1-chloro-4-methylhexane | 86646-45-9

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 有机氯化物
• 英文名称: 1-chloro-4-methylhexane
• CAS: 86646-45-9
• 化学式: C₇H₁₅Cl
• 分子量: 134.649
• InChiKey: HKKQSNCJIFHCQD-UHFFFAOYSA-N

物化性质

• 沸点：
  150.0±8.0 °C(Predicted)
• 密度：
  0.864±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  1-chloro-4-methylhexane 、 甲基丙二酸二乙酯 在 NaH 作用下， 生成 (5-methyl-heptyl)-malonic acid diethyl ester
  参考文献：
  名称：

  Method of attracting Tribolium confusum J. using 2,6-dimethyl-1-octanol

  摘要：

  一种对混淆谷甲Tribolium confusum J.具有吸引活性的引诱剂，其中包含2,6-二甲基-1-辛醇作为展现吸引活性的成分。2,6-二甲基-辛醇可以与适当的溶剂稀释，或者由适当的固相载体以片剂形式携带。这种引诱剂可以有效地用于诱捕。

  公开号：

  US05063058A1
• 作为产物：
  描述：

  2-溴丁烷 、 1-溴-3-氯丙烷 在 copper(I) bromide 作用下， 以 四氢呋喃 为溶剂， 以65%的产率得到1-chloro-4-methylhexane
  参考文献：
  名称：

  Method of attracting Tribolium confusum J. using 2,6-dimethyl-1-octanol

  摘要：

  一种对混淆谷甲Tribolium confusum J.具有吸引活性的引诱剂，其中包含2,6-二甲基-1-辛醇作为展现吸引活性的成分。2,6-二甲基-辛醇可以与适当的溶剂稀释，或者由适当的固相载体以片剂形式携带。这种引诱剂可以有效地用于诱捕。

  公开号：

  US05063058A1

文献信息

• Isobutylene polymer and process for producing the same
  申请人：KANEGAFUCHI KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0722957A1

  公开（公告）日：1996-07-24

  The present invention provides a novel solvent which is capable of providing an excellent isobutylene polymer, little affects the environment, has a lower solubility in water than those of halogenated hydrocarbons having 1 or 2 carbon atoms and can be decomposed relatively easily. Namely, the present invention relates to: a process for producing an isobutylene polymer, which comprises performing a cationic polymerization reaction in a solvent containing primary and/or secondary monohalogenated hydrocarbon(s) having 3 to 8 carbon atoms, and an isobutylene polymer thus obtained; and a process for producing an isobutylene polymer having a vinyl group introduced into the terminal thereof, which comprises reacting the isobutylene polymer produced above with 1,9-decadiene or allyltrimethylsialne, and an isobutylene polymer thus obtained.

  本发明提供了一种新型溶剂，它能够提供优良的异丁烯聚合物，对环境影响小，在水中的溶解度低于具有 1 或 2 个碳原子的卤代烃，并且相对容易分解。 也就是说，本发明涉及：一种异丁烯聚合物的生产工艺，包括在含有具有 3 至 8 个碳原子的一级和/或二级单卤代烃的溶剂中进行阳离子聚合反应，以及由此获得的异丁烯聚合物；以及一种在其末端引入乙烯基的异丁烯聚合物的生产工艺，包括将上述生产的异丁烯聚合物与 1，9-癸二烯或烯丙基三甲基炔反应，以及由此获得的异丁烯聚合物。
• Process for producing isobutylene block copolymer
  申请人：KANEKA CORPORATION

  公开号：EP0949282A2

  公开（公告）日：1999-10-13

  A process for producing an isobutylene block copolymer, which comprises performing cationic polymerization of a monomer component containing isobutylene as a major monomer and a monomer component whose major monomer is not isobutylene in the presence of an initiator, wherein the polymerization is carried out in a mixed solvent containing a monohalogenated hydrocarbon solvent and a non-halogenated hydrocarbon solvent, the monohalogenated hydrocarbon solvent containing a primary monohalogenated hydrocarbon having three to eight carbon atoms and/or a secondary monohalogenated hydrocarbon having three to eight carbon atoms, the non-halogenated hydrocarbon solvent containing an aliphatic hydrocarbon and/or an aromatic hydrocarbon.

  一种异丁烯嵌段共聚物的生产工艺，包括在引发剂存在下，对以异丁烯为主要单体的单体组分和以非异丁烯为主要单体的单体组分进行阳离子聚合，其中聚合在含有单卤代烃溶剂和非卤代烃溶剂的混合溶剂中进行、单卤代烃溶剂含有 3 至 8 个碳原子的一级单卤代烃和/或 3 至 8 个碳原子的二级单卤 代烃，非卤代烃溶剂含有脂肪烃和/或芳香烃。
• PROCESS FOR PRODUCING ISOBUTYLENE BLOCK COPOLYMER
  申请人：Kaneka Corporation

  公开号：EP1752473A1

  公开（公告）日：2007-02-14

  An object of the present invention is to provide a process for producing an isobutylene block copolymer, which process can provide a resin having a low content of a catalyst residue and high transparency. The object can be achieved by a process for producing an isobutylene block copolymer by living cationic polymerization using a Lewis acid, wherein, for removing the Lewis acid from a solution after the polymerization, the solution is charged into and mixed with water in which a nonionic surfactant with an HLB of 10 or less is contained in an amount of 0.01 to 0.5 part by weight based on 100 parts by weight of the isobutylene block copolymer.

  本发明的目的是提供一种生产异丁烯嵌段共聚物的工艺，该工艺可提供一种催化剂残留物含量低、透明度高的树脂。本发明的目的可以通过使用路易斯酸进行活阳离子聚合来生产异丁烯嵌段共聚物的工艺来实现，其中，为了在聚合后从溶液中去除路易斯酸，将溶液注入水中并与水混合，在水中含有 HLB 为 10 或以下的非离子表面活性剂，其含量为 0.01 至 0.5 份（以 100 份异丁烯嵌段共聚物的重量计）。
• METHOD FOR PRODUCING ISOBUTYLENE POLYMER
  申请人：Kaneka Corporation

  公开号：EP1775310A1

  公开（公告）日：2007-04-18

  Disclosed is a method for stably and efficiently removing a catalyst from an isobutylene polymer by improving the separatability of an organic phase and an aqueous phase during the operation wherein a catalyst is washed out from a reaction solution containing an isobutylene polymer by means of water. Specifically disclosed is a method for producing an isobutylene polymer which is characterized in that the water containing 0.00005 - 0.005 weight % of a nonionic polymer surfactant having a hydroxyl group is used when a reaction solution after polymerization which contains an isobutylene polymer is cleaned with water after deactivating the catalyst by treating the reaction solution with water and removing the aqueous phase.

  本发明公开了一种从异丁烯聚合物中稳定有效地除去催化剂的方法，该方法是在用水从含有异丁烯聚合物的反应溶液中冲洗催化剂的操作过程中，提高有机相和水相的可分离性。具体地说，本发明公开了一种生产异丁烯聚合物的方法，其特征在于，在用水处理含有异丁烯聚合物的聚合反应溶液并除去水相，使催化剂失活后，用水清洗含有 0.00005 - 0.005 重量％羟基的非离子聚合物表面活性剂的反应溶液时，使用含有 0.00005 - 0.005 重量％羟基的非离子聚合物表面活性剂的水。
• CURABLE COMPOSITION
  申请人：Kaneka Corporation

  公开号：EP1923431A1

  公开（公告）日：2008-05-21

  The present invention has its object to provide a crosslinkable silyl group-terminated vinyl polymer-containing curable composition which secures a sufficiently long pot life and, at the same time, can be cured rapidly on the occasion of need and can give cured products excellent in thermal stability, oil resistance, weathering resistance, mechanical properties and adhesiveness, among others. The present invention provides a curable composition containing (I) and (II) mentioned in the following: a vinyl polymer (I) having, on an average, at least one crosslinkable silyl group at its termini, and a photo acid generator (II). The vinyl polymer (I) according to the present invention is preferably a (meth)acrylic polymer.

  本发明的目的是提供一种含可交联硅烷基端基的乙烯基聚合物可固化组合物，该组合物可确保足够长的固化寿命，同时可在需要时快速固化，并可使固化产品具有优异的热稳定性、耐油性、耐候性、机械性能和粘合性等。 本发明提供了一种可固化组合物，其中包含以下所述的（I）和（II）：乙烯基聚合物 （I），其端部平均具有至少一个可交联的硅基；以及光酸发生器（II）。 根据本发明，乙烯基聚合物（I）最好是（甲基）丙烯酸聚合物。