2-dodecylbenzene-1,4-diol | 4595-23-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-dodecylbenzene-1,4-diol
• 英文别名: 2-Dodecyl-hydrochinon；2-dodecyl-hydroquinone；2.5-Dihydroxy-1-dodecyl-benzol
• CAS: 4595-23-7
• 化学式: C₁₈H₃₀O₂
• 分子量: 278.435
• InChiKey: ZNQOWAYHQGMKBF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  20
• 可旋转键数：
  11
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

安全信息

• 海关编码：
  2907299090

反应信息

• 作为反应物：
  描述：

  2-dodecylbenzene-1,4-diol 在 三氧化硫 作用下， 生成 2-Dodecyl-5-sulfo-hydrochinon
  参考文献：
  名称：

  Vandenberghe,A.; Willems,J.F., Bulletin des Societes Chimiques Belges, 1965, vol. 74, p. 397 - 406

  摘要：

  DOI：
• 作为产物：
  描述：

  Methyl-(4-hydroxy-3-dodecyl-phenyl)-aether 在 三氯化铝 、 苯 作用下， 生成 2-dodecylbenzene-1,4-diol
  参考文献：
  名称：

  Asano; Hase, Yakugaku Zasshi/Journal of the Pharmaceutical Society of Japan, 1940, vol. 60, p. 650,658

  摘要：

  DOI：

文献信息

• A Convenient Synthesis of 2-Alkylated 1,4-Benzenediols
  作者：Yutaka Ozaki、Ayako Hosoya、Kyouko Okamura、Sang-Won Kim

  DOI：10.1055/s-1997-806

  日期：1997.4

  Reaction of 1,4-cyclohexanedione with a variety of aldehydes in the presence of metal halides generated the 2-alkylated 1,4-benzenediols in good yields without any aromatic by-products.

  在金属卤化物的存在下，1,4-环己二酮与多种醛反应，以良好的产率生成了2-烷基化的1,4-苯二酚，没有任何芳香副产物。
• Cell-Surface Engineering by a Conjugation-and-Release Approach Based on the Formation and Cleavage of Oxime Linkages upon Mild Electrochemical Oxidation and Reduction
  作者：Abigail Pulsipher、Debjit Dutta、Wei Luo、Muhammad N. Yousaf

  DOI：10.1002/anie.201404099

  日期：2014.9.1

  We report a strategy to rewire cell surfaces for the dynamic control of ligand composition on cell membranes and the modulation of cell–cell interactions to generate three‐dimensional (3D) tissue structures applied to stem‐cell differentiation, cell‐surface tailoring, and tissue engineering. We tailored cell surfaces with bioorthogonal chemical groups on the basis of a liposome‐fusion and ‐delivery

  我们报告了一种重新连接细胞表面的策略，用于动态控制细胞膜上的配体组成以及调节细胞间相互作用，从而生成应用于干细胞分化，细胞表面剪裁和组织的三维（3D）组织结构工程。我们基于脂质体融合和递送方法，通过生物正交化学基团对细胞表面进行剪裁，以通过涉及化学选择性缀合和释放的化学方法创建动态，电活性和可切换的细胞组织组装体。可以通过无创，无标签的分析技术来监控和调节修饰细胞表面的每个步骤：激活，缀合，释放和再生。
• Image bearing member, method of manufacturing the same, image formation method, image forming apparatus and process cartridge
  申请人：Nagai Kazukiyo

  公开号：US20080304867A1

  公开（公告）日：2008-12-11

  An image bearing member including an electroconductive substrate, a photosensitive layer located overlying the electroconductive substrate and a cross linking surface layer comprising a charge transport curing compound and located overlying the photosensitive layer, wherein the charge transport curing compound includes a material including a structure unit represented by the following Chemical formula A: Chemical formula A where R 1 to R 5 and R 1 ′ to R 5 ′ independently represent a hydrogen atom, an alkyl group having 1 to 4 carbon atoms or an alkoxy group having 1 to 4 carbon atoms, R 6 represents a hydrogen atom or a methyl group and X represents an alkylene group having a straight chain or a branched chain having 2 to 5 carbon atoms.

  一种图像承载成员，包括导电基底、位于导电基底上方的感光层和包括电荷传输固化化合物、位于感光层上方的交联表面层，其中电荷传输固化化合物包括一种材料，该材料包括以下化学式A所表示的结构单元： 化学式A 其中R1至R5和R1'至R5'独立地表示氢原子、具有1至4个碳原子的烷基或具有1至4个碳原子的烷氧基，R6表示氢原子或甲基基团，X表示具有2至5个碳原子的直链或支链烷基。
• ACRYLIC ESTER COMPOUND AND MANUFACTURING INTERMEDIATE THEREOF, METHOD FOR MANUFACTURING ACRYLIC ESTER COMPOUND, AND LATENT ELECTROSTATIC IMAGE BEARING MEMBER, IMAGE FORMING METHOD, IMAGE FORMING APPARATUS AND PROCESS CARTRIDGE
  申请人：HORIUCHI Tamotsu

  公开号：US20110287353A1

  公开（公告）日：2011-11-24

  To provide: a latent electrostatic image bearing member including one of a cured material obtained through radical polymerization of a radically polymerizable compound of component (A1), and a cured material obtained through radical polymerization of a radically polymerizable compound of component (A2) in the outermost layer, wherein the component (A1) includes two radically polymerizable groups and a substituted amino group which does not include a radically polymerizable group in a molecule, and the radically polymerizable group and the nearest substituted amino group which does not include an unsaturated bond in between are connected with two or more aromatic hydrocarbon compounds, and, the radically polymerizable compound of component (A2) includes a condensed polycyclic aromatic hydrocarbon formed by bonding a radically polymerizable group and a non-radically polymerizable substituted amine group through a condensed polycyclic aromatic hydrocarbon group; and an image forming apparatus, image forming method and process cartridge which uses thereof.

  提供一种潜在的静电图像承载成员，包括通过组分（A1）的自由基聚合获得的固化材料之一，以及在最外层通过组分（A2）的自由基聚合获得的固化材料，其中组分（A1）包括两个自由基聚合基团和一个分子中不包含自由基聚合基团的取代氨基团，并且最近的不包含不饱和键的取代氨基团与自由基聚合基团之间连接有两个或更多芳香族碳氢化合物，而组分（A2）的自由基聚合化合物包括通过连接一个自由基聚合基团和一个非自由基聚合取代胺基团的环状多环芳香族碳氢化合物形成的缩聚多环芳香族碳氢化合物；以及使用该承载成员的图像形成设备、图像形成方法和处理盒。
• Photographic recording material containing polymers which coordinate with metal ions
  申请人：EASTMAN KODAK COMPANY (a New Jersey corporation)

  公开号：EP0009411A2

  公开（公告）日：1980-04-02

  Photographic recording material containing polymers which coordinate with metal ions, complexes produced thereby and novel polymers are disclosed. The recording material comprises a support, a photosensitive silver halide emulsion layer, an image dye or dye-forming material and a layer containing a dye mordant. The mordant layer has associated therewith a source of metal ions and a polymer which is capable of forming a complex with metal ions. The complex provides improved light stability to image dyes. The image dyes are preferably dye ligands or dye ligand forming materials.

  本发明公开了含有与金属离子配位的聚合物的照相记录材料、由此产生的络合物和新型聚合物。 记录材料包括一个支架、一个感光卤化银乳剂层、一种图像染料或染料形成材料和一个含有染料媒染剂的层。 媒染剂层与金属离子源和一种能够与金属离子形成络合物的聚合物相关联。 络合物为图像染料提供更好的光稳定性。 图像染料最好是染料配体或染料配体形成材料。