甲烷亚磺酰氟化物 | 56755-41-0

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 亚磺酸及其衍生物
• 中文名称: 甲烷亚磺酰氟化物
• 英文名称: Methanesulphinyl fluoride
• 英文别名: Methansulfinsaeure-fluorid；Methansulfinylfluorid；Methylsulfinylfluorid；Methanesulfinyl fluoride
• CAS: 56755-41-0
• 化学式: CH₃FOS
• 分子量: 82.0986
• InChiKey: GWNPPHYEJITOHT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.1
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.3
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  Methylsulfur trifluoride 、 丙酮 以 一氟三氯甲烷 为溶剂， 生成 2,2-二氟丙烷 、 甲烷亚磺酰氟化物
  参考文献：
  名称：

  Synthesis, physical characterisation and chemical properties of methylsulphur trifluoride, CH3SF3

  摘要：

  Methylsulphur trifluoride, CH3SF3, has been synthesised by the reaction between AgF2 and a solution of CH3SCl in CCl3F. It is a clear, viscous liquid which attacks glass, is hydrolysed rapidly, and decomposes at ambient temperatures to give CH2FSF3 and CH2FSSCH2F. The compound has been characterised by its H-1 and F-19 NMR and vibrational spectra, and a partial vibrational assignment is proposed. The chemistry of CH3SF3 is akin to that of SF4. Thus, it functions as a fluoride ion donor much more readily than as a fluoride ion acceptor. It reacts with Pyrex glass to give CH3S(O)F, is hydrolysed to CH3S(O)OH, and effects O-F exchange with acetone to yield 2,2-difluoropropane.

  DOI：

  10.1039/dt9910000081

文献信息

• Dehydrogenative Cycloisomerization/Arylation Sequence of <i>N</i> ‐Propargyl Carboxamides with Arenes by Iodine(III)‐Catalysis
  作者：Yuki Umakoshi、Yusuke Takemoto、Akira Tsubouchi、Viktor V. Zhdankin、Akira Yoshimura、Akio Saito

  DOI：10.1002/adsc.202200219

  日期：2022.6.21

  provides a facile and powerful approach to C−C bond formation between the generated heterocycles and unfunctionalized arenes. Here, we describe a hypervalent iodine(III)-catalyzed synthesis of oxazoles concomitant with the introduction of aryl groups into side chain from N-propargyl carboxamides and arenes, representing first C(sp3)−C(sp2) bond formation by the catalytic dehydrogenative cycloisomerization/arylation

  杂原子亲核试剂束缚的未活化炔烃的脱氢环异构化/芳基化序列为生成的杂环和未官能化芳烃之间的 C-C 键形成提供了一种简便而有效的方法。在这里，我们描述了一种高价碘（III）催化的恶唑合成，同时将芳基引入N-炔丙基甲酰胺和芳烃的侧链，代表第一个 C( sp 3 )-C( sp 2 ) 键形成exo-dig模式下的催化脱氢环异构化/芳基化反应。