(Et4N)2S

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: (Et4N)2S
• 英文别名: Tetraethylazanium;sulfide；tetraethylazanium;sulfide
• 化学式: 2C₈H₂₀N*S
• 分子量: 292.573
• InChiKey: UKPQUUGIEQBCPE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.88
• 重原子数：
  10
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  二硫化碳 、 (Et4N)2S 反应 4.0h， 以53%的产率得到
  参考文献：
  名称：

  Crystal structures of (Et ₄ N) ₂ C ₂ S ₆ , (Et ₄ N) ₂ C ₂ S ₅ , (Et ₄ N) ₂ CS ₄ , (Et ₄ N)HCS ₃ , (Et ₄ N) ₂ CS ₃  ⋅ 2H ₂ O and (Et ₄ N) ₂ CS _4‐y  ⋅ yH ₂ O (y=0.69).

  摘要：

  AbstractThe crystal structures of (Et4N)2C2S6, (Et4N)2C2S5, (Et4N)2CS4, (Et4N)HCS3, (Et4N)2CS3 ⋅ 2H2O and (Et4N)2CS4‐y ⋅ yH2O (y=0.69) were determined by single‐crystal X‐ray diffraction analysis at 150 K. For the first time, salts with the C2S52− and HCS3− anions could be synthesized.

  DOI：

  10.1002/zaac.202100001
• 作为产物：
  描述：

  四乙基氢氧化铵 在 硫化氢 作用下， 生成 (Et4N)2S
  参考文献：
  名称：

  Crystal structures of (Et ₄ N) ₂ C ₂ S ₆ , (Et ₄ N) ₂ C ₂ S ₅ , (Et ₄ N) ₂ CS ₄ , (Et ₄ N)HCS ₃ , (Et ₄ N) ₂ CS ₃  ⋅ 2H ₂ O and (Et ₄ N) ₂ CS _4‐y  ⋅ yH ₂ O (y=0.69).

  摘要：

  AbstractThe crystal structures of (Et4N)2C2S6, (Et4N)2C2S5, (Et4N)2CS4, (Et4N)HCS3, (Et4N)2CS3 ⋅ 2H2O and (Et4N)2CS4‐y ⋅ yH2O (y=0.69) were determined by single‐crystal X‐ray diffraction analysis at 150 K. For the first time, salts with the C2S52− and HCS3− anions could be synthesized.

  DOI：

  10.1002/zaac.202100001

文献信息

• [EN] BICYCLYL-SUBSTITUTED ISOTHIAZOLINE COMPOUNDS<br/>[FR] COMPOSÉS ISOTHIAZOLINE SUBSTITUÉS PAR UN BICYCLYLE
  申请人：BASF SE

  公开号：WO2014206910A1

  公开（公告）日：2014-12-31

  The present invention relates to bicyclyl-substituted isothiazoline compounds of formula (I) wherein the variables are as defined in the claims and description. The compounds are useful for combating or controlling invertebrate pests, in particular arthropod pests and nematodes. The invention also relates to a method for controlling invertebrate pests by using these compounds and to plant propagation material and to an agricultural and a veterinary composition comprising said compounds.

  本发明涉及公式（I）中变量如索权和说明中所定义的自行车基取代异噻唑啉化合物。这些化合物对抗或控制无脊椎动物害虫，特别是节肢动物害虫和线虫方面具有用途。该发明还涉及一种通过使用这些化合物来控制无脊椎动物害虫的方法，以及包含所述化合物的植物繁殖材料、农业和兽医组合物。
• [EN] THIOPHENE- OR FURAN-SUBSTITUTED ISOTHIAZOLINE COMPOUNDS AS PESTICIDES<br/>[FR] COMPOSÉS ISOTHIAZOLINE SUBSTITUÉS PAR UN THIOPHÈNE OU UN FURANE COMME PESTICIDES
  申请人：BASF SE

  公开号：WO2014206909A1

  公开（公告）日：2014-12-31

  The present invention relates to thiophene- or furan-substituted isothiazoline compounds of formula I wherein the variables are as defined in the claims and description. The compounds are useful for combating or controlling invertebrate pests, in particular arthropod pests and nematodes. The invention also relates to a method for controlling invertebrate pests by using these compounds and to plant propagation material and to an agricultural and a veterinary composition comprising said compounds.

  本发明涉及式I的噻吩或呋喃取代的异噻唑啉化合物，其中变量如权利要求和描述中所定义。这些化合物对抗或控制无脊椎动物害虫，特别是节肢动物害虫和线虫方面具有用途。该发明还涉及一种通过使用这些化合物来控制无脊椎动物害虫的方法，以及包括所述化合物的植物繁殖材料、农业和兽医组合物。
• [EN] METHODS FOR PREPARATION OF FLUORINATED SULFUR-CONTAINING COMPOUNDS<br/>[FR] PROCÉDÉ DE PRÉPARATION DE COMPOSÉS FLUORÉS CONTENANT DU SOUFRE
  申请人：DU PONT

  公开号：WO2015051141A1

  公开（公告）日：2015-04-09

  Methods for preparing fluorinated sulfides and fluorinated sulfones are described. To prepare a fluorinated sulfides, a sulfur-containing reactant represented by the formula: R1SM or M2S, wherein R1 is a C1 to C10 alkyl or fluoroalkyl, S is sulfur, and M is a cation, is reacted with a fluorinated alkyl compound. A fluorinated sulfone is formed by oxidizing the fluorinated sulfide. The fluorinated sulfones prepared by the methods disclosed herein are particularly useful as electrolyte solvents for electrochemical cells, such as a lithium ion battery, where a high purity solvent is desired.

  描述了制备氟硫化物和氟磺酮的方法。要制备氟硫化物，将表示为R1SM或M2S的含硫反应物（其中R1是C1到C10的烷基或氟烷基，S是硫，M是阳离子）与氟化烷基化合物发生反应。通过氧化氟硫化物形成氟磺酮。根据本公开的方法制备的氟磺酮在电化学电池等电化学电池中特别适用作电解质溶剂，其中需要高纯度溶剂。
• [EN] NONAQUEOUS ELECTROLYTE COMPOSITIONS COMPRISING FLUORINATED SULFONES<br/>[FR] COMPOSITIONS D'ÉLECTROLYTE NON AQUEUSES COMPRENANT DES SULFONES FLUORÉS
  申请人：DU PONT

  公开号：WO2017209762A1

  公开（公告）日：2017-12-07

  Disclosed herein are electrolyte compositions comprising a fluorinated solvent, a fluorinated sulfone, at least one component selected from a borate salt, and/or an oxalate salt, and/or a fluorinated cyclic carbonate, and at least one electrolyte salt. The fluorinated solvent may be a fluorinated acyclic carboxylic acid ester, a fluorinated acyclic carbonate, a fluorinated acyclic ether, or combinations thereof. The electrolyte compositions are useful in electrochemical cells, such as lithium ion batteries.

  本文揭示了包括氟化溶剂、氟化砜、至少一种硼酸盐、和/或草酸盐、和/或氟化环状碳酸酯、以及至少一种电解质盐的电解质组合物。氟化溶剂可以是氟化非环状羧酸酯、氟化非环状碳酸酯、氟化非环状醚，或其组合物。这些电解质组合物在电化学电池（如锂离子电池）中有用。
• [EN] ISOTHIAZOLINE COMPOUNDS SUBSTITUTED WITH A CARBOBICYCLIC GROUP<br/>[FR] COMPOSÉS ISOTHIAZOLINE SUBSTITUÉS PAR UN GROUPE CARBOBICYCLIQUE
  申请人：BASF SE

  公开号：WO2014206908A1

  公开（公告）日：2014-12-31

  The present invention relates to isothiazoline compounds substituted with a carbobicyclic group of formula (I) wherein the variables are as defined in the claims and description. The compounds are useful for combating or controlling invertebrate pests, in particular arthropod pests and nematodes. The invention also relates to a method for controlling invertebrate pests by using these compounds and to plant propagation material and to an agricultural and a veterinary composition comprising said compounds.

  本发明涉及一种具有化学式（I）的含有碳环族取代基的异噻唑啉化合物，其中变量如权利要求和描述中所定义。这些化合物对抗或控制无脊椎动物害虫，特别是节肢动物害虫和线虫具有用处。本发明还涉及一种利用这些化合物控制无脊椎动物害虫的方法，以及包含该化合物的植物繁殖材料、农业和兽医组合物。