cyclo[bis(2,7-naphthalenediyl diethylphorphoramidite)] | 373363-90-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: cyclo[bis(2,7-naphthalenediyl diethylphorphoramidite)]
• 英文别名: 3-N,3-N,13-N,13-N-tetraethyl-2,4,12,14-tetraoxa-3,13-diphosphapentacyclo[13.5.3.35,11.018,22.08,25]hexacosa-1(21),5(26),6,8(25),9,11(24),15(23),16,18(22),19-decaene-3,13-diamine
• CAS: 373363-90-7
• 化学式: C₂₈H₃₂N₂O₄P₂
• 分子量: 522.521
• InChiKey: MJPDQIFAEZUOCM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.41
• 重原子数：
  36.0
• 可旋转键数：
  6.0
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  59.04
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  cyclo[bis(2,7-naphthalenediyl diethylphorphoramidite)] 在 过氧化脲素 作用下， 以 二氯甲烷 为溶剂， 反应 2.5h， 以93%的产率得到3-N,3-N,13-N,13-N-tetraethyl-3,13-dioxo-2,4,12,14-tetraoxa-3λ5,13λ5-diphosphapentacyclo[13.5.3.35,11.018,22.08,25]hexacosa-1(21),5(26),6,8(25),9,11(24),15(23),16,18(22),19-decaene-3,13-diamine
  参考文献：
  名称：

  摘要：

  1,5- and 2,7-dihydroxynaphthalenes were reacted with P(III) amides to obtain naphthocyclophanes. The structures and chemical properties of the products were studied.

  DOI：

  10.1023/a:1012378817167
• 作为产物：
  描述：

  2,7-二羟基萘 以 1,4-二氧六环 、 二氯甲烷 、 乙腈 为溶剂， 反应 144.33h， 生成 cyclo[bis(2,7-naphthalenediyl diethylphorphoramidite)]
  参考文献：
  名称：

  Phosphomacrocyclic systems based on 2,2′-dihydroxy-1,1′-dinaphtylmethane

  摘要：

  For the first time phosphomacrocyclic systems were synthesized based on 2,2'-dihydroxy-1,1'-dinaphthylmethane, other aromatic diols, and phosphorous hexaethyltriamide. Spontaneous transformation of the obtained macrocycles into the more stable 1,3,2-dioxaphosphacyn and cyclobisamidophosphite was established.

  DOI：

  10.1134/s1070363210050099

文献信息

• Rhodium(I) carbonyl complexes based on naphthophosphacyclophanes
  作者：P. V. Slitikov、V. S. Boldyrev、Yu. B. Evdokimenkova

  DOI：10.1007/s11172-017-1831-7

  日期：2017.5

  Naphthphosphacyclophanes based on symmetrical dihydroxynaphthalenes linked by diethylamidophospite groups were used to synthesize rhodium(I) complexes containing carb-onyl and acetylacetonato fragments. The physicochemical and spectral characteristics of the synthesized coordination systems were studied.

  基于由二乙基酰胺基亚磷酸酯基团连接的对称二羟基萘的萘并磷杂环芳被用于合成含有羰基和乙酰丙酮基片段的铑 (I) 配合物。研究了合成配位体系的理化和光谱特性。
• Phosphorylation of 1,4-bis(hydroxymethyl)benzene with trivalent phosphorus derivatives
  作者：P. V. Slitikov、V. A. Bogoyavlenskii、E. N. Rasadkina、E. E. Nifant’ev

  DOI：10.1134/s1070363207060126

  日期：2007.6

  Phosphorylation of 1,4-bis(hydroxymethyl)benzene with complete phosphorous acid amides and phenyl phosphorodichloridite is studied. Some phosphorus-containing linear systems, the phosphamacrocycle precursors, are synthesized. The possibility of synthesis of phosphamacrocyclic systems based on 1,4-bis(hydroxymethyl)benzene is considered; it was shown that this compound does not tend to form macrocycles.
• Dismutation of arylene phosphorodiamidites: Specific features and aspects of preparative use
  作者：E. N. Rasadkina、P. V. Slitikov、E. E. Nifant’ev

  DOI：10.1134/s1070363206020046

  日期：2006.2

  The dismutation ofarylene phosphorodiamidites derived from the simplest phenols and naphthols and of their dibasic analogs was studied. The main regular trends of this process and the limits of its synthetic applicability were determined.
• Macrocyclic Systems on the Basis of Phosphorus Acids and 2,7-Dihydroxynaphthalene
  作者：E. N. Rasadkina、P. V. Slitikov、Yu. B. Evdokimenkova、E. E. Nifant'ev

  DOI：10.1023/b:rugc.0000007643.79978.ad

  日期：2003.8

  Syntheses of macrocyclic systems containing three 2,7-dihydroxynaphthalene residues and three residues of thiophosphoric and phosphorous amides in various ratios are developed. Chemical properties of the obtained compounds are studied.