F-N,N-dimethyl-n-butylamine | 103217-80-7

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 卤代烷
• 英文名称: F-N,N-dimethyl-n-butylamine
• 英文别名: Perfluor-N,N-dimethyl-n-butylamin；1,1,2,2,3,3,4,4,4-nonafluoro-N,N-bis(trifluoromethyl)butan-1-amine
• CAS: 103217-80-7
• 化学式: C₆F₁₅N
• 分子量: 371.049
• InChiKey: CKWDXIIKKRRLCW-UHFFFAOYSA-N

物化性质

• 沸点：
  66.1±35.0 °C(Predicted)
• 密度：
  1.711±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  22
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  16

反应信息

• 作为反应物：
  描述：

  F-N,N-dimethyl-n-butylamine 在 五氯化钼 硫酸 作用下， 反应 24.0h， 以39.3%的产率得到perfluoro(N-methyl,N-n-butylcarbamoyl fluoride)
  参考文献：
  名称：

  通过全氟（N，N-二烷基甲基胺）与发烟硫酸的反应合成全氟（N，N-二烯丙基氨基甲酰氟）

  摘要：

  一种方便的一步制备新的全氟（N，N-二烷基氨基甲酰氟）[二烷基：R f = R'f = C 2 F 5（1b）; R f＝ C 2 F 5，R′f＝ C 3 F 7（2b）；ř ˚F = R' ˚F = NC 3 ˚F 7（图3b）; ř ˚F = NC 3 ˚F 7，R' ˚F = NC 4 ˚F 9（图4b）; ř ˚F = NC 3 ˚F 7，R' ˚F = NC 5F 11（5b）；ř ˚F = R' ˚F = NC 4 ˚F 9 6B; ř ˚F = NC 3 ˚F 7，R' ˚F = CF 3（图7b）; R f＝ nC 4 F 9 R′＝ CF 3（8b）；ř ˚F = NC 5 ˚F 11，R' ˚F = CF 3（9B）]中描述了：全氟对应（N，N-dialkylmethylamines）用发烟硫酸处理。催化剂（HgSO 4和MoCl 5）提高了所得产品的收率和纯度。描述

  DOI：

  10.1016/s0022-1139(00)84155-x
• 作为产物：
  描述：

  N,N-二甲基丁胺 、 氢氟酸 以12%的产率得到
  参考文献：
  名称：

  ABE, TAKASHI;HAYASHI, EIJI;BABA, HAJIME;NAGASE, SHUNJI, J. CHEM. SOC. JAP., CHEM. AND IND. CHEM., 1985, N 10, 1980-1987

  摘要：

  DOI：

文献信息

• Electrochemical fluorination of (N,N-dialkylamino)alcohols
  作者：Takashi Abe、Haruhiko Fukaya、Eiji Hayashi、Taizo Ono、Masakazu Nishida、Irina Soloshonok、Kunio Okuhara

  DOI：10.1016/s0022-1139(99)00053-6

  日期：1999.7

  Series of amino alcohols including 2-(N,N-dialkylamino)ethanols, 3-(N,N-dimethylamino)propanol and 4-(N,N-dimethylamino)butanol were subjected to electrochemical fluorination. In the case of 2-(N,N-dialkylamino)ethanols, the F-(2-N, N-dialkylamino) acetyl fluorides were obtained in fair to good yields. Yields of each target compound were strongly dependent on the kind of the dialkylamino group. Cyclic amines having an N-(2-hydroxylethyl) group afforded the corresponding F-[N-(c-alkylamino)-substituted acetyl fluorides]. Their yields were generally better than those of acyclic analogs. Several 2-(N,N-dialkylamino)ethanols and 3-(N,N-dimethylamino)propanol were converted into the corresponding trimethylsilylethers, aminoalkyl methyl carbonates and bis-aminoalkyl carbonate, respectively, and they were subjected to fluorination for a comparison of the yield with that obtained from that of the parent aminoalcohol. (C) 1999 Elsevier Science S.A. All rights reserved.
• ABE, TAKASHI;HAYASHI, EIJI, J. FLUOR. CHEM., 45,(1989) N, C. 293-311
  作者：ABE, TAKASHI、HAYASHI, EIJI

  DOI：——

  日期：——
• COMPOSITE MOLDED BODY WITH A LAYER OF A COPOLYMER OF TETRAFLUOROETHYLENE AND PERFLUORO(ETHYL VINYL ETHER)
  申请人：Du Pont-Mitsui Fluorochemicals Co. Ltd.

  公开号：EP3122557A1

  公开（公告）日：2017-02-01
• COMPOSITE MOLDED BODY OF A COPOLYMER OF TETRAFLUOROETHYLENE AND PERFLUORO(ETHYL VINYL ETHER)
  申请人：Dupont Mitsui Fluorochemicals Co., Ltd.

  公开号：US20160185995A1

  公开（公告）日：2016-06-30

  A composite molded body, and its manufacturing method, is provided wherein the composite body contains a layer comprising a copolymer of tetrafluoroethylene (TFE) and perfluoro(ethyl vinyl ether) (PEVE). The composite body can be manufactured under conditions in which an adjoined layer of thermoplastic resin and/or thermosetting resin is not be melted, thermally degraded or decomposed. The copolymer has a PEVE content of 20 to 80 weight percent, based on the total weight of the copolymer, and a melt flow rate of from 0.1 to 100 g/10 min, as measured in compliance with ASTM D1238 at a temperature of 250° C.±0.1 using a 5 kg weight.
• [EN] COMPOSITE MOLDED BODY WITH A LAYER OF A COPOLYMER OF TETRAFLUOROETHYLENE AND PERFLUORO(ETHYL VINYL ETHER)<br/>[FR] CORPS MOULÉ COMPOSITE POURVU D'UNE COUCHE D'UN COPOLYMÈRE DE TÉTRAFLUOROÉTHYLÈNE ET DE PERFLUORO(ÉTHYLVINYLÉTHER)
  申请人：MITSUI DU PONT FLUORCHEMICAL

  公开号：WO2015148285A1

  公开（公告）日：2015-10-01

  A composite molded body, and its manufacturing method, is provided wherein the composite body contains a layer comprising a copolymer of tetrafluoroethylene (TFE) and perfluoro(ethyl vinyl ether) (PEVE). The composite body can be manufactured under conditions in which an adjoined layer of thermoplastic resin and/or thermosetting resin is not be melted, thermally degraded or decomposed. The copolymer has a PEVE content of 20 to 80 weight percent, based on the total weight of the copolymer, and a melt flow rate of from 0.1 to 100 g/10 min, as measured in compliance with ASTM D1238 at a temperature of 250°C ± 0.1 using a 5 kg weight.