thiolane;trichloromolybdenum | 39210-31-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫杂环戊烷
• 英文名称: thiolane;trichloromolybdenum
• CAS: 39210-31-6
• 化学式: C₁₂H₂₄Cl₃MoS₃
• 分子量: 466.82
• InChiKey: ZXRWRAWFQWSUET-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  thiolane;trichloromolybdenum 以 甲苯 为溶剂， 生成 (tetrahydrothiophene)Cl2molybdenum(III)(μ-tetrahydrothiophene)(μ-Cl)2molybdenum(III)Cl2(tetrahydrothiophene) 、 meso-(tetrahydrothiophene)Cl2molybdenum(III)(μ-Cl)3molybdenum(Cl)(tetrahydrothiophene)2
  参考文献：
  名称：

  Moynihan, Kelly J.; Gao, Xiaoliang; Boorman, P. Michael, Inorganic Chemistry, 1990, vol. 29, # 9, p. 1648 - 1654

  摘要：

  DOI：
• 作为产物：
  描述：

  四氢噻吩 、 trichlorotris(tetrahydrofuran)molybdenum(III) 以83%的产率得到thiolane;trichloromolybdenum
  参考文献：
  名称：

  Moynihan, Kelly J.; Gao, Xiaoliang; Boorman, P. Michael, Inorganic Chemistry, 1990, vol. 29, # 9, p. 1648 - 1654

  摘要：

  DOI：

文献信息

• Molybdenum(<scp>III</scp>) chloride–tetrahydrothiophene (tht) complexes in the catalytic polymerization and cyclotrimerization of alkynes: structures and reactivities of the possible intermediates [MoCl₃(tht)₂(PhCCR)](R = Me or Et)
  作者：P. Michael Boorman、Meiping Wang、Masood Parvez

  DOI：10.1039/dt9960004533

  日期：——

  The binuclear complexes [Mo2Cl6(tht)(3)] (both the C-2. and C-s isomers, tht = tetrahydrothiophene) have been found to be active catalysts for the selective polymerization and cyclotrimerization of a variety of alkynes. The mononuclear complex [MoCl3(tht)(3)] shows similar behaviour, leading to the postulate that the active species in all cases is mononuclear. Two unique molybdenum(III) alkyne complexes, [MoCl3(tht)(2)L] (L = PhC=CMe or PhC=CEt) have been isolated and structurally characterized. The structural parameters for these complexes suggest that the alkynes behave as four-electron donors. These complexes are also catalytically active, and the alkyne L is incorporated into the product cyclotrimers and polymers suggesting they are the first intermediates in the formation of active catalysts from the original thioether complexes.