[1,1'-binaphthalene]-2,2',8,8'-tetraol

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: [1,1'-binaphthalene]-2,2',8,8'-tetraol
• 英文别名: 2.8.2'.8'-Tetraoxy-dinaphthyl-(1.1')；[1,1']Binaphthyl-2,8,2',8'-tetraol；8-(2,8-Dihydroxynaphthalen-1-yl)naphthalene-1,7-diol；8-(2,8-dihydroxynaphthalen-1-yl)naphthalene-1,7-diol
• 化学式: C₂₀H₁₄O₄
• 分子量: 318.329
• InChiKey: PPBFNYKIABMSKK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.6
• 重原子数：
  24
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  80.9
• 氢给体数：
  4
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  [1,1'-binaphthalene]-2,2',8,8'-tetraol 在 [N,N'-bis(salicylidene)ethane-1,2-diaminato]cobalt(II) 、 氧气 作用下， 以 乙腈 为溶剂， 反应 15.5h， 以50%的产率得到(±)-naphtho[1,8-bc]naphtho[1',8':3,4,5]furo[2,3-d]furan-5,12-dione
  参考文献：
  名称：

  Selective Oxidation of 8,8′-Hydroxylated Binaphthols to Bis-spironaphthalenones or Binaphtho-para- and Binaphtho-ortho-quinones

  摘要：

  The selective oxidation of a series of functionalized 8,8'-hydroxylated binaphthols to binaphtho-para- and binaphtho-ortho-quinones has been realized using either a Co-salen catalyst or ortho-iodoxybenzoic acid. A unique spirocyclic bis-spironaphthalenone was also obtained in good yield via a phenyliodonium diacetate promoted oxidative dearomatization.

  DOI：

  10.1021/ol302195e
• 作为产物：
  描述：

  1,7-二羟基萘 在 乙醇 、 氢碘酸 、 lead dioxide 、 苯 作用下， 生成 [1,1'-binaphthalene]-2,2',8,8'-tetraol
  参考文献：
  名称：

  Morgan; Vining, Journal of the Chemical Society, 1921, vol. 119, p. 1710

  摘要：

  DOI：

文献信息

• SECONDARY BATTERY
  申请人：NOMURA Masayoshi

  公开号：US20160268607A1

  公开（公告）日：2016-09-15

  Provided is a secondary battery that includes an electrode active material including an organic compound represented by the following General Formula 1. Ar—(OH) n In the General Formula 1, Ar denotes at least one selected from the group consisting of 1,1-binaphthalene, anthracene, triphenylene, tetraphenylene, and pyrene, and is optionally substituted with a substituent. The substituent of Ar is at least one selected from the group consisting of an OH group, a carbonyl group produced through oxidization of the OH group, an alkyl group containing 3 or less carbon atoms, a halogen atom, and an amino group. n denotes an integer in a range of from 2 through 8.