hexadecamethylhexasilane | 812-53-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: hexadecamethylhexasilane
• 英文别名: permethylhexasilane；Tetradecamethyl-hexasilan；Hexasilane, tetradecamethyl-；[dimethyl(trimethylsilyl)silyl]-[[dimethyl(trimethylsilyl)silyl]-dimethylsilyl]-dimethylsilane
• CAS: 812-53-3
• 化学式: C₁₄H₄₂Si₆
• 分子量: 379.0
• InChiKey: MYVYLCKNQVLMQO-UHFFFAOYSA-N

物化性质

• 熔点：
  28 °C
• 沸点：
  125-128 °C(Press: 1 Torr)
• 密度：
  0.799±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.89
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  hexadecamethylhexasilane 在 三氯化铝 作用下， 以 苯 为溶剂， 生成 1,1,1-tris(trimethylsilyl)-2,2,3,3,3-pentamethyltrisilane
  参考文献：
  名称：

  氯化铝催化全甲基化线性聚硅烷的骨架重排

  摘要：

  在沸腾的苯中存在氯化铝的情况下，全甲基化的线性聚硅烷Me（Me 2 Si）n Me非常容易发生骨架重排，形成支链异构体。

  DOI：

  10.1039/c2970000157a
• 作为产物：
  描述：

  十二甲基环己硅烷 在 五氯化磷 作用下， 以 四氯化碳 、 乙醚 、 正己烷 为溶剂， 反应 24.0h， 生成 hexadecamethylhexasilane
  参考文献：
  名称：

  Sun, Ya-Ping; Michl, Josef, Journal of the American Chemical Society, 1992, vol. 114, # 21, p. 8186 - 8191

  摘要：

  DOI：

文献信息

• Photolysis of permethylated linear polysilanes
  作者：Mitsuo Ishikawa、Tadahiko Takaoka、Makoto Kumada

  DOI：10.1016/s0022-328x(00)90082-2

  日期：1972.9

  The UV photolysis of teh permethylated linear polysilanes Me(Me2Si)nMe (I), with n = 4 to 8, in cyclohexane at, or al little above, room temperature has been found to proceed simultaneously by two different routes, one of these involves contraction of the chain with loss of dimethylsilylene species to produce octamethyltrisilane which was usually very resistant to the photolysis), while the other comprises

  发现n = 4至8的全甲基化线性聚硅烷Me（Me 2 Si）n Me（I）在环己烷中或略高于室温下的紫外光解反应通过两种不同的途径同时进行其中包括链的收缩和二甲基甲硅烷基物质的损失，从而产生通常对光解非常抗性的八甲基三硅烷），而另一种则包括对硅键的均裂，随后氢原子被形成的甲硅烷基基团夺取而形成。 1小时-聚甲基聚硅烷。从（I）在二乙基甲基硅烷中的光解表明，均相的程度随（I）链长的增加而增加，而二甲基亚甲硅烷基物质的有效产率几乎恒定，而与该链长无关。没有证据表明将光化学生成的二甲基甲硅烷基插入硅硅键中。
• The preparation of several permethylated linear polysilanes. From octasilane to dodecasilane
  作者：Makoto Kumada、Mitsuo Ishikawa、Sajiro Maeda

  DOI：10.1016/s0022-328x(00)93628-3

  日期：1966.2

  Five new permethylated linear polysilanes of the formula CH3[Si(CH3)2]nCH3, where n is equal to 8, 9, 10, 11 and 12, have been prepared from the co-condensation of appropriate chlorosilanes using sodium-potassium alloy as condensing agent in a benzene-ligroin or benzene-n-heptane mixture. These compounds are all white crystalline substances. The melting points display a regular progression as the number

  由合适的氯硅烷与钠共缩合，制备了五种新的式CH 3 [Si（CH 3）2 ] n CH 3的全甲基化线性聚硅烷，其中n等于8、9、10、11和12。 -钾合金作为苯-古丁胶或苯-正庚烷混合物中的缩合剂。这些化合物都是白色结晶物质。熔点随着硅原子数量的增加而显示出规律的变化，这与该系列化合物的奇数和偶数结构的熔点交替出现的较低同系物的熔点形成了鲜明的对比。
• Aluminium chloride-catalysed skeletal rearrangement of permethylated linear polysilanes
  作者：M. Ishikawa、M. Kumada

  DOI：10.1039/c2970000157a

  日期：——

  Permethylated linear polysilanes, Me(Me2Si)nMe undergo skeletal rearrangement to branched-chain isomers very easily in the presence of aluminium chloride in boiling benzene.

  在沸腾的苯中存在氯化铝的情况下，全甲基化的线性聚硅烷Me（Me 2 Si）n Me非常容易发生骨架重排，形成支链异构体。
• Palladium-catalyzed insertion of isocyanides into the silicon-silicon linkages of oligosilanes
  作者：Yoshihiko Ito、Michinori Suginome、Takaharu Matsuura、Masahiro Murakami

  DOI：10.1021/ja00023a043

  日期：1991.11

  Full details of a study on the reactions of oligosilanes with isocyanides promoted by a palladium catalyst are described. Heating a mixture of oligosilanes and excess 2,6-disubstituted aryl isocyanide in the presence of palladium(II) acetate led to the complete insertion of isocyanide into all silicon-silicon linkages, giving oligo(silylimine) derivatives. The oligo(silylimine)s have been isolated and characterized so far in the complete insertion reaction with oligosilanes up to a hexasilane. Use of the limiting amount of isocyanide permitted insertion of isocyanide into predominantly the terminal silicon-silicon linkages. The mode of the insertion reaction depends on the substituent at the silicon, e.g., tetrasilanes with phenyl groups on the internal silicon atoms favorably underwent the insertion reaction at the terminal silicon-silicon linkages, resulting in the partial insertion. The bulkiness of the ortho substituents on the aromatic isocyanide was also found to have much influence on the insertion; hence, 2,6-diisopropylphenyl isocyanide favored the partial insertion. New skeletal rearrangement of oligosilanes took place in a palladium-catalyzed reaction of substituted aryl isocyanide with tetra- and hexasilanes, forming 3,3-bis(silyl)-l-aza-2, 4-disilacyclobutane derivatives. The rearrangement, which is unique and intriguing in that the product is properly reconstituted from four fragments of the tetrasilane and two fragments of the isocyanide, was promoted in the copresence of a tert-alkyl isocyanide.
• ISHIKAWA MITSUO; IYODA JUN; IKEDA HARUHIKO; KOTAKE KAZUNORI; HASHIMOTO TO+, J. AMER. CHEM. SOC., 1981, 103, NO 16, 4845-4850
  作者：ISHIKAWA MITSUO、 IYODA JUN、 IKEDA HARUHIKO、 KOTAKE KAZUNORI、 HASHIMOTO TO+

  DOI：——

  日期：——