2,3-dichlorodiphenyl ether | 68486-28-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,3-dichlorodiphenyl ether
• 英文别名: 2,3-dichlorodiphenyl oxide；dichlorodiphenyloxide；1-Phenoxy-2,3-dichlorbenzol；2,3-Dichlordiphenylether；1,2-dichloro-3-phenoxybenzene
• CAS: 68486-28-2
• 化学式: C₁₂H₈Cl₂O
• 分子量: 239.101
• InChiKey: VSKSUBSGORDMQX-UHFFFAOYSA-N

物化性质

• 沸点：
  299.6±30.0 °C(Predicted)
• 密度：
  1.300±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  碘苯 、 二氯-苯酚 在 sodium hydroxide 作用下， 以 neat (no solvent) 为溶剂， 反应 6.0h， 以95%的产率得到2,3-dichlorodiphenyl ether
  参考文献：
  名称：

  固定在胺基磁性金属-有机骨架上的 CoII：一种在无溶剂条件下用于 C-O 交叉偶联反应的高效多相纳米结构催化剂

  摘要：

  在本文中，我们报道了基于金属-有机骨架结构的 Fe3O4@AMCA-MIL53(Al)-NH2-CoII NPs 的合成，作为一种磁性可分离且环境友好的多相纳米催化剂。制备的纳米结构催化剂在无溶剂条件下有效地促进了 C-O 交叉偶联反应，而无需使用有毒溶剂和/或昂贵的钯催化剂。

  DOI：

  10.1007/s10562-019-03070-5

文献信息

• [EN] (R)-CHIRAL HALOGENATED 1-SUBSTITUTEDAMINO-(n+1)-ALKANOLS USEFUL FOR INHIBITING CHOLESTERYL ESTER TRANSFER PROTEIN ACTIVITY<br/>[FR] AMINO-(N+1)-ALCANOLS 1-SUBSTITUES HALOGENES R-CHIRAUX, UTILES COMME INHIBITEURS DE L'ACTIVITE DE LA PROTEINE DE TRANSFERT DE L'ESTER DE CHOLESTERYLE
  申请人：MONSANTO CO

  公开号：WO2000018724A1

  公开（公告）日：2000-04-06

  The invention relates to substituted aryl and heteroaryl (R)-Chiral Halogenated 1-Substitutedamino-(n+1)-Alkanol compounds useful as inhibitors of cholesteryl ester transfer protein (CETP; plasma lipid transfer protein-I) and compounds, compositions and methods for treating atherosclerosis and other coronary artery diseases. Novel high yield, stereoselective processes for the preparation of the chiral substituted alkanol compounds from chiral and achiral intermediates are described.

  本发明涉及取代芳基和杂环芳基(R)-手性卤代1-取代氨基-(n+1)-脂肪醇化合物，用于抑制胆固醇酯转移蛋白(CETP;血浆脂质转移蛋白-I)以及用于治疗动脉硬化和其他冠状动脉疾病的化合物、组合物和方法。本发明还描述了从手性和非手性中间体制备手性取代脂肪醇化合物的新型高产率、立体选择性过程。
• PROCESS FOR OBTAINING MALEIC ANHYDRIDE BY DISTILLATION
  申请人：Windecker Gunther

  公开号：US20100113805A1

  公开（公告）日：2010-05-06

  What is described is a process for obtaining maleic anhydride by distillation from a solution of maleic anhydride in a high-boiling absorbent which has been obtained by gas phase oxidation of a hydrocarbon and at least partial absorption of the oxidation products into the absorbent, by i) introducing the solution into the side of a feed column with a rectifying section disposed above the feed point and a stripping section disposed below the feed point, ii) providing an upper combining column which communicates with the upper end of the rectifying section and a lower combining column which communicates with the lower end of the stripping section, iii) providing a draw column which communicates with the upper combining column and the lower combining column, iv) drawing maleic anhydride off as a side draw from the draw column, and drawing off compounds having a lower boiling point than maleic anhydride at the top of the upper combining column and the high-boiling absorbent at the bottom of the lower combining column. The maleic anhydride obtained as a side draw has a low content of acrylic acid and acetic acid.

  所描述的是一种从高沸点吸收剂中的马来酸酐溶液中通过蒸馏获取马来酸酐的过程，该吸收剂是通过气相氧化烃类并至少部分吸收氧化产物而获得的，其步骤包括：i）将溶液引入具有上置精馏段和下置脱馏段的进料柱的侧面，ii）提供一个与上部的精馏段相通的上部组合柱和一个与下部的脱馏段相通的下部组合柱，iii）提供一个与上部组合柱和下部组合柱相通的取出柱，iv）从取出柱侧面取出马来酸酐，并从上部组合柱的顶部和下部组合柱的底部取出比马来酸酐沸点低的化合物和高沸点吸收剂。作为侧面取出的马来酸酐含有较低的丙烯酸和乙酸含量。
• Electrostatographic toner composition
  申请人：XEROX CORPORATION

  公开号：EP0021851A1

  公开（公告）日：1981-01-07

  An electrostatographic toner composition including a colorant and a resin, the resin being a polyether polymer containing repeating units of the following formula: wherein R is a residue remaining subsequent to the removal of the hydroxyl groups from a dihydric phenol, R" is an aryl or alkyl radical, Z is the residue remaining subsequent to the removal of the hydroxyl groups from an alkylene ether glycol of the formula wherein R' is a hydrogen atom, or methyl, n is an integer having a value of 2 to 4, and m is a number such that the polyether polymer has a reduced viscosity of from 0.2 to 0.6.

  一种电显影调色剂组合物，包括着色剂和树脂，树脂是一种含有下式重复单元的聚醚聚合物： 其中 R 是二水酚去除羟基后的残留物，R "是芳基或烷基，Z 是如下式的烷基醚二醇去除羟基后的残留物 其中 R'是氢原子或甲基，n 是数值为 2 至 4 的整数，m 是使聚醚聚合物的粘度降低到 0.2 至 0.6 的数值。
• Process for producing aromatic sulfide polymers
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0079144A1

  公开（公告）日：1983-05-18

  An aromatic sulfide polymer, from which molded articles can be prepared, is produced by reacting together in an organic solvent elemental sulfur, a polyhalogen-substituted aromatic compound, an aldehyde or condensate thereof as a reductant to remove excess oxygen and a caustic alkali as a scavenger for gaseous carbon dioxide.

  芳香族硫化物聚合物是通过将元素硫、多卤素取代的芳香族化合物、作为还原剂以除去过量氧气的醛或其缩合物以及作为气态二氧化碳清除剂的苛性碱在有机溶剂中一起反应而制得的，用这种聚合物可以制备模塑制品。
• Process for production of high to ultra-high molecular weight linear polyarylenesulfides
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0166368A2

  公开（公告）日：1986-01-02

  By maintaining an arylenesulfide prepolymer with a melt viscosity of 5 to 3,000 poise at a temperature of 245 to 290 °C under a liquid-liquid two-phase separated state in a solvent for 1 to 50 hours, the molecular weight of said prepolymer is increased to a high to ultra-high value while the linearity of the polymer is retained.

  在 245 至 290 °C 的温度下，将熔融粘度为 5 至 3,000 poise 的亚芳基硫醚预聚物在溶剂中以液液两相分离的状态保持 1 至 50 小时，可将所述预聚物的分子量提高到高至超高值，同时保持聚合物的线性。