2,4,6-tri(naphthalen-1-yl)-1,3,5-triazine

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 2,4,6-tri(naphthalen-1-yl)-1,3,5-triazine
• 英文别名: TN1Ta；tri-[1]naphthyl-[1,3,5]triazine；Tri-[1]naphthyl-[1,3,5]triazin；2,4,6-Trinaphthalen-1-yl-1,3,5-triazine
• 化学式: C₃₃H₂₁N₃
• 分子量: 459.55
• InChiKey: PBIAMVUZDNGEKB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.7
• 重原子数：
  36
• 可旋转键数：
  3
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  38.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2,4,6-tri(naphthalen-1-yl)-1,3,5-triazine 、 alkaline earth salt of/the/ methylsulfuric acid 生成 1-萘甲酸
  参考文献：
  名称：

  v.Meyer,E.; Naebe, Journal fur praktische Chemie (Leipzig 1954), 1910, vol. <2>82, p. 537

  摘要：

  DOI：
• 作为产物：
  描述：

  2,4,6-三溴-1,3,5-三嗪 、 萘 在 二硫化碳 、 三氯化铝 作用下， 生成 2,4,6-tri(naphthalen-1-yl)-1,3,5-triazine
  参考文献：
  名称：

  v.Meyer,E.; Naebe, Journal fur praktische Chemie (Leipzig 1954), 1910, vol. <2>82, p. 537

  摘要：

  DOI：

文献信息

• STABILIZATION OF COSMETIC COMPOSITIONS AGAINST PHOTODEGRADATION
  申请人：BASF SE

  公开号：EP3492144A1

  公开（公告）日：2019-06-05

  Disclosed is the use of UV absorbers selected from (a2) hydroxyphenyl triazines of formula in which R1, R2 and R3 independently of one another, are C1-C18alkyl; and (a3) benzotriazole derivatives of formula wherein R4 is a random statistical mixture of at least three isomeric branched secondary alkyl groups each having 8 to 30 carbon atoms and having the formula E1 is a straight-chain C1-C14alkyl; E2 is a straight-chain C4-C15alkyl; wherein the total number of carbon atoms in E1 plus E2 is from 7 to 29; and R5 is C1-C5alkyl; for stabilizing cosmetic compositions against photodegradation comprising (b)symmetrical triazine derivatives of formula wherein A is a radical of formula R6 and R10 independently from each other are hydrogen; C1-C18alkyl; or C6-C12aryl; R7, R8 and R9 independently from each other are hydrogen; or a radical of formula wherein, in formula (3a), at least one of the radicals R7, R8 and R9 are a radical of formula (3c); R11, R12, R13 and R14 independently from each other are hydrogen; hydroxy; halogen; C1-C18alkyl; C1-C18alkoxy; C6-C12aryl; biphenylyl; C6-C12aryloxy; C1-C18alkylthio; carboxy; -COOM; C1-C18-alkylcarboxyl; aminocarbonyl; mono- or di-C1-C18alkylamino; C1-C10acylamino; or -COOH; M is an alkali metal ion; x is 1 or 2; and y is a number from 2 to 10; and a UV-absorber selected from (c1) cinnamic acid derivatives; and (c2) dibenzoylmethane derivatives.

  所公开的紫外线吸收剂选自以下物质 (a2) 式中的羟苯基三嗪 其中 R1、R2 和 R3 相互独立地为 C1-C18 烷基；以及 (a3) 式中的苯并三唑衍生物 其中 R4 是至少三个异构支链仲烷基的无规统计混合物，每个烷基具有 8 至 30 个碳原子，其式为 E1 是直链 C1-C14 烷基； E2 是直链 C4-C15 烷基；其中 E1 加 E2 的碳原子总数为 7 至 29；以及 R5 是 C1-C5 烷基； 用于稳定化妆品组合物以防止光降解，包括 (b) 式中的对称三嗪衍生物 其中 A 是式中的基团 R6和R10各自独立地为氢、C1-C18烷基或C6-C12芳基； R7、R8 和 R9 相互独立地为氢；或式中的一个基团 其中，在式 (3a) 中，R7、R8 和 R9 中至少有一个是式 (3c) 的基； R11、R12、R13 和 R14 相互独立地为氢；羟基；卤素；C1-C18 烷基；C1-C18 烷氧基；C6-C12 芳基；联苯；C6-C12 芳氧基；C1-C18 烷硫基；羧基；-COOM；C1-C18-烷基羧基；氨基羰基；单-或二-C1-C18 烷基氨基；C1-C10 乙酰氨基；或 -COOH； M 是碱金属离子 x 是 1 或 2；以及 y 是 2 至 10 的数字； 紫外线吸收剂选自 (c1) 肉桂酸衍生物；和 (c2) 二苯甲酰甲烷衍生物。
• Symmetrical triazine derivatives
  申请人：BASF SE

  公开号：EP1606270B1

  公开（公告）日：2013-08-14
• STABILIZATION OF COSMETIC COMPOSITIONS
  申请人：BASF SE

  公开号：EP2180878B1

  公开（公告）日：2019-01-16
• US7311897B2
  申请人：——

  公开号：US7311897B2

  公开（公告）日：2007-12-25
• [EN] STABILIZATION OF COSMETIC COMPOSITIONS<br/>[FR] STABILISATION DE COMPOSITIONS COSMÉTIQUES
  申请人：CIBA HOLDING INC

  公开号：WO2009027390A2

  公开（公告）日：2009-03-05

  Disclosed is the use of UV absorbers selected from (a1) diphenylacrylates; (a2) hydroxyphenyl triazines of formula (1), in which R1, R2 and R3 independently of one another, are C1-C18alkyl; (a3) benzotriazole derivatives of formula (2), wherein R4 is a random statistical mixture of at least three isomeric branched secondary alkyl groups each having 8 to 30 carbon atoms and having the formula (2a); E1 is a straight-chain C1-C14alkyl; E2 is a straight-chain C4-C15alkyl; wherein the total number of carbon atoms in E1 plus E2 is from 7 to 29; and R5 is C1-C5alkyl; and (a4) dialkyl naphthalate; for stabilizing cosmetic compositions comprising (b) symmetrical triazine derivatives of formula (3), wherein A is a radical of formula (3a); or (3b) R6 and R10 independently from each other are hydrogen; C1-C18alkyl; or C6-C12aryl; R7, R8 and R9 independently from each other are hydrogen; or a radical of formula (3c), wherein, in formula (3a), at least one of the radicals R7, R8 and R9 are a radical of formula (3c); R11, R12, R13 and R14 independently from each other are hydrogen; hydroxy; halogen; C1-C18alkyl; C1-C18alkoxy; C6-C12aryl; biphenylyl; C6-C12aryloxy; C1-C18alkylthio; carboxy; -COOM; C1-C18-alkylcarboxyl; aminocarbonyl; mono- or di-C1-C18alkylamino; C1-C10acylamino; or -COOH; M is an alkali metal ion; x is 1 or 2; and y is a number from 2 to 10; and a UV-absorber selected from (c1) cinnamic acid derivatives; and (C2) dibenzoylmethane derivatives.