二乙胺氮氧化物 | 10605-31-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 中文名称: 二乙胺氮氧化物
• 英文名称: diethyl nitroxide
• CAS: 10605-31-9
• 化学式: C₄H₁₀NO
• 分子量: 88.1295
• InChiKey: LHPDAPVJSKDGCA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.5
• 重原子数：
  6
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  4.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  二乙胺氮氧化物 以 甲苯 为溶剂， 生成
  参考文献：
  名称：

  ESR studies of nitroxide radicals formed in the low temperature photolysis ofN-nitrosamines

  摘要：

  AbstractVarious N‐nitrosamines were photolyzed in toluene solution in the temperature range −100°C to −30°C to yield dialkyl nitroxides. The nitrosamines studied were N‐nitrosodimethylamine, N‐nitrosodiethylamine, N‐nitrosodipropylamine, N‐nitrosodibutylamine and N‐nitrosodicyclohexylamine. Subsequent nitroxide side products were also detected by ESR, and a mechanism for their formation is proposed. Temperature dependent hyperfine couplings of the methylene protons were observed for a few radicals of the type R1CH2NO˙R2.

  DOI：

  10.1002/mrc.1270170213
• 作为产物：
  描述：

  二乙基羟胺 在 1,1-二苯基-2-苦味酰肼 作用下， 以 四氯化碳 为溶剂， 生成 二乙胺氮氧化物
  参考文献：
  名称：

  Revision of the αH2 value for N,N-dialkylhydroxylamines based on kinetic and spectroscopic measurements

  摘要：

  动力学溶剂效应对2,2-二苯基-1-苦基肼基自由基（DPPH·）从N,N-二乙基羟胺和N,N-二苄基羟胺中夺取氢原子的影响表明，这些化合物作为氢键供体的强度远低于当前公认的αH2值0.453所暗示的程度。通过在四氯化碳中使用红外光谱监测与两种强氢键受体HMPA和DMSO形成1∶1复合物的过程，也得到了较低的αH2值。因此得出结论，对于空间位阻不受限的N,N-二烷基羟胺，其αH2值应向下修正为0.29。

  DOI：

  10.1039/b102247o

文献信息

• Aromatic radical anions as possible intermediates in the nucleophilic aromatic substitution (SNAr): an EPR study
  作者：Loris Grossi、Samantha Strazzari

  DOI：10.1039/a903407b

  日期：——

  The reactions among halonitrobenzenes or polynitrobenzenes and alkoxides, thiolates or tertiary amines have provided the evidence that in a SNAr reaction type a single electron transfer from the nucleophile to the aromatic substrate, to generate two radical species within the solvent cage, can take place to some extent. The detection of radical intermediates by EPR spectroscopy, in several SNAr reactions

  卤代硝基苯或多硝基苯与醇盐，硫醇盐或叔胺之间的反应提供了证据，表明在S N Ar反应类型中，可以发生从亲核体到芳族底物的单电子转移，从而在溶剂笼内产生两个自由基在某种程度上。通过EPR光谱学，在几μs自由基中间体的检测Ñ氩反应报道。
• Base-catalyzed autoxidation of trialkylamines. An e.s.r study
  作者：Loris Grossi

  DOI：10.1016/s0040-4039(00)95520-5

  日期：1987.1

  When a freshly distilled tertiary alkyl amine is dissolved in water a base-catalyzed oxidative dealkylation process takes place, leading to the formation of secondary nitroxyl radicals, alkenes and carbonyl-containing compounds.

  当将新鲜蒸馏的叔烷基胺溶解在水中时，会发生碱催化的氧化脱烷基过程，从而导致仲硝氧基自由基，烯烃和含羰基化合物的形成。
• Korth, Hans-Gert; Sustmann, Reiner; Dupuis, Jacques, Chemische Berichte, 1987, vol. 120, p. 1197 - 1202
  作者：Korth, Hans-Gert、Sustmann, Reiner、Dupuis, Jacques、Giese, Bernd

  DOI：——

  日期：——
• Possible mediators of the “living” radical polymerization
  作者：M.V. Motyakin、A.M. Wasserman、P.E. Stott、G.E. Zaikov

  DOI：10.1016/j.saa.2005.10.007

  日期：2006.3

  The stable radicals derived from different compounds were detected in process of styrene autopolymerization. The nitroxide radicals are produced from nitrosocompound, hindered hydroxylamine, nitrophenols and nitroanisoles. The phenoxyl radicals are formed from quinine methides, and naphtoxyl radicals are generated from 2-nitro-1-naphtol. The radicals are identified, the kinetics of their formation and follow-up evolution are studied. These radicals can participate in process of living radical polymerization as the mediators and can effect significantly on kinetics of polymerization and structure of the resulting polymer. (c) 2006 Published by Elsevier B.V.
• Cholvad, Vlado; Stasko, Andrej; Tkac, Alexander, Collection of Czechoslovak Chemical Communications, 1981, vol. 46, # 4, p. 823 - 832
  作者：Cholvad, Vlado、Stasko, Andrej、Tkac, Alexander、Buchanenko, Anatolii L.、Malik, Lubomir

  DOI：——

  日期：——