N,N,N',N'-tetraphenyl-o-phenylenediamine | 29325-55-1

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N,N',N'-tetraphenyl-o-phenylenediamine
• 英文别名: N,N,N',N'-Tetraphenyl-o-phenylendiamin；1-N,1-N,2-N,2-N-tetraphenylbenzene-1,2-diamine
• CAS: 29325-55-1
• 化学式: C₃₀H₂₄N₂
• 分子量: 412.534
• InChiKey: IJVBYWCDGKXHKK-UHFFFAOYSA-N

物化性质

• 沸点：
  548.7±33.0 °C(Predicted)
• 密度：
  1.172±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  8.4
• 重原子数：
  32
• 可旋转键数：
  6
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  6.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Li[Al(perfluoro-tertbutoxide)4] 、 N,N,N',N'-tetraphenyl-o-phenylenediamine 在 silver hexafluoroantimonate 作用下， 以 二氯甲烷 为溶剂， 以65%的产率得到
  参考文献：
  名称：

  具有意外的非Kekulé双自由基特征的邻-喹二甲烷的氮类似物

  摘要：

  三种1,2-二（双苯基氨基）-苯的二电子氧化提供了一类邻喹二甲烷的氮类似物。通过包括EPR和UV-vis吸收光谱在内的光谱技术研究了它们在基态下的电子结构。它们具有开壳的单重态基态和热可接近的三重态。其中一个（1 2+）已被结晶并分离。SQUID测量，单晶X射线衍射和理论计算表明1 2+具有出乎意料的非Kekulé双自由基特性，与邻喹啉甲烷有显着差异。

  DOI：

  10.1002/cjoc.201700801
• 作为产物：
  描述：

  碘苯 、 邻氨基二苯胺 在 18-冠醚-6 、 铜 、 potassium carbonate 作用下， 反应 6.0h， 以63%的产率得到N,N,N',N'-tetraphenyl-o-phenylenediamine
  参考文献：
  名称：

  Polyaromatic amines. Part 2. Synthesis of 4,4′,4″-tris(N-aryl-N-phenylamino)triphenylamine, N,N-bis[4-(N-aryl-N-phenylamino)phenyl]tolylamine and N,N,N′,N′-tetraaryl-o-phenylenediamine derivatives

  摘要：

  所述化合物作为研究新芳香胺作为电荷传输材料的一部分进行了合成和表征。由于它们在CDCl3中的容易氧化，化合物1-6的质子和碳谱数据是在C6D6中获得的。每个化合物均通过循环伏安法进行了表征。根据第一次和第二次氧化电位之间的差值，推测出了分子内电荷迁移率的估计值。

  DOI：

  10.1039/b106273p

文献信息

• NAPHTHALENEDICARBOXIMIDE DERIVATIVE AND ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER
  申请人：KYOCERA Document Solutions Inc.

  公开号：US20170153560A1

  公开（公告）日：2017-06-01

  A naphthalenedicarboximide derivative is represented by general formula (1) or (2). In general formulas (1) and (2), R 1 , R 2 , and R 3 each represent, independently of one another, an alkyl group which has a carbon number from 1 to 10 and which may have an aryl group having a carbon number from 6 to 14, an aryl group which has a carbon number from 6 to 14 and which may have an alkyl group having a carbon number from 1 to 10, a cycloalkyl group having a carbon number from 3 to 10, or an alkoxy group having a carbon number from 1 to 6, and m represents an integer from 0 to 4. When m represents an integer of 2 or more, chemical groups R 2 may each be the same or may each be different.

  一种萘二甲酰亚胺衍生物由通式（1）或（2）表示。在通式（1）和（2）中，R1、R2和R3分别独立地表示碳数为1至10的烷基基团，可能具有碳数为6至14的芳基基团，具有碳数为6至14的芳基基团，可能具有碳数为1至10的烷基基团，具有碳数为3至10的环烷基基团，或具有碳数为1至6的烷氧基基团，m代表0至4之间的整数。当m表示2或更多的整数时，化学基团R2可能相同，也可能不同。
• Quinoxaline derivatives, and light emitting element using thereof
  申请人：Shitagaki Satoko

  公开号：US20050065342A1

  公开（公告）日：2005-03-24

  It is an object to provide an organic compound that has a bipolar property and also a light emitting property, and further has heat resistance. A quinoxaline derivative represented by a general formula ( 1 ) is provided. In the formula, A represents any one of an alkylene chain, silicon (Si), oxygen (O), nitrogen (N), and sulfur (S). R 1 to R 8 , which may be identical or different, individually represent any one of a lower alkyl group, an aryl group, and a heterocyclic group. R 9 to R 24 , which may be identical or different, individually represent any one of a hydrogen atom, a halogen atom, a lower alkyl group, an alkoxy group, an acyl group, a nitro group, a cyano group, an amino group, a dialkylamino group, a diarylamino group, a vinyl group, an aryl group which may have a substituent, and a heterocyclic group.

  提供一种具有双极性和发光性质的有机化合物，并且具有耐热性。提供了由通式（1）表示的喹啉衍生物。在该式中，A代表碳链、硅（Si）、氧（O）、氮（N）和硫（S）中的任意一种。R1至R8，可以相同也可以不同，分别表示较低的烷基、芳基和杂环基中的任意一种。R9至R24，可以相同也可以不同，分别表示氢原子、卤素原子、较低的烷基、烷氧基、酰基、硝基、氰基、氨基、二烷基氨基、二芳基氨基、乙烯基、可能有取代基的芳基和杂环基中的任意一种。
• BRANCHED COMPOUNDS, ORGANIC THIN FILMS MADE BY USING THE SAME, AND ORGANIC THIN FILM DEVICES
  申请人：Osaka University

  公开号：EP2251335A1

  公开（公告）日：2010-11-17

  A branched compound including a core part, at least one side chain part bonded to the core part, and an end, wherein one repeating unit or two or more repeating units expressed by the following formula (1) repeat in the or each side chain part, with the proviso that in a repeating unit bonded to the core part, T is bonded to the core part, and in two or more contiguous repeating units, each L is bonded to the T, each L is formed of a plurality of conjugation-forming units linked together; each L includes at least one thienylene unit as the conjugation-forming unit; and at least two of the groups existing at the ends of Ls (the ends of the L in sides which are not bonded to T) are acceptor groups. (In the formula, each L represents a divalent organic group which may have a substituent and the T represents a trivalent organic group which may have a substituent.)

  一种分支化合物，包括一个核心部分，至少一个与核心部分结合的侧链部分和一个末端，在该化合物中，由下式（1）表示的一个重复单元或两个或更多重复单元在每个侧链部分中重复，条件是在与核心部分结合的重复单元中，T与核心部分结合，在两个或更多相邻的重复单元中，每个L与T结合，每个L由多个共轭形成单元连接在一起形成；每个L包括至少一个噻吩亚烯单元作为共轭形成单元；并且在L的末端（在未与T结合的侧链中的L的末端）存在的至少两个基团是受体基团。（在公式中，每个L代表可能具有取代基的二价有机基团，T代表可能具有取代基的三价有机基团。）
• Organic-inorganic hybrid material, composition for synthesizing the same, and manufacturing method of the same
  申请人：Semiconductor Energy Laboratory Co., Ltd.

  公开号：US20040265253A1

  公开（公告）日：2004-12-30

  An organic-inorganic hybrid material chelating a metal atom of a metal oxide matrix 103 in a pendant shape is synthesized, where the organic compound (the functional chelating agent) 104 is able to develop a function of a coloring property, a light-emitting property, or semiconductivity by chelating a metal atom. As a synthesis method, sol (a composition for coating application) including a metal alkoxide and/or a metal salt and a functional chelating agent may be prepared and the organic-inorganic hybrid material may be synthesized by sol-gel method. Due to the above-mentioned structure, it is possible to synthesize an organic-inorganic hybrid material that has an organic group directly bonded to a metal oxide matrix and is able to develop a different function from that of a mere metal oxide. In other words, it is possible to realize a functional organic-inorganic hybrid material that develops a coloring property, a light-emitting property, or semiconductivity due to the organic group directly bonded to the metal oxide matrix.

  合成一种有机-无机混合材料，其中有机化合物（功能螯合剂）能够通过螯合金属原子来发展一种着色特性、发光特性或半导体性能。作为一种合成方法，可以准备包含金属烷氧化物和/或金属盐以及功能螯合剂的溶胶（用于涂层应用的组合物），并通过溶胶-凝胶方法合成有机-无机混合材料。由于上述结构，可以合成一种有机-无机混合材料，其中有机基直接与金属氧化物基质结合，并能够发展出与单纯金属氧化物不同的功能。换句话说，由于有机基直接与金属氧化物基质结合，可以实现一种具有着色特性、发光特性或半导体性能的功能性有机-无机混合材料。
• TERPHENYL COMPOUND, ELECTROPHOTOGRAPHIC PHOTOSENSITIVE MEMBER, AND METHOD FOR PRODUCING TERPHENYL COMPOUND
  申请人：KYOCERA Document Solutions Inc.

  公开号：US20200231535A1

  公开（公告）日：2020-07-23

  A compound is represented by general formula (1). In general formula (1), R 1 and R 2 each represent, independently of one another, a hydrogen atom, a methyl group, or an ethyl group, and a sum of the number of carbon atoms of the chemical group represented by R 1 and the number of carbon atoms of the chemical group represented by R 2 is 2. R 3 and R 4 each represent, independently of one another, a hydrogen atom, a methyl group, or an ethyl group, and a sum of the number of carbon atoms of the chemical group represented by R 3 and the number of carbon atoms of the chemical group represented by R 1 is 2. A photosensitive layer of an electrophotographic photosensitive member contains at least a charge generating material, a hole transport material, and a binder resin. The hole transport material includes a compound represented by general formula (1)

  化合物用一般式（1）表示。在一般式（1）中，R1和R2各自独立地表示氢原子、甲基基团或乙基基团，以及由R1表示的化学基团的碳原子数和由R2表示的化学基团的碳原子数之和为2。R3和R4各自独立地表示氢原子、甲基基团或乙基基团，以及由R3表示的化学基团的碳原子数和由R1表示的化学基团的碳原子数之和为2。电子照相感光成员的光敏层至少包含一个电荷发生材料，一个空穴传输材料和一个粘合树脂。空穴传输材料包括一个由一般式（1）表示的化合物。