1-ethylidene-1H-indene | 51926-97-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• 英文名称: 1-ethylidene-1H-indene
• 英文别名: 1H-Indene, 1-ethylidene-；(1E)-1-ethylideneindene
• CAS: 51926-97-7
• 化学式: C₁₁H₁₀
• 分子量: 142.2
• InChiKey: HNZQPQACDDJLTD-XNWCZRBMSA-N

物化性质

• 沸点：
  75-78 °C(Press: 1.0 Torr)
• 密度：
  1.102±0.06 g/cm3(Predicted)
• 保留指数：
  1263.8;1277.8

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  magnesium,1-bromo-2-methanidylbenzene,bromide 在 bis-triphenylphosphine-palladium(II) chloride 、 potassium carbonate 作用下， 以 乙醚 、 乙醇 、 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 生成 1-ethylidene-1H-indene
  参考文献：
  名称：

  Ma, Shengming; Negishi, Ei-Ichi, Journal of the American Chemical Society, 1995, vol. 117, # 23, p. 6345 - 6354

  摘要：

  DOI：

文献信息

• Complete Study of the Pyrolysis and Gasification of Scrap Tires in a Pilot Plant Reactor
  作者：Juan A. Conesa、I. Martín-Gullón、R. Font、J. Jauhiainen

  DOI：10.1021/es034608u

  日期：2004.6.1

  The pyrolysis and gasification of tires was studied in a pilot plant reactor provided with a system for condensation of semivolatile matter. The study comprises experiments at 450, 750, and 1000 degreesC both in nitrogen and 10% oxygen atmospheres. Analysis of all the products obtained (gases, liquids, char, and soot) are presented. In the gas phase only methane and benzene yields increase with temperature until 1000 degreesC. In the liquids the main components are styrene, limonene, and isoprene. The solid fraction (including soot) increases with temperature. Zinc content of the char decreases with increasing temperature.
• Meng, Qingshui; Thibblin, Alf, Journal of the Chemical Society. Perkin Transactions 2 (2001), 1998, # 3, p. 583 - 589
  作者：Meng, Qingshui、Thibblin, Alf

  DOI：——

  日期：——
• Oelwegard, Maria; Ahlberg, Per, Acta Chemica Scandinavica, 1990, vol. 44, # 6, p. 642 - 644
  作者：Oelwegard, Maria、Ahlberg, Per

  DOI：——

  日期：——
• The stereochemistry of solvent-promoted E1cB/E2 reactions of α-indenyl substituted ethyl halides
  作者：Qingshui Meng、Alf Thibblin

  DOI：10.1039/cc9960000345

  日期：——

  The solvent-promoted elimination reactions of threo-1-(1-X-ethyl)indene 1-X (X = Cl, Br, I) and the corresponding erythro isomer 2-Br in 25 vol% acetonitrile in water at 55 degrees C, which are concluded to be of E1cB and E2 types, exhibit leaving-group dependent-, non-stereospecific and stereospecific 1,2-elimination, respectively.
• OLWEGARD, MARIA;AHLBERG, PER, ACTA CHEM. SCAND., 44,(1990) N, C. 642-644
  作者：OLWEGARD, MARIA、AHLBERG, PER

  DOI：——

  日期：——