trimethylamine; deuteronated form | 16962-53-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: trimethylamine; deuteronated form
• 英文别名: N-Deuterio-trimethylammonium；Trimethyl(D)ammonium；Deuterio(trimethyl)azanium
• CAS: 16962-53-1
• 化学式: C₃H₁₀N
• 分子量: 61.1112
• InChiKey: GETQZCLCWQTVFV-DYCDLGHISA-O

计算性质

• 辛醇/水分配系数(LogP)：
  0.3
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  4.4
• 氢给体数：
  1
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  硼烷-三甲胺络合物 、 重水 在 氘代硫酸 作用下， 以 四氯化碳 、 重水 为溶剂， 生成 trimethylamine; deuteronated form 、 硼酸-d3
  参考文献：
  名称：

  Hydrolysis of (trimethylamine)borane with ion-exchange resins: effect of ionic surfactants

  摘要：

  The hydrolysis of (trimethylamine)borane (TB) with the D+ form of ion-exchange resin suspended in organic solvent was studied. The hydrolysis retardation is observed in two cases: (i) due to inhibition by the hydrolysis side product, trimethylammonium, or (ii) due to resin pretreatment by long-chain cationic surfactants. The effect of hydrolysis inhibition is attributed to adsorption of surfactants on the resin which lowered the concentration of exchangeable deuterons in the reaction zone.

  DOI：

  10.1021/j100153a077

文献信息

• Hydrolysis of (trimethylamine)borane with ion-exchange resins: effect of ionic surfactants
  作者：Lev Bromberg、Dmitri Muraviev、Abraham Warshawsky

  DOI：10.1021/j100153a077

  日期：1993.12

  The hydrolysis of (trimethylamine)borane (TB) with the D+ form of ion-exchange resin suspended in organic solvent was studied. The hydrolysis retardation is observed in two cases: (i) due to inhibition by the hydrolysis side product, trimethylammonium, or (ii) due to resin pretreatment by long-chain cationic surfactants. The effect of hydrolysis inhibition is attributed to adsorption of surfactants on the resin which lowered the concentration of exchangeable deuterons in the reaction zone.