tert-butyl N-[2-[bis[3-[2-(naphthalene-1-carbonylamino)ethylamino]-3-oxopropyl]amino]ethyl]carbamate | 1018686-86-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: tert-butyl N-[2-[bis[3-[2-(naphthalene-1-carbonylamino)ethylamino]-3-oxopropyl]amino]ethyl]carbamate
• CAS: 1018686-86-6
• 化学式: C₃₉H₄₈N₆O₆
• 分子量: 696.847
• InChiKey: BIXUCBSTUNHYQV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  51
• 可旋转键数：
  19
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.36
• 拓扑面积：
  158
• 氢给体数：
  5
• 氢受体数：
  7

反应信息

• 作为反应物：
  描述：

  tert-butyl N-[2-[bis[3-[2-(naphthalene-1-carbonylamino)ethylamino]-3-oxopropyl]amino]ethyl]carbamate 、 三氟乙酸 生成 C₂HF₃O₂*C₃₄H₄₀N₆O₄
  参考文献：
  名称：

  Synthesis and energy-transfer properties of poly(amidoamine) dendrons modified with naphthyl and dansyl groups

  摘要：

  Poly(amidoamine) dendrons of 1-3 generations with naphthyl groups at the periphery and a dansyl group at the focal point were synthesized and carefully characterized. Intramolecular energy-transfer properties of these flexible aliphatic-scaffold light-harvesting dendrons were investigated by UV-vis absorption and fluorescence spectroscopy. Efficient energy transfer from the naphthyl groups to the dansyl group occurred for both the first and the second generation dendrons (the energy-transfer efficiency was 94.3% and 76.9%, respectively), whereas the third generation dendron exhibited a low energy-transfer efficiency of 17.8%. The average donor-acceptor distances between the naphthyl and dansyl groups were calculated for different generation dendrons. Different degrees of the backfolding of dendritic branches were used to interpret the different donor-acceptor distances. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.01.083
• 作为产物：
  描述：

  1-萘甲酸 、 tert-butyl (2-(bis(3-((2-aminoethyl)amino)-3-oxopropyl)amino)ethyl)carbamate 在 N,N'-二环己基碳二亚胺 作用下， 以 氯仿 为溶剂， 反应 25.0h， 生成 tert-butyl N-[2-[bis[3-[2-(naphthalene-1-carbonylamino)ethylamino]-3-oxopropyl]amino]ethyl]carbamate
  参考文献：
  名称：

  Synthesis and energy-transfer properties of poly(amidoamine) dendrons modified with naphthyl and dansyl groups

  摘要：

  Poly(amidoamine) dendrons of 1-3 generations with naphthyl groups at the periphery and a dansyl group at the focal point were synthesized and carefully characterized. Intramolecular energy-transfer properties of these flexible aliphatic-scaffold light-harvesting dendrons were investigated by UV-vis absorption and fluorescence spectroscopy. Efficient energy transfer from the naphthyl groups to the dansyl group occurred for both the first and the second generation dendrons (the energy-transfer efficiency was 94.3% and 76.9%, respectively), whereas the third generation dendron exhibited a low energy-transfer efficiency of 17.8%. The average donor-acceptor distances between the naphthyl and dansyl groups were calculated for different generation dendrons. Different degrees of the backfolding of dendritic branches were used to interpret the different donor-acceptor distances. (c) 2008 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2008.01.083

文献信息

• Synthesis and energy-transfer properties of poly(amidoamine) dendrons modified with naphthyl and dansyl groups
  作者：Wu-Song Li、Ming-Jun Teng、Xin-Ru Jia、Bing-Bing Wang、Jui-Ming Yeh、Yen Wei

  DOI：10.1016/j.tetlet.2008.01.083

  日期：2008.3

  Poly(amidoamine) dendrons of 1-3 generations with naphthyl groups at the periphery and a dansyl group at the focal point were synthesized and carefully characterized. Intramolecular energy-transfer properties of these flexible aliphatic-scaffold light-harvesting dendrons were investigated by UV-vis absorption and fluorescence spectroscopy. Efficient energy transfer from the naphthyl groups to the dansyl group occurred for both the first and the second generation dendrons (the energy-transfer efficiency was 94.3% and 76.9%, respectively), whereas the third generation dendron exhibited a low energy-transfer efficiency of 17.8%. The average donor-acceptor distances between the naphthyl and dansyl groups were calculated for different generation dendrons. Different degrees of the backfolding of dendritic branches were used to interpret the different donor-acceptor distances. (c) 2008 Elsevier Ltd. All rights reserved.