bis(nonafluoropentanoyl) peroxide | 308-29-2

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: bis(nonafluoropentanoyl) peroxide
• 英文别名: bis(nonafluoropentanoyl)peroxide；2,2,3,3,4,4,5,5,5-nonafluoropentanoyl 2,2,3,3,4,4,5,5,5-nonafluoropentaneperoxoate
• CAS: 308-29-2
• 化学式: C₁₀F₁₈O₄
• 分子量: 526.079
• InChiKey: UOFIMQWMHHYTIK-UHFFFAOYSA-N

物化性质

• 沸点：
  175.2±50.0 °C(Predicted)
• 密度：
  1.759±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  6.5
• 重原子数：
  32
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.8
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  22

安全信息

• 海关编码：
  2915900090

反应信息

• 作为反应物：
  描述：

  bis(nonafluoropentanoyl) peroxide 以 1,1,2-三氯三氟乙烷（CFC-113） 、 水 为溶剂， 生成 九氟戊酸
  参考文献：
  名称：

  Ostrizhko, F. N.; Yuminov, V. S.; Salivon, N. Ya., Journal of applied chemistry of the USSR, 1981, vol. 54, # 8, p. 1555 - 1559

  摘要：

  DOI：
• 作为产物：
  描述：

  perfluoropentanoic anhydride 在 C₄F₉COOK 、 双氧水 作用下， 以 水 为溶剂， 反应 0.17h， 生成 九氟戊酸 、 bis(nonafluoropentanoyl) peroxide
  参考文献：
  名称：

  A Novel Catalytic Pathway for Perfluoroacyl Peroxide Synthesis

  摘要：

  [GRAPHICS]A new catalytic method for synthesis of bis(perfluoroacyl) peroxides (BPFAP) was elaborated by using hydrogen peroxide and perfluoroacyl anhydrides. The desired BPFAP were formed quantitatively in situ when perfluoroacyl anhydride was mixed with hydrogen peroxide (ratio greater than or equal to 2:1) in the presence of a catalytic amount of the carboxylate RfCOO- M+. The essentially irreversible character of this process was shown experimentally and supported on the basis of DFT calculations. The synthesis of new acetyltrifluoroacetyl peroxides is also described.

  DOI：

  10.1021/ol016338v

文献信息

• Compositions including fluorinated peroxides, methods of making, and the use thereof
  申请人：——

  公开号：US20030004369A1

  公开（公告）日：2003-01-02

  Methods of making compositions including fluorinated peroxides are disclosed. The compositions are useful, for example, for reacting with organic compounds. In one embodiment, novel peroxides are provided.

  本发明公开了制备包括氟代过氧化物的组合物的方法。例如，这些组合物可用于与有机化合物反应。在一种实施方式中，提供了新型的过氧化物。
• Compounds with growth hormone releasing properties
  申请人：——

  公开号：US20030055261A1

  公开（公告）日：2003-03-20

  Compounds of peptide mimetic nature having the general formula I formula I 1 wherein a and b are independently 1 or 2, R 1 and R 2 are independently H or C 1-6 alkyl, G and J are independently, inter alia, aromats, and D and E are independently several different groups are growth hormone secretagogous with improved bioavailability.

  具有一般式I1的类肽类似物化合物，其中a和b独立地为1或2，R1和R2独立地为H或C1-6烷基，G和J独立地为芳香族等，D和E独立地为几种不同的基团，均为具有改善生物利用度的生长激素分泌剂。
• Process for preparation of fluorine-containing polymer films
  申请人：TOKUYAMA SODA KABUSHIKI KAISHA

  公开号：EP0155173A2

  公开（公告）日：1985-09-18

  A fluorine-containing polymer film is prepared by flow-casting a fluorine-containing vinyl monomer, which is liquid under polymerization conditions, in the form of a film having a thickness of up to 1 mm and polymerizing the flow-cast monomer.

  含氟聚合物薄膜的制备方法是将在聚合条件下呈液态的含氟乙烯基单体流延成厚度不超过 1 毫米的薄膜，然后将流延单体聚合。
• PERFLUOROALKYLATED NAPHTHALOCYANINE DERIVATIVE, PRODUCTION THEREOF, AND OPTICAL RECORDING MEDIUM
  申请人：NIPPON OIL AND FATS COMPANY, LIMITED

  公开号：EP0491951A1

  公开（公告）日：1992-07-01

  A perfluoroalkylated naphthalocyanine derivative which is excellent in weathering resistance and very highly soluble in various solvents and has a specified structure adapted for film formation; and an optical recording medium produced therefrom which enables recording by means of focused beams of a semiconductor laser. The above derivative is produced by the reaction of a perfluoroalkanoyl peroxide having a specified structure with a naphthalocyanine.

  一种全氟烷基化萘酞菁衍生物，其耐候性极佳，在各种溶剂中的溶解度极高，并具有适于成膜的特定结构；以及由其制成的一种光学记录介质，可通过半导体激光的聚焦光束进行记录。上述衍生物是由具有特定结构的全氟烷酰基过氧化物与萘酞菁反应生成的。
• PROCESS FOR PRODUCING TETRAFLUOROETHYLENE/HEXAFLUOROPROPYLENE COPOLYMER
  申请人：DAIKIN INDUSTRIES, LIMITED

  公开号：EP0606492A1

  公开（公告）日：1994-07-20

  A process for producing a tetrafluoroethylene/hexafluoropropylene copolymer by copolymerizing tetrafluoroethylene with hexafluoropropylene in an aqueous medium using di(fluoroacyl) peroxide as the polymerization initiator, wherein a fluoroalkylcarboxylic acid is fed to the reaction system. The obtained copolymer has a stabilized molecular weight and the polymerization initiator can be utilized more efficiently.

  一种生产四氟乙烯/六氟丙烯共聚物的工艺，其方法是使用二（氟酰基）过氧化物作为聚合引发剂，在水介质中使四氟乙烯与六氟丙烯共聚，其中向反应体系加入氟烷基羧酸。得到的共聚物分子量稳定，聚合引发剂的使用效率更高。