N3,N3,N7,N7-tetramethyl-2,4,6,8-tetraoxa-3,7-diphospha-1,5(1,6)-dinaphthalenacyclooctaphane-3,7-diamine | 863650-39-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: N3,N3,N7,N7-tetramethyl-2,4,6,8-tetraoxa-3,7-diphospha-1,5(1,6)-dinaphthalenacyclooctaphane-3,7-diamine
• CAS: 863650-39-9
• 化学式: C₂₄H₂₄N₂O₄P₂
• 分子量: 466.413
• InChiKey: AQHPLULYGPEQIW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.85
• 重原子数：
  32.0
• 可旋转键数：
  2.0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  59.04
• 氢给体数：
  0.0
• 氢受体数：
  6.0

反应信息

• 作为反应物：
  描述：

  N3,N3,N7,N7-tetramethyl-2,4,6,8-tetraoxa-3,7-diphospha-1,5(1,6)-dinaphthalenacyclooctaphane-3,7-diamine 在 sulfur 作用下， 以 二氯甲烷 为溶剂， 反应 24.0h， 以80%的产率得到C₂₄H₂₄N₂O₄P₂S₂
  参考文献：
  名称：

  2,6- and 1,6-Dihydroxynaphthalenes in the Synthesis of Phosphacyclophanes

  摘要：

  Peculiar phosphacyclophanes were prepared from symmetrical 2,6- and unsymmetrical 1,6-dihydroxynaphthalenes. The position of the hydroxy groups in dihydroxynaphthalenes considerably affects their reactivity, the structure of the phosphacyclophanes obtained, and also the disproportionation of bisphosphoramidites. Oxo and thio derivatives of these phosphoramidites as well as their molybdenum complexes were prepared.

  DOI：

  10.1023/b:rugc.0000045868.37162.87
• 作为产物：
  描述：

  1,6-二羟基萘 、 三(二甲胺基)膦 以 乙腈 为溶剂， 反应 24.0h， 以70%的产率得到N3,N3,N7,N7-tetramethyl-2,4,6,8-tetraoxa-3,7-diphospha-1,5(1,6)-dinaphthalenacyclooctaphane-3,7-diamine
  参考文献：
  名称：

  2,6- and 1,6-Dihydroxynaphthalenes in the Synthesis of Phosphacyclophanes

  摘要：

  Peculiar phosphacyclophanes were prepared from symmetrical 2,6- and unsymmetrical 1,6-dihydroxynaphthalenes. The position of the hydroxy groups in dihydroxynaphthalenes considerably affects their reactivity, the structure of the phosphacyclophanes obtained, and also the disproportionation of bisphosphoramidites. Oxo and thio derivatives of these phosphoramidites as well as their molybdenum complexes were prepared.

  DOI：

  10.1023/b:rugc.0000045868.37162.87