Ni(thiodiacetate)(H2O)3 | 50858-84-9

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 亚磺酸及其衍生物
• 英文名称: Ni(thiodiacetate)(H2O)3
• 英文别名: [Ni(thiodiglycolate(2-))(H2O)3]
• CAS: 50858-84-9；31542-05-9；36443-43-3
• 化学式: C₄H₁₀NiO₇S
• 分子量: 260.875
• InChiKey: CNGXAUKVUYXXMT-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  Ni(thiodiacetate)(H2O)3 、 1,8-二氨基萘 以 乙醇 、 水 为溶剂， 以70%的产率得到[Ni(1,8-diaminonaphthalene)(thiodiglycolate(2-))(H2O)]
  参考文献：
  名称：

  Syntheses and study on nickel(II) complexes with thiodiglycolic acid and nitrogen-donor ligands. X-ray structures of [Ni(bpy)(tdga)(H2O)] · 4H2O and [(en)Ni(μ-tdga)2Ni(en)] · 4H2O (tdgaH2=thiodiglycolic acid)

  摘要：

  Mixed-ligand Ni(II) complexes involving thiodiglycolate(2-) anion (tdga) and nitrogen-donor ligands in the coordination sphere have been prepared. The complexes of composition [Ni(bpy)(tdga)(H2O)].4H(2)O (1), [(en)Ni(mu-tdga)(2)Ni(en)].4H(2)O (2), [Ni(phen)(tdga)(H2O)] (3), [Ni(1,8-dan)(tdga)(H2O)] (4), [Ni(nphen)(tdga)(H2O)].H2O (5), [Ni(ampy)(tdga)(H2O)] (6), where bpy = 2,2'-bipyridine,en = ethylenediamine,phen = 1,10-phenanthroline, 1,8-dan = 1,8-diaminonaphthalene, nphen = 5-nitro-1,10-phenanthroline and ampy = 2-(aminomethyl)-pyridine, have been characterized by elemental analysis, IR and UV-Vis spectroscopies, and magnetic susceptibility measurements. Room temperature effective magnetic moments for 1-6 are ranging from 3.06 to 3.28 mu(eff)/mu(B). and thus indicating that nickel atoms are six-coordinated in a deformed octahedral arrangement in all the prepared complexes. This conclusion has been confirmed by single-crystal X-ray analysis of [Ni(bpy)(tdga)(H2O)].4H(2)O (1). A binuclear structure of complex [(en)Ni(mu-tdga)(2)Ni(en)].4H(2)O (2) has been anticipated in connection with study of its magnetic properties over the 1.8-300 K temperature range (J = 4.35 cm(-1), D = 5.53 cm(-1), zJ = -0.94 cm(-1) for g = 2.00) and unambiguously proved by a single-crystal X-ray analysis. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.03.005
• 作为产物：
  描述：

  basic nickel carbonate tetrahydrate 、 硫代二乙酸 、 水 以 水 为溶剂， 以68%的产率得到Ni(thiodiacetate)(H2O)3
  参考文献：
  名称：

  Syntheses and study on nickel(II) complexes with thiodiglycolic acid and nitrogen-donor ligands. X-ray structures of [Ni(bpy)(tdga)(H2O)] · 4H2O and [(en)Ni(μ-tdga)2Ni(en)] · 4H2O (tdgaH2=thiodiglycolic acid)

  摘要：

  Mixed-ligand Ni(II) complexes involving thiodiglycolate(2-) anion (tdga) and nitrogen-donor ligands in the coordination sphere have been prepared. The complexes of composition [Ni(bpy)(tdga)(H2O)].4H(2)O (1), [(en)Ni(mu-tdga)(2)Ni(en)].4H(2)O (2), [Ni(phen)(tdga)(H2O)] (3), [Ni(1,8-dan)(tdga)(H2O)] (4), [Ni(nphen)(tdga)(H2O)].H2O (5), [Ni(ampy)(tdga)(H2O)] (6), where bpy = 2,2'-bipyridine,en = ethylenediamine,phen = 1,10-phenanthroline, 1,8-dan = 1,8-diaminonaphthalene, nphen = 5-nitro-1,10-phenanthroline and ampy = 2-(aminomethyl)-pyridine, have been characterized by elemental analysis, IR and UV-Vis spectroscopies, and magnetic susceptibility measurements. Room temperature effective magnetic moments for 1-6 are ranging from 3.06 to 3.28 mu(eff)/mu(B). and thus indicating that nickel atoms are six-coordinated in a deformed octahedral arrangement in all the prepared complexes. This conclusion has been confirmed by single-crystal X-ray analysis of [Ni(bpy)(tdga)(H2O)].4H(2)O (1). A binuclear structure of complex [(en)Ni(mu-tdga)(2)Ni(en)].4H(2)O (2) has been anticipated in connection with study of its magnetic properties over the 1.8-300 K temperature range (J = 4.35 cm(-1), D = 5.53 cm(-1), zJ = -0.94 cm(-1) for g = 2.00) and unambiguously proved by a single-crystal X-ray analysis. (C) 2004 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2004.03.005

文献信息

• Structural correlations in nickel(II)–thiodiacetato complexes: molecular and crystal structures and properties of [Ni(tda)(H2O)3]
  作者：C. Alarcón-Payer、T. Pivetta、D. Choquesillo-Lazarte、J.M. González-Pérez、G. Crisponi、A. Castiñeiras、J. Niclós-Gutiérrez

  DOI：10.1016/j.inoche.2004.10.008

  日期：2004.12

  Abstract Triaqua(thiodiacetato)nickel(II) has been synthesized and studied by X-ray crystallography, thermal, spectral and magnetic methods. The compound crystallizes in the triclinic system, space group P 1 ¯ , in contrast to the related compound [Ni(tda)(H2O)3] · H2O (orthorhombic) reported long time ago. As in other four Ni–tda derivatives, the metal atom exhibits an octahedral coordination and

  摘要 Triaqua(thiodiacetato)nickel(II) 已通过 X 射线晶体学、热、光谱和磁性方法合成和研究。该化合物在三斜晶系，空间群 P 1 ¯ 中结晶，与很久以前报道的相关化合物 [Ni(tda)(H2O)3] · （斜方晶系）形成对比。与其他四种 Ni-tda 衍生物一样，金属原子呈现八面体配位，tda 配体采用 fac-三齿螯合作用。研究的化合物与[Zn(tda)( )3]密切相关。此外，二元和三元 Ni-tda 衍生物的结构比较表明，辅助 N 供体配体使用向 Ni-O（羧基）键的转位结合金属原子，但不与 Ni-S 反式结合(硫醚)键。
• Antibacterial study on nickel and copper dicarboxylate complexes
  作者：Ivana Loubalová、Eva Zahradníková、Lukáš Masaryk、Ivan Nemec、Lucie Hochvaldová、Aleš Panáček、Libor Kvítek、Renata Večeřová、Marcin Świątkowski、Pavel Kopel

  DOI：10.1016/j.ica.2022.121273

  日期：2023.1