1-(4-hydroxymethylphenyl)-3,3-dimethyltriazene

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-(4-hydroxymethylphenyl)-3,3-dimethyltriazene
• 英文别名: [4-(3,3-dimethyltriaz-1-enyl)phenyl]methanol；p-Dimethylaminoazobenzyl alcohol；[4-(dimethylaminodiazenyl)phenyl]methanol
• 化学式: C₉H₁₃N₃O
• 分子量: 179.222
• InChiKey: ZLVSQUFFQBYFOW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1
• 重原子数：
  13
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  48.2
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  对氨基苯甲醇 、 二甲胺 在 盐酸 、 sodium nitrite 作用下， 以 水 为溶剂， 反应 0.25h， 以88%的产率得到1-(4-hydroxymethylphenyl)-3,3-dimethyltriazene
  参考文献：
  名称：

  Manolov, Ilia; Machulla; Momekov, Pharmazie, 2006, vol. 61, # 6, p. 511 - 516

  摘要：

  DOI：

文献信息

• Manolov, Ilia; Machulla; Momekov, Pharmazie, 2006, vol. 61, # 6, p. 511 - 516
  作者：Manolov, Ilia、Machulla、Momekov

  DOI：——

  日期：——
• Combining Aryltriazenes and Electrogenerated Acids To Create Well-Defined Aryl-Tethered Films and Patterns on Surfaces
  作者：Mikkel Kongsfelt、Jesper Vinther、Kristoffer Malmos、Marcel Ceccato、Kristian Torbensen、Cindy S. Knudsen、Kurt V. Gothelf、Steen Uttrup Pedersen、Kim Daasbjerg

  DOI：10.1021/ja111731d

  日期：2011.3.23

  Immobilization of submonolayers to 4-5 multilayers of organic molecules on carbon surfaces can be performed by in situ generation of aryl radicals from aryltriazenes. The central idea consists of oxidatively forming an electrogenerated acid of N,N'-diphenylhydrazine to convert the aryltriazene to the corresponding diazonium salt in the diffusion layer of the electrode. In a second step, the diazonium salt is reduced at the same electrode to give a surface of covalently attached aryl groups. In this manner, various moieties tethered to the aryl groups can be immobilized on the surface. Here a ferrocenyl group was introduced as redox marker, the electrochemical signal of which is extraordinarily well-defined. This behavior is independent of film thickness, the latter being easily controlled by the number of repetitive cycles performed. It is also demonstrated that the new approach is suitable for patterning of surfaces using scanning electrochemical microscopy.