naphtho[2,3-f]pentathiepin

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: naphtho[2,3-f]pentathiepin
• 英文别名: Benzo[h][1,2,3,4,5]benzopentathiepine
• 化学式: C₁₀H₆S₅
• 分子量: 286.488
• InChiKey: FHDJIBQBRJBBJJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  15
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  127
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为产物：
  描述：

  2-萘硫醇 在 氨 、 sulfur 作用下， 以 二氯甲烷 为溶剂， 生成 naphtho[2,3-f]pentathiepin
  参考文献：
  名称：

  Cyclic polysulfides fused to polyaromatics

  摘要：

  Pentathiepins fused to naphthalene and phenanthrene have been synthesized by a simple method. Ring size depends on the stability of generated products related to steric and electronic factors. Sometimes, delocalized pi-electron of polyarornatics shows synergistic effect on the stabilization of polysulfur rings. The structures of two polysulfides were also studied by X-ray crystallography and phenanthrene bearing C2S5 ring showed different solid-state properties than corresponding phenanthrene bearing C2S3 ring. (c) 2006 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2006.11.026