4-bromo-N,N-bis(diphenylphosphanomethyl)aniline

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 4-bromo-N,N-bis(diphenylphosphanomethyl)aniline
• 英文别名: 4-bromo-N,N-bis(diphenylphosphanylmethyl)aniline
• 化学式: C₃₂H₂₈BrNP₂
• 分子量: 568.433
• InChiKey: MFYFCWMWPBFKDF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  36
• 可旋转键数：
  9
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  4-bromo-N,N-bis(diphenylphosphanomethyl)aniline 在 正丁基锂 、 sodium hydroxide 作用下， 以 四氢呋喃 、 乙醇 、 正己烷 、 水 为溶剂， 反应 0.25h， 生成 (Ph₂PCH₂)₂N(C₆H₄-4-Si(CH₂CH₂CH₂SiMe₂(CH₂S(CH₂)₂NMe₂))₃)
  参考文献：
  名称：

  Synthesis of palladium(II) complexes of bidentate phosphano ligands with carbosilane substituents

  摘要：

  The synthesis of carbosilane dendrons with bidentate bis(diphenylphosphanomethyl)amino ligands at the focal point and terminal alkyl or dimethylamino end-groups, together with their palladium(II) complexes and a cationic ammonium-quaternized derivative, is described. All compounds were characterized by elemental analysis and NMR spectroscopy (H-1, C-13, P-31 and Si-29). (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.07.032
• 作为产物：
  描述：

  Bis<(diphenylphosphino)methyl>phosphan 、 4-溴苯胺 在 聚合甲醛 作用下， 以 甲苯 为溶剂， 生成 4-bromo-N,N-bis(diphenylphosphanomethyl)aniline
  参考文献：
  名称：

  Synthesis of palladium(II) complexes of bidentate phosphano ligands with carbosilane substituents

  摘要：

  The synthesis of carbosilane dendrons with bidentate bis(diphenylphosphanomethyl)amino ligands at the focal point and terminal alkyl or dimethylamino end-groups, together with their palladium(II) complexes and a cationic ammonium-quaternized derivative, is described. All compounds were characterized by elemental analysis and NMR spectroscopy (H-1, C-13, P-31 and Si-29). (C) 2012 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2012.07.032

文献信息

• New functionalised ditertiary phosphines via phosphorus based Mannich condensation reactions
  作者：Sean E. Durran、Mark R.J. Elsegood、Neil Hawkins、Martin B. Smith、Salem Talib

  DOI：10.1016/s0040-4039(03)01273-5

  日期：2003.7

  The one-step synthesis of a family of functionalised ditertiary aminophosphines are described including the X-ray crystal structure of 4-(Ph2PCH2)2N}C6H4CO2H.

  描述了包括4-（Ph 2 PCH 2）2 N} C 6 H 4 CO 2 H的X射线晶体结构的功能化二叔氨基膦家族的一步合成。
• Synthesis of palladium(II) complexes of bidentate phosphano ligands with carbosilane substituents
  作者：Susana Vigo、Román Andrés、Pilar Gómez-Sal、Javier de la Mata、Ernesto de Jesús

  DOI：10.1016/j.jorganchem.2012.07.032

  日期：2012.10

  The synthesis of carbosilane dendrons with bidentate bis(diphenylphosphanomethyl)amino ligands at the focal point and terminal alkyl or dimethylamino end-groups, together with their palladium(II) complexes and a cationic ammonium-quaternized derivative, is described. All compounds were characterized by elemental analysis and NMR spectroscopy (H-1, C-13, P-31 and Si-29). (C) 2012 Elsevier B. V. All rights reserved.