1,4-methano-1,4,4a,9a-tetrahydrofluorenone | 65495-96-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 芴
• 英文名称: 1,4-methano-1,4,4a,9a-tetrahydrofluorenone
• 英文别名: 1,4,4a,9a-Tetrahydro-9H-1,4-methanofluoren-9-one；tetracyclo[9.2.1.02,10.03,8]tetradeca-3,5,7,12-tetraen-9-one
• CAS: 65495-96-7
• 化学式: C₁₄H₁₂O
• 分子量: 196.249
• InChiKey: YNXVRVCNNLPORR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.5
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1,4-methano-1,4,4a,9a-tetrahydrofluorenone 以95%的产率得到1-茚酮
  参考文献：
  名称：

  吉那霉素抗生素的第一种方法：吉那芴酮支架的合成

  摘要：

  已成功进行茚并酮5与邻苯二甲砜6的环合，以提供模型苯并[b]芴酮7，说明了向那那霉素抗生素的潜在途径。

  DOI：

  10.1016/0040-4039(96)00349-8
• 作为产物：
  描述：

  2-(p-chlorophenylsulfinyl)-1-indanone 、 环戊二烯 以53%的产率得到
  参考文献：
  名称：

  SZMANT H. H.; NANJUNDIAH R., J. ORG. CHEM., 1978, 43, NO 9, 1835-1837

  摘要：

  DOI：

文献信息

• MOLDED ARTICLE FOR CLEAN ROOM AND METHOD FOR PRODUCING SAME
  申请人：Fuji Bakelite Co., Ltd

  公开号：EP1790690A1

  公开（公告）日：2007-05-30

  Provided is a shaped article for clean rooms comprising a resin composition prepared by melt-kneading 100 parts by weight of a cyclic olefin polymer (A) having a glass transition temperature of from 60 to 200°C, from 1 to 150 parts by weight of a flexible copolymer (B) prepared by polymerizing at least two monomers selected from a group consisting of olefins, dienes and aromatic vinyl-hydrocarbons, and having a glass transition temperature of 0°C or lower, from 0.001 to 1 part by weight of a radical initiator (C), and from 0 to 1 part by weight of a polyfunctional compound (D) having at least two radical-polymerizable functional groups in the molecule. The shaped article for clean rooms has good chemical resistance, heat resistance and dimensional accuracy, it is inhibited from releasing a volatile component around it, and it has good abrasion resistance and is inhibited from producing particles.

  本发明提供了一种用于洁净室的成型制品，该制品包括一种树脂组合物，该树脂组合物是通过熔融捏合100份(重量)玻璃化转变温度为60至200℃的环烯烃聚合物(A)制备的；1至150份(重量)柔性共聚物(B)，该柔性共聚物是通过聚合至少两种选自烯烃、二烯烃和芳香族乙烯基烃的单体制备的，玻璃化转变温度为0℃或更低；0.001 至 1 重量份的自由基引发剂 (C)，以及 0 至 1 重量份的多官能化合物 (D)，其分子中至少有两个可自由基聚合的官能团。洁净室用异型制品具有良好的耐化学性、耐热性和尺寸精度，可抑制周围挥发性成分的释放，具有良好的耐磨性，并可抑制颗粒的产生。
• METHOD FOR PRODUCING RESIN COMPOSITION
  申请人：Mitsui Chemicals, Inc.

  公开号：EP1790691B1

  公开（公告）日：2009-06-10
• RESIN COMPOSITION AND MOLDED ARTICLE OBTAINED FROM THE COMPOSITION
  申请人：Mitsui Chemicals, Inc.

  公开号：EP2143763B1

  公开（公告）日：2013-02-27
• Method for producing resin composition
  申请人：Kaneko Kazuyoshi

  公开号：US20070155903A1

  公开（公告）日：2007-07-05

  Provided is a method for producing a resin composition by melt-kneading a cyclic olefin polymer (A) having a glass transition temperature of from 60 to 200° C. and a flexible polymer (B) having a glass transition temperature of 0° C. or lower, wherein a part of the cyclic olefin polymer (A) is previously melt-kneaded with the flexible polymer (B) and a radical initiator (C) and then the remaining cyclic olefin polymer (A) is added thereto and melt-kneaded. The cyclic olefin polymer (A) is divided into two portions and added separately at two times, and accordingly, the mixture having a crosslinked structure may be diluted with the cyclic olefin polymer (A) not having a crosslinked structure, and the increase in the melt viscosity of the resin composition may be thereby prevented. A composition having good abrasion resistance and good melt shapability can be obtained.
• Molded Article for Clean Room and Method for Producing Same
  申请人：Sakamoto Takaki

  公开号：US20070255030A1

  公开（公告）日：2007-11-01

  Provided is a shaped article for clean rooms comprising a resin composition prepared by melt-kneading 100 parts by weight of a cyclic olefin polymer (A) having a glass transition temperature of from 60 to 200° C., from 1 to 150 parts by weight of a flexible copolymer (B) prepared by polymerizing at least two monomers selected from a group consisting of olefins, dienes and aromatic vinyl-hydrocarbons, and having a glass transition temperature of 0° C. or lower, from 0.001 to 1 part by weight of a radical initiator (C), and from 0 to 1 part by weight of a polyfunctional compound (D) having at least two radical-polymerizable functional groups in the molecule. The shaped article for clean rooms has good chemical resistance, heat resistance and dimensional accuracy, it is inhibited from releasing a volatile component around it, and it has good abrasion resistance and is inhibited from producing particles.