3-dimethylamino-phenol; hydrochloride | 74347-16-3

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 3-dimethylamino-phenol; hydrochloride
• 英文别名: 3-Dimethylamino-phenol; Hydrochlorid；3-(Dimethylamino)phenol hydrochloride；3-(dimethylamino)phenol;hydrochloride
• CAS: 74347-16-3
• 化学式: C₈H₁₁NO*ClH
• 分子量: 173.642
• InChiKey: QFFMLAOGZNJIBZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -2.83
• 重原子数：
  11
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  24.7
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-dimethylamino-phenol; hydrochloride 在 氯仿 、 水 、 铂 作用下， 生成 4-nitro-benzoic acid-(3-dimethylamino-cyclohexyl ester); hydrochloride
  参考文献：
  名称：

  Heckel; Adams, Journal of the American Chemical Society, 1925, vol. 47, p. 1717

  摘要：

  DOI：
• 作为产物：
  描述：

  3-羟基-N,N-二甲基苯胺 、 盐酸 在 氮 、 乙醚 作用下， 以 乙醚 为溶剂， 反应 2.0h， 生成 3-dimethylamino-phenol; hydrochloride
  参考文献：
  名称：

  Chemically -modified supports and supported catalyst systems prepared therefrom

  摘要：

  本发明提供了一种化学修饰的支持体，包括一种含有可选官能化羟基的无机氧化物，其化学上与一个阳离子/阴离子对的阳离子相连。本发明还提供了一种支持的催化剂体系，包括上述化学修饰的支持体和第3-10族过渡金属化合物（优选为第4族金属化合物），该化合物含有至少一个π-配位的阴离子配体基团，该过渡金属化合物能够通过阳离子/阴离子对的阳离子与化学修饰的支持体反应，从而使得过渡金属化合物具有催化活性。本发明还提供了一种制备该化学修饰的支持体的方法。本发明还提供了一种加成聚合过程，包括在加成聚合条件下将一种或多种加成聚合单体与上述支持的催化剂体系接触。

  公开号：

  US20030212222A1

文献信息

• Chemically-modified supports and supported catalyst systems prepared therefrom
  申请人：Carnahan M. Edmund

  公开号：US20070105709A1

  公开（公告）日：2007-05-10

  The present invention provides a chemically-modified support comprising an inorganic oxide containing optionally functionalized hydroxyl groups, having chemically linked thereto the cation of a cation/anion pair. The present invention further provides a supported catalyst system comprising the chemically-modified support as described above, and a transition metal compound of Groups 3-10 (preferably a Group 4 metal compound) containing at least one π-bonded anionic ligand group, said transition metal compound being capable of reacting with the chemically-modified support through the cation of the cation/anion pair to thereby render the transition metal compound catalytically active. The present invention further provides a process for preparing the chemically-modified support of the invention. The present invention further provides an addition polymerization process comprising contacting one or more addition polymerizable monomers with the supported catalyst system of the invention under addition polymerization conditions.

  本发明提供了一种化学修饰的支撑体，包括一种无机氧化物，其中含有可选的功能化羟基，其化学上与阳离子/阴离子对的阳离子相连。本发明还提供了一种支撑催化剂体系，包括上述化学修饰的支撑体和3-10族过渡金属化合物（优选为4族金属化合物），其中过渡金属化合物含有至少一个π键配体阴离子基团，该过渡金属化合物能够通过阳离子/阴离子对的阳离子与化学修饰的支撑体反应，从而使过渡金属化合物具有催化活性。本发明还提供了一种制备上述化学修饰的支撑体的方法。本发明还提供了一种加成聚合过程，包括在加成聚合条件下将一种或多种加成聚合单体与本发明的支撑催化剂体系接触。
• CHEMICALLY-MODIFIED SUPPORTS AND SUPPORTED CATALYST SYSTEMS PREPARED THEREFROM
  申请人：THE DOW CHEMICAL COMPANY

  公开号：EP1248808A1

  公开（公告）日：2002-10-16
• US7491672B2
  申请人：——

  公开号：US7491672B2

  公开（公告）日：2009-02-17
• [EN] CHEMICALLY-MODIFIED SUPPORTS AND SUPPORTED CATALYST SYSTEMS PREPARED THEREFROM<br/>[FR] SUPPORTS CHIMIQUEMENT MODIFIES ET SYSTEMES DE CATALYSEURS SUPPORTES PREPARES A PARTIR DESDITS SUPPORTS
  申请人：DOW CHEMICAL CO

  公开号：WO2001058969A1

  公开（公告）日：2001-08-16

  The present invention provides a chemically-modified support comprising an inorganic oxide containing optionally functionalized hydroxyl groups, having chemically linked thereto the cation of a cation/anion pair. The present invention further provides a supported catalyst system comprising the chemically-modified support as described above, and a transition metal compound of Groups 3-10 (preferably a Group 4 metal compound) containing at least one π-bonded anionic ligand group, said transition metal compound being capable of reacting with the chemically-modified support through the cation of the cation/anion pair to thereby render the transition metal compound catalytically active. The present invention further provides a process for preparing the chemically-modified support of the invention. The present invention further provides an addition polymerization process comprising contacting one or more addition polymerizable monomers with the supported catalyst system of the invention under addition polymerization conditions.