| 195148-70-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 萘并吡喃类
• CAS: 195148-70-0
• 化学式: C₂₈H₂₇N₃O₂
• 分子量: 437.541
• InChiKey: XUMGBDRHGVFMAG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.89
• 重原子数：
  33.0
• 可旋转键数：
  0.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.21
• 拓扑面积：
  55.21
• 氢给体数：
  1.0
• 氢受体数：
  5.0

反应信息

• 作为反应物：
  描述：

  在 甲醇 、 sodium tetrahydroborate 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 0.08h， 以65%的产率得到2,5-Dioxa-17,20,23-triazapentacyclo[23.8.0.06,15.09,14.026,31]tritriaconta-1(25),6(15),7,9,11,13,26,28,30,32-decaene
  参考文献：
  名称：

  A novel aluminum-sensitive fluorescent nano-chemosensor based on naphthalene macrocyclic derivative

  摘要：

  A novel fluorescence nano-chemosensor (L) for Al3+ cations has been synthesized and characterized by NMR studies, IR spectroscopy, elemental analyses, and scanning electron microscopy. The fluorescent nano-chemosensors with size about 40 nm were prepared by nanoprecipitation method. The sensor shows selectivity to Al3+ cations over 17 other metal cations. Upon addition of Al3+, the fluorescence emission of the sensor at 358 nm is significantly increased. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.02.047
• 作为产物：
  描述：

  2-[2-(2-formylnaphthoxy)ethoxy]naphthaldehyde 、 二乙烯三胺 以 甲醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 2.0h， 生成
  参考文献：
  名称：

  A novel aluminum-sensitive fluorescent nano-chemosensor based on naphthalene macrocyclic derivative

  摘要：

  A novel fluorescence nano-chemosensor (L) for Al3+ cations has been synthesized and characterized by NMR studies, IR spectroscopy, elemental analyses, and scanning electron microscopy. The fluorescent nano-chemosensors with size about 40 nm were prepared by nanoprecipitation method. The sensor shows selectivity to Al3+ cations over 17 other metal cations. Upon addition of Al3+, the fluorescence emission of the sensor at 358 nm is significantly increased. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2013.02.047