3,3'-二甲基-[1,1'-联苯基]-2-醇 | 78210-32-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 3,3'-二甲基-[1,1'-联苯基]-2-醇
• 英文名称: 2-hydroxy-3,3'-dimethylbiphenyl
• 英文别名: 3,3'-dimethyl-[1,1'-biphenyl]-2-ol；2-Methyl-6-(3-methylphenyl)phenol
• CAS: 78210-32-9
• 化学式: C₁₄H₁₄O
• 分子量: 198.265
• InChiKey: UYXNJZZGNFQPTJ-UHFFFAOYSA-N

物化性质

• 沸点：
  142 °C(Press: 9 Torr)
• 密度：
  1.067±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  15
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  4,6-二甲基-二苯并呋喃 以70%的产率得到
  参考文献：
  名称：

  KEUMI TAKASHI; MURATA CHOZO; SASAKI YASUTO; OGASAWARA KOZO; KITAJIMA HIDE+, NIXON KAGAKU KAJSI, NIRRON KAGAKU KAISNI, J. CHEM. SOS. JAR., CHEM. AND I+

  摘要：

  DOI：

文献信息

• [EN] HYDROCARBON RECOVERY FROM SULFONES FORMED BY OXIDATIVE DESULFURIZATION PROCESS<br/>[FR] RÉCUPÉRATION D'HYDROCARBURES ISSUS DE SULFONES FORMÉES PAR UN PROCESSUS DE DÉSULFURATION OXYDATIVE
  申请人：SAUDI ARABIAN OIL CO

  公开号：WO2011056941A1

  公开（公告）日：2011-05-12

  The process provided herein is concerned with recovery of hydrocarbons from sulfones using an individual alkali and alkaline-earthy base and a mixture of thereof. As the starting materials are sulfones generated by ODS and commercially inexpensive alkali and alkaline-earth bases, the cost and ecological impact of solid waste disposal is minimized.

  本过程涉及使用单一碱性和碱性-地碱性基和其混合物从磺酮中回收烃类。由于起始材料是由ODS生成的磺酮和商业廉价的碱性和碱性-地碱性基，因此固体废物处理的成本和生态影响得到了最小化。
• Silylations of aromatic substrates with base-activated organosilanes
  申请人：CALIFORNIA INSTITUTE OF TECHNOLOGY

  公开号：US10927065B2

  公开（公告）日：2021-02-23

  The present disclosure describes methods for silylating aromatic organic substrates, and associated chemical systems, said methods comprising or consisting essentially of contacting the aromatic organic substrate with a mixture of (a) at least one organosilane and (b) at least one strong base, under conditions sufficient to silylate the aromatic substrate.

  本公开描述了使芳香族有机基质硅烷化的方法及相关化学体系，所述方法包括或主要包括在足以使芳香族基质硅烷化的条件下，使芳香族有机基质与(a)至少一种有机硅烷和(b)至少一种强碱的混合物接触。
• KEUMI TAKASHI; MURATA CHOZO; SASAKI YASUTO; OGASAWARA KOZO; KITAJIMA HIDE+, NIXON KAGAKU KAJSI, NIRRON KAGAKU KAISNI, J. CHEM. SOS. JAR., CHEM. AND I+
  作者：KEUMI TAKASHI、 MURATA CHOZO、 SASAKI YASUTO、 OGASAWARA KOZO、 KITAJIMA HIDE+

  DOI：——

  日期：——
• HYDROCARBON RECOVERY FROM SULFONES FORMED BY OXIDATIVE DESULFURIZATION PROCESS
  申请人：Saudi Arabian Oil Company

  公开号：EP2496538A1

  公开（公告）日：2012-09-12
• ONE-POT PROCESS FOR THE REDUCTION OF SULFUR, NITROGEN AND THE PRODUCTION OF USEFUL OXYGENATES FROM HYDROCARBON MATERIALS VIA ONE-POT SELECTIVE OXIDATION
  申请人：YOO Jin S.

  公开号：US20080149533A1

  公开（公告）日：2008-06-26

  The present invention relates to a process of reducing sulfur- or nitrogen-containing compounds and producing oxygenates, and in particular to a one-pot process of reducing sulfur- or nitrogen-containing compounds and also producing oxygenates in the presence of a homogeneous catalyst such as M n+ /a first solvent or M 1 n+ /a second solvent/M 2 m+ /a third solvent or a mixture thereof, the process herein being useful as an excellent octane booster in the reformulated gasoline and as a cetane booster for the future oxygenated diesel in a one-pot reaction.