1,2-dimethoxyethane;triiodolanthanum | 186413-30-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 1,2-dimethoxyethane;triiodolanthanum
• CAS: 186413-30-9
• 化学式: C₈H₂₀I₃LaO₄
• 分子量: 699.863
• InChiKey: DSGAGSBHMCKQJS-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  S-1,1'-联-2-萘酚 、 1,2-dimethoxyethane;triiodolanthanum 在 potassium hydride 作用下， 以 四氢呋喃 为溶剂， 以85%的产率得到[(R)-1,1'-(bis-2,2'-naphthoxide)]-iodolanthane-bis-tetrahydrofurane
  参考文献：
  名称：

  (R)-bis-Binaphthoxy iodo lanthanides as catalysts for Diels–Alder reactions

  摘要：

  [(R)-1,1'bi-2,2'-Naphthoxy]LnI(THF)(2) (Ln: Yb, Sm, La) 5 have been prepared by reaction of the bispotassium salt. of (R)-binaphthol with lanthanide triiodides, and characterized. They are active catalysts for Diels-Alder reactions although with low asymmetric inductions. The lanthanum iodo bisbinaphthoxide gives a slightly higher enantiomeric excess than the two other complexes. (C) 2003 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1381-1169(03)00092-x

文献信息

• Iodo bis bistrimethylsilylamido lanthanides
  作者：Jacqueline Collin、Nicolas Giuseppone、Nada Jaber、Angela Domingos、Leonor Maria、Isabel Santos

  DOI：10.1016/s0022-328x(01)00793-8

  日期：2001.5

  Reactions of lanthanide triiodides with potassium bistrimethylsilyl amide have been investigated. For lanthanum, recrystallisation from THF-toluene led to monocrystals of the dimeric bisamide [La(mu -I)N(TMS)(2))(2)(THF)](2). We have shown that samarium diiodide and lanthanide triiodides are efficient for lanthanum and samarium reactions, a mixture of tris amides and iodo bisamides is obtained, while only the latter compound is obtained for ytterbium. (C) 2001 Elsevier Science B.V. All rights reserved.