2,6-Dinitro-3-methylphenol | 603-03-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2,6-Dinitro-3-methylphenol
• 英文别名: 2.4-dinitro-3-hydroxy-toluene；2.4-Dinitro-3-hydroxy-toluol；2.4-Dinitro-3-oxy-1-methyl-benzol；2.6-Dinitro-m-kresol；2,6-dinitro-m-cresol；2,4-dinitrocresol；3-Methyl-2,6-dinitrophenol
• CAS: 603-03-2
• 化学式: C₇H₆N₂O₅
• 分子量: 198.135
• InChiKey: RXUSMLCMOQWNOQ-UHFFFAOYSA-N

物化性质

• 熔点：
  74 °C
• 沸点：
  266.7±35.0 °C(Predicted)
• 密度：
  1.550±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  14
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.14
• 拓扑面积：
  112
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  2,6-Dinitro-3-methylphenol 生成 3-methyl-2,6-dinitro-anisole
  参考文献：
  名称：

  Gornall; Robinson, Journal of the Chemical Society, 1926, p. 1984

  摘要：

  DOI：
• 作为产物：
  描述：

  1-甲基-2,3,4-三硝基苯 在 sodium acetate 作用下， 生成 2,6-Dinitro-3-methylphenol
  参考文献：
  名称：

  Brady; Hewetson; Klein, Journal of the Chemical Society, 1924, vol. 125, p. 2403

  摘要：

  DOI：

文献信息

• USE OF QUINONE METHIDES AS ANTIPOLYMERANTS FOR VINYLIC MONOMERS
  申请人：Ecolab USA Inc.

  公开号：US20160289147A1

  公开（公告）日：2016-10-06

  The present invention generally relates to compounds and methods for inhibiting the radical polymerization of unsaturated compounds, particularly vinyl monomers. More particularly, it relates to the use of cinnamyl quinone methides to inhibit the polymerization of unsaturated hydrocarbon compounds (e.g., vinyl monomers) soluble in organic solvents, particularly hydrocarbon streams.

  本发明通常涉及化合物和方法，用于抑制不饱和化合物的自由基聚合，特别是乙烯单体。更具体地说，它涉及使用肉桂基喹喙甲醚来抑制可溶于有机溶剂，特别是烃流中的不饱和碳氢化合物（例如乙烯单体）的聚合。
• [EN] AMINO-QUINONE ANTIPOLYMERANTS AND METHODS OF USING<br/>[FR] AGENT D'ANTIPOLYMÉRISATION À BASE D'AMINO-QUINONE ET PROCÉDÉS D'UTILISATION
  申请人：ECOLAB USA INC

  公开号：WO2020068735A1

  公开（公告）日：2020-04-02

  Described are methods and composition for inhibiting polymerization of a monomer (e.g., styrene) composition using an aminated quinone antipolymerant, such as an aminated benzoquinone or aminated naphthoquinone antipolymerant having one or more secondary or tertiary amine group(s). The aminated quinone antipolymerant can be used with little or no nitroxyl group containing antipolymerant yet still provide excellent antipolymerant activity in a monomer-containing composition.

  描述了一种使用氨基喹诺烷抗聚合剂（例如，氨基苯醌或氨基萘醌抗聚合剂）来抑制单体（例如苯乙烯）组合物的聚合的方法和组合物，该氨基喹诺烷抗聚合剂具有一个或多个次级或三级胺基团。氨基喹诺烷抗聚合剂可以与几乎不含氮氧自由基的抗聚合剂一起使用，但仍然在含单体组合物中提供出色的抗聚合活性。
• [EN] QUINONE METHIDE AND AMMONIUM SALT ANTIPOLYMERANT COMPOSITION AND METHOD<br/>[FR] COMPOSITION D'ANTI-POLYMÈRE DE MÉTHIDE DE QUINONE ET DE SEL D'AMMONIUM, ET PROCÉDÉ
  申请人：ECOLAB USA INC

  公开号：WO2021072181A1

  公开（公告）日：2021-04-15

  Described are compositions and methods for inhibiting polymerization of a monomer (e.g., styrene) composition a quinone methide polymerization retarder and an ammonium salt. In a mixture, the ammonium salt improves the efficacy of the quinone methide polymerization retarder and provides greater antipolymerant activity. In turn, the mixture reduces or prevents apparatus fouling and improves the purity of monomer streams.

  本文描述了一种抑制单体（例如苯乙烯）聚合的组合物和方法，该组合物包括醌甲醛聚合抑制剂和铵盐。在混合物中，铵盐提高了醌甲醛聚合抑制剂的功效，并提供了更强的抗聚合活性。反过来，该混合物减少或预防设备污染，并提高单体流的纯度。
• SYNTHESIS OF 7-ACETYLENO QUINONE METHIDE DERIVATIVES AND THEIR APPLICATION AS VINYLIC POLYMERIZATION RETARDERS
  申请人：Masere Jonathan

  公开号：US20120313036A1

  公开（公告）日：2012-12-13

  The invention provides a method for synthesizing 7-Acetyleno quinone methide compounds that is safe and inexpensive. The method avoids the need for extremely cold reaction temperatures and unlike the prior art does not require any highly explosive materials. The method comprises the steps of a) performing a condensation reaction between 3,5-di-tert-butyl-4-hydroxybenzaldehyde and a secondary amine thereby forming a secondary amine quinone methide intermediate; b) removing water from the secondary amine quinone methide intermediate by azeotropic distillation; c) adding the dehydrated secondary amine quinone methide intermediate to an organic medium containing a metal acetylide to form a Mannich base intermediate; and d) adding a release agent to the Mannich base intermediate to yield a 7-Acetyleno quinone methide.

  本发明提供了一种安全、廉价的合成7-乙炔基喹啉甲醇化合物的方法。该方法避免了需要极低的反应温度，不像先前的技术需要任何高度爆炸性的材料。该方法包括以下步骤：a）在3,5-二叔丁基-4-羟基苯甲醛和二级胺之间进行缩合反应，从而形成二级胺喹啉甲醇中间体；b）通过共沸蒸馏去除二级胺喹啉甲醇中间体中的水分；c）将脱水的二级胺喹啉甲醇中间体加入含有金属乙炔基的有机介质中，形成曼尼希碱中间体；d）向曼尼希碱中间体中加入释放剂，得到7-乙炔基喹啉甲醇。
• Refining of tertiary butylstyrene
  申请人：EL PASO PRODUCTS COMPANY (A Delaware Corporation)

  公开号：EP0186269A1

  公开（公告）日：1986-07-02

  Dialkenylbenzene compounds, present in t-butylstyrene in small quantities as impurities, are removed by liquid/liquid extraction using aqueous sulfolane as solvent.

  使用水性磺烷作为溶剂，通过液/液萃取法去除少量存在于叔丁基苯乙烯中的杂质二烯丙基苯化合物。