diiodo(N-phenylethane-1,2-diamine)platinum(II) | 207923-11-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二苯乙烯类
• 英文名称: diiodo(N-phenylethane-1,2-diamine)platinum(II)
• CAS: 207923-11-3
• 化学式: C₈H₁₂I₂N₂Pt
• 分子量: 585.086
• InChiKey: RTDLYGFMGBZCEK-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  吡啶 、 六氟苯 、 diiodo(N-phenylethane-1,2-diamine)platinum(II) 在 Tl₂CO₃ 作用下， 以 吡啶 为溶剂， 以32%的产率得到[N-(pentafluorophenyl)-N'-(phenyl)ethane-1,2-diaminato(2-)]dipyridineplatinum(II)
  参考文献：
  名称：

  Organoamidometallics—VI. A new synthetic route to [N,N′-bis(polyfluorophenyl)ethane-1,2-diaminato(2-)]dipyridineplatinum(II) complexes and the preparation of [N-phenyl-N′-(polyfluorophenyl)ethane-1,2-diaminato(2-)] dipyridineplatinum(II) complexes

  摘要：

  Reaction of [Pt(en)Cl-2] (en = ethane-1,2-diamine) with thallium(I) carbonate (or in some cases K2CO3) and a polyfluorobenzene in hot pyridine (py) or 3-methylpyridine (tmpy) yields the [N,N'-bis (polyfluorophenyl)ethane-1,2-diaminato(2-)]platinum(II) complexes, [Pt{N(R)CH2}(2)L-2] (L = py, R = p-HC6F4. C6F5, p-BrC6F4, p-IC6F4, p-MeC6F4, p-C6F5C6F4, 2,3,5-F3C6H2, p-O(H)CC6F4, p-MeOC6F4; L = tmpy, R = p-HC6F4). Yields were markedly greater with the use of Tl2CO3 than reported for reactions of [Pt(en)Cl-2] with thallium(I) polyfluorobenzoates. A new class of platinum(II) amides, namely [N-(phenyl)-N'-(polyfluorophenyl)ethane-1,2-diaminato (2-)]platinum(II) complexes, [Pt{N(Ph)CH2CH2N(R)}L-2] (L = py, R = p-HC6F4, C6F5, p-MeC6F4, B-ClC6F4, p-BrC6F4; L = 4-methylpyridine, R = p-HC6F4): has been prepared by reaction of [Pt(PhNHCH2CH2NH2)I-2] with Tl2CO3 or a thallium(I) polyfluorobenzoate and a polyfluoroaromatic compound in pyridine or 4-methylpyridine. The complexes where R = p-MeC6F4, p-ClC6F4, p-BrC6F4 could be prepared only with Tl2CO3, which also provided cleaner products where both routes were used. The crystal structure of [Pt{N(Ph)CH2CH2N(p-MeC6F4)}(py)(2)] has been determined and shows a slightly distorted square planar coordination for platinum, with two amide and two cis pyridine nitrogen donors. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00310-0
• 作为产物：
  描述：

  potassium tetrachloroplatinate(II) 、 N-苯基乙二胺 、 potassium iodide 以 水 为溶剂， 以90%的产率得到diiodo(N-phenylethane-1,2-diamine)platinum(II)
  参考文献：
  名称：

  Organoamidometallics—VI. A new synthetic route to [N,N′-bis(polyfluorophenyl)ethane-1,2-diaminato(2-)]dipyridineplatinum(II) complexes and the preparation of [N-phenyl-N′-(polyfluorophenyl)ethane-1,2-diaminato(2-)] dipyridineplatinum(II) complexes

  摘要：

  Reaction of [Pt(en)Cl-2] (en = ethane-1,2-diamine) with thallium(I) carbonate (or in some cases K2CO3) and a polyfluorobenzene in hot pyridine (py) or 3-methylpyridine (tmpy) yields the [N,N'-bis (polyfluorophenyl)ethane-1,2-diaminato(2-)]platinum(II) complexes, [Pt{N(R)CH2}(2)L-2] (L = py, R = p-HC6F4. C6F5, p-BrC6F4, p-IC6F4, p-MeC6F4, p-C6F5C6F4, 2,3,5-F3C6H2, p-O(H)CC6F4, p-MeOC6F4; L = tmpy, R = p-HC6F4). Yields were markedly greater with the use of Tl2CO3 than reported for reactions of [Pt(en)Cl-2] with thallium(I) polyfluorobenzoates. A new class of platinum(II) amides, namely [N-(phenyl)-N'-(polyfluorophenyl)ethane-1,2-diaminato (2-)]platinum(II) complexes, [Pt{N(Ph)CH2CH2N(R)}L-2] (L = py, R = p-HC6F4, C6F5, p-MeC6F4, B-ClC6F4, p-BrC6F4; L = 4-methylpyridine, R = p-HC6F4): has been prepared by reaction of [Pt(PhNHCH2CH2NH2)I-2] with Tl2CO3 or a thallium(I) polyfluorobenzoate and a polyfluoroaromatic compound in pyridine or 4-methylpyridine. The complexes where R = p-MeC6F4, p-ClC6F4, p-BrC6F4 could be prepared only with Tl2CO3, which also provided cleaner products where both routes were used. The crystal structure of [Pt{N(Ph)CH2CH2N(p-MeC6F4)}(py)(2)] has been determined and shows a slightly distorted square planar coordination for platinum, with two amide and two cis pyridine nitrogen donors. (C) 1998 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0277-5387(97)00310-0