5,10,15,20-tetrakis(p-[ω-methoxy poly(oxyethylene)]phenyl)porphyrin

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 5,10,15,20-tetrakis(p-[ω-methoxy poly(oxyethylene)]phenyl)porphyrin
• 英文别名: poly-{5-(4-acryloyloxyphenyl)-10,15,20-triphenylporphine}；carbon dioxide nitrogen hydrate I type；cyamelide
• 化学式: CHNO
• InChiKey: STURPKJTDSBKSC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.22
• 重原子数：
  3.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  66.5
• 氢给体数：
  1.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  5,10,15,20-tetrakis(p-[ω-methoxy poly(oxyethylene)]phenyl)porphyrin 、 cobalt(II) acetate 以 吡啶 为溶剂， 生成 cobalt(II)-5,10,15,20-tetrakis(p-[ω-methoxy poly(oxyethylene)]phenyl)porphyrin
  参考文献：
  名称：

  不带电荷的水溶性Co（II）-卟啉：芳香族α-氨基酸的受体。

  摘要：

  对于非手性5,10,15,20-四（{-ω-甲氧基聚（氧基-乙烯）]苯基}卟啉钴（II）（Co-P）和芳香族α-L-氨基酸（Trp和Phe）为Co-P和氨基酸之间的配位提供了直接证据。考虑到除Co原子（一个固定点系统）外，Co-P在分子中不包含活性配体基团，并且在Co-P / Ala的情况下未观察到ICD信号，因此得出结论卟啉的芳香环与Trp或Phe的芳香环之间的疏水相互作用或堆积相互作用，作为进一步的氨基酸（AA）固定点，可以大大降低手性客体的迁移率，因此可以产生ICD信号。还研究了pH（在2-9范围内）和氨基酸结构变化对ICD现象的影响。特别是，已观察到以下情况：（i）所有pH为7的Co-P / N-乙酰基氨基酸水溶液的强ICD信号，（ii）Co-P具有双符号形式的意外ICD带/ Ala溶液在长时间老化后的pH值为9，并且（iii）当使用alpha-D-Phe和alpha-D-Trp对

  DOI：

  10.1021/jp052408u
• 作为产物：
  描述：

  间苯二胺 在 iron(III) chloride hexahydrate 作用下， 生成 5,10,15,20-tetrakis(p-[ω-methoxy poly(oxyethylene)]phenyl)porphyrin
  参考文献：
  名称：

  高性能超级电容器用聚邻苯二胺衍生碳材料的集成合成

  摘要：

  具有优异电容性能的源自聚邻苯二胺（POPD）的功能性碳材料（见图）已通过集成的一步法成功合成，其中FeCl 3不仅能氧化有机单体的聚合反应，而且还能氧化有机单体的聚合反应。激活碳化。此外，大量研究证明，这种发现新型碳的策略不仅对电容器有用，而且对其他能量存储/转换设备也有用。

  DOI：

  10.1002/adma.201202461

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: NH4: MVol.2, 6, page 362 - 377
  作者：

  DOI：——

  日期：——
• Sinozaki, H.; Hara, R., Technology Reports of the Tohoku University, 1926, vol. 6, p. 117
  作者：Sinozaki, H.、Hara, R.

  DOI：——

  日期：——
• Structure and Guest Distribution of the Mixed Carbon Dioxide and Nitrogen Hydrates As Revealed by X-ray Diffraction and ¹³C NMR Spectroscopy
  作者：Yu-Taek Seo、Huen Lee

  DOI：10.1021/jp0351371

  日期：2004.1.1

  In this contribution, X-ray diffraction and C-13 NMR spectroscopy were used to identify structure and guest distribution of the mixed N-2 + CO2 hydrates. X-ray diffraction results of the mixed N-2 + CO2 hydrates confirmed that the unit cell parameter was similar to11.8 Angstrom over the gas mixture composition range of 3-20 mol % CO2 and the formed hydrates were identified as structure I. When the composition of the gas mixture was reduced to 1 mol % CO2, the structure of the mixed hydrate was transformed to structure II showing the unit cell parameter of 17.26(2) Angstrom. C-13 cross-polarization (CP) NMR spectroscopy was used to examine the distribution of carbon dioxide molecules in small 5(12) and large 5(12)6(2) cages of structure I. From NMR spectra of the mixed N-2 + CO2 hydrate formed from gas mixture of 20 and 10 MOl % CO2, powder patterns having chemical shift anisotropy of -54.5 and -53.8 ppm were observed, respectively. There was no clear isotropic line indicating carbon dioxide molecules in the small 5(12) cages of structure I. These NMR spectra showed that the carbon dioxide molecules occupied mainly the large 5(12)6(2) cages of structure I when the mixed N-2 + CO2 hydrate was formed at a vapor-phase composition range of 10-20 mol % CO2. In addition, from the analysis of the gases collected from a dissociating hydrate sample, the amount of carbon dioxide in the mixed N-2 + CO2 hydrates increased greatly with a small increase of carbon dioxide in the vapor phase. Accordingly, the carbon dioxide molecules seemed to occupy both the small and large cages of structure I above the vapor-phase composition of 33.3 mol % CO2.
• Integrated Synthesis of Poly(<i>o</i>-phenylenediamine)-Derived Carbon Materials for High Performance Supercapacitors
  作者：Hui Zhu、Xiaolei Wang、Xuexia Liu、Xiurong Yang

  DOI：10.1002/adma.201202461

  日期：2012.12.18

  Poly(o‐phenylenediamine) (POPD)‐derived functional carbon materials with excellent capacitive performance (see figure) are successfully synthesized by means of an integrated one‐step process, in which FeCl3 not only oxidizes the polymerization of the organic monomers but also activates the carbonization. Furthermore, extensive research has proved that this strategy to discover novel carbons is useful

  具有优异电容性能的源自聚邻苯二胺（POPD）的功能性碳材料（见图）已通过集成的一步法成功合成，其中FeCl 3不仅能氧化有机单体的聚合反应，而且还能氧化有机单体的聚合反应。激活碳化。此外，大量研究证明，这种发现新型碳的策略不仅对电容器有用，而且对其他能量存储/转换设备也有用。
• Uncharged Water-Soluble Co(II)−Porphyrin:  A Receptor for Aromatic α-Amino Acids
  作者：Nicola Angelini、Norberto Micali、Placido Mineo、Emilio Scamporrino、Valentina Villari、Daniele Vitalini

  DOI：10.1021/jp052408u

  日期：2005.10.1

  (Co-P) and aromatic alpha-L-amino acids (Trp and Phe) give direct evidence for the coordination between the Co-P and amino acids. Considering that Co-P, besides the Co atom (one-fixation-point system), does not contain in the molecule active ligand groups and that no ICD signals have been observed in the case of Co-P/Ala, it has been concluded that hydrophobic interactions or stacking interactions between

  对于非手性5,10,15,20-四（-ω-甲氧基聚（氧基-乙烯）]苯基}卟啉钴（II）（Co-P）和芳香族α-L-氨基酸（Trp和Phe）为Co-P和氨基酸之间的配位提供了直接证据。考虑到除Co原子（一个固定点系统）外，Co-P在分子中不包含活性配体基团，并且在Co-P / Ala的情况下未观察到ICD信号，因此得出结论卟啉的芳香环与Trp或Phe的芳香环之间的疏水相互作用或堆积相互作用，作为进一步的氨基酸（AA）固定点，可以大大降低手性客体的迁移率，因此可以产生ICD信号。还研究了pH（在2-9范围内）和氨基酸结构变化对ICD现象的影响。特别是，已观察到以下情况：（i）所有pH为7的Co-P / N-乙酰基氨基酸水溶液的强ICD信号，（ii）Co-P具有双符号形式的意外ICD带/ Ala溶液在长时间老化后的pH值为9，并且（iii）当使用alpha-D-Phe和alpha-D-Trp对