4-((2',4'-Dinitrophenyl)azo)-2-((octadecylamino)carbonyl)-1-naphthol | 144883-71-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 4-((2',4'-Dinitrophenyl)azo)-2-((octadecylamino)carbonyl)-1-naphthol
• 英文别名: 4-[(2,4-dinitrophenyl)diazenyl]-1-hydroxy-N-octadecylnaphthalene-2-carboxamide
• CAS: 144883-71-6
• 化学式: C₃₅H₄₇N₅O₆
• 分子量: 633.788
• InChiKey: ARYKRSZPKQOUQD-UHFFFAOYSA-N

物化性质

• 沸点：
  784.4±60.0 °C(Predicted)
• 密度：
  1.20±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  12.9
• 重原子数：
  46
• 可旋转键数：
  20
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.51
• 拓扑面积：
  166
• 氢给体数：
  2
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  1-羟基-2-萘甲酸 在 硫酸 、 sodium carbonate 、 N,N'-二环己基碳二亚胺 、 sodium nitrite 作用下， 以 四氢呋喃 为溶剂， 反应 4.17h， 生成 4-((2',4'-Dinitrophenyl)azo)-2-((octadecylamino)carbonyl)-1-naphthol
  参考文献：
  名称：

  Novel type of ion-selective fluorosensor based on the inner filter effect: an optrode for potassium

  摘要：

  An optrode for potassium ion has been designed that exploits the inner filter effect (IFE) of fluorescence. The sensing scheme makes use of neutral ion carriers as described by Simon et al., but transduction is based on the use of two different dyes, viz. an absorber and a fluorescer. The absorber acts as the proton carrier, while the other is a stable and pH-independent fluorophore bound to minute particles contained in the sensor membrane. Fluorescence varies as a result of the varying absorption of the dye which in turn is modulated by the potassium concentration through the IFE. The sensor material is extremely sensitive to potassium to which it fully reversibly responds over the 1 muM to 10 mM concentration range with a useful dynamic range from 1 muM to 1 mM. The sensing approach presented here is generic in that it can be applied to almost any species for which respective carriers are known. Thus, by replacing valinomycin by carriers for ammonium and calcium ion, respective ion sensors are obtained without requiring any changes in the optical system.

  DOI：

  10.1021/ac00050a006