides the expected substitution products, pentiptycene quinone 4. This approach to 4 is compared with a Diels-Alder strategy to the same compound. (C) 2003 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(03)00755-x

文献信息

• The reaction of triptycene haloquinones with alkoxides. An unusual route to pentiptycene quinones
  作者：Spyros Spyroudis、Nikoletta Xanthopoulou

  DOI：10.1016/s0040-4039(03)00755-x

  日期：2003.5

  Triptycene haloquinones 3 react with sodium alkoxides in refluxing alcohol to afford, besides the expected substitution products, pentiptycene quinone 4. This approach to 4 is compared with a Diels-Alder strategy to the same compound. (C) 2003 Elsevier Science Ltd. All rights reserved.