Dithiobenzoesaeure-n-propylester | 27249-63-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Dithiobenzoesaeure-n-propylester
• 英文别名: Thiobenzoesaeure-propylthioester；Propyldithiobenzoat；propyl dithiobenzoate；Benzenecarbodithioic acid, propyl ester；propyl benzenecarbodithioate
• CAS: 27249-63-4
• 化学式: C₁₀H₁₂S₂
• 分子量: 196.337
• InChiKey: IRIVASWWWGVFNW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  57.4
• 氢给体数：
  0
• 氢受体数：
  2

安全信息

• 海关编码：
  2930909090

反应信息

• 作为产物：
  描述：

  溴丙烷 以42%的产率得到
  参考文献：
  名称：

  CAIRON, P.;LABIAD, B.;VILLEMIN, D., EUR. POLYM. J., 24,(1988) N 7, C. 697-698

  摘要：

  DOI：

文献信息

• Phosphorus Pentasulfide:  A Mild and Versatile Catalyst/Reagent for the Preparation of Dithiocarboxylic Esters
  作者：Arumugam Sudalai、Subbareddy Kanagasabapathy、Brian C. Benicewicz

  DOI：10.1021/ol006407q

  日期：2000.10.1

  The reaction of carboxylic acids (1) with a variety of thiols or alcohols in the presence of phosphorus pentasulfide (P(4)S(10)) as a catalyst and reagent (20-40 mol %) proceeded effectively to afford the corresponding dithiocarboxylic esters (2) in high yields.

  在作为催化剂和五硫化二磷（P（4）S（10））和试剂（20-40 mol％）的五硫化二磷（P（4）S（10））存在下，羧酸（1）与多种硫醇或醇的反应有效进行，得到了相应的二硫代羧酸酯（2），收率高。
• Preparation of dithioesters by ester interchange and the PMR spectral properties of these compounds
  作者：N.H. Leon、R.S. Asquith

  DOI：10.1016/s0040-4020(01)93022-4

  日期：1970.1

  Aromatic and aliphatic dithioesters, many of them new, have been easily synthesized in excellent yields by the ester interchange reaction between carboxymethyl dithioesters and mercaptans. PMR spectra of these dithioesters and the corresponding oxygen analogues show that a strong anisotropic deshielding effect is associated with the highly polarized thiocarbonyl group.

  通过羧甲基二硫代酯与硫醇的酯交换反应，可以容易地以优异的产率合成芳族和脂肪族二硫代酯，其中许多是新的。这些二硫代酸酯和相应的氧类似物的PMR光谱表明，强极化的各向异性屏蔽作用与高度极化的硫代羰基有关。
• Dithiocarboxylic ester synthetic process
  申请人：——

  公开号：US20020019554A1

  公开（公告）日：2002-02-14

  A process the preparation of a dithiocarboxylic esters comprises reacting a carboxylic acid compound of formula R 1 (COOH) m , a compound of formula R 2 AH and phosphorus pentasulfide to produce a compound of structure I. An alternate process comprises reacting a 1 compound of formula R 3 (COAH) m and a compound of structure II 2 in the presence of a clay catalyst; and treating products of the reaction with a thiating agent to produce a compound of structure III, a compound of structure IV, or a combination of compounds of structure III and structure IV. 3

  一种制备二硫代羧酸酯的过程包括将具有公式R1(COOH)m的羧酸化合物、具有公式R2AH的化合物和五硫化磷反应以产生结构I的化合物。另一种方法包括在存在粘土催化剂的情况下，将具有公式R3(COAH)m的化合物和结构II2的化合物反应；并用硫化剂处理反应产物以产生结构III的化合物、结构IV的化合物，或结构III和结构IV的组合物。
• COMPOSITION
  申请人：FUJIFILM Corporation

  公开号：EP2357204A1

  公开（公告）日：2011-08-17

  A composition for film formation which can form a film suitable for use as an interlayer dielectric in a semiconductor device, etc. and having an appropriate even thickness and can give a film having excellent characteristics including permittivity and Young's modulus; and a dielectric film obtained from the film-forming composition. The composition contains a compound (X) having a functional group which is partly eliminated by heating, irradiation with light, irradiation with radiation, or a combination thereof to generate volatile matter and yield an unsaturated group in the remaining part of the functional group.

  一种成膜用组合物，它能形成适合用作半导体器件等的层间电介质的薄膜，且具有适当的均匀厚度，并能生成具有优异特性（包括介电常数和杨氏模量）的薄膜；以及一种从该成膜组合物中获得的电介质薄膜。该组合物含有一种具有官能团的化合物 (X)，通过加热、光照射、辐射照射或它们的组合可消除部分官能团，从而产生挥发性物质，并在官能团的剩余部分产生不饱和基团。
• Perregaard,J. et al., Bulletin des Societes Chimiques Belges, 1977, vol. 86, p. 321 - 328
  作者：Perregaard,J. et al.

  DOI：——

  日期：——