(silver(I))(5,5-diethylbarbiturate)(pyridine-2-ylmethanol)*H2O | 1190836-13-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 咪唑并吡啶类
• 英文名称: (silver(I))(5,5-diethylbarbiturate)(pyridine-2-ylmethanol)*H2O
• CAS: 1190836-13-5
• 化学式: C₁₄H₁₈AgN₃O₄*H₂O
• 分子量: 418.198
• InChiKey: JNDVIDQLKBIPRY-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  (silver(I))(5,5-diethylbarbiturate)(pyridine-2-ylmethanol)*H2O 以 neat (no solvent, solid phase) 为溶剂， 生成 银
  参考文献：
  名称：

  Two-dimensional supramolecular networks generated from weak Ag⋯Cpy interactions: Synthesis, structural, thermal and fluorescence studies of silver(I) complexes of 5,5-diethylbarbiturato with pyridine-2-ylmethanol and 2,6-dimethoxypyridine

  摘要：

  Two new silver(I) complexes [Ag(barb)(pym)]center dot H2O (1) and [Ag(barb)(dmpy)]center dot 1.5H(2)O (2) (barb = 5,5-diethylbarbiturate, pym = pyridine-2-ylmethanol and dmpy = 2,6-dimethoxypyridine) have been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. In both complexes, the silver(I) ions are linearly coordinated by the N atoms of a barb anion and a pym or a dmpy ligand, forming mononuclear species. The molecules of 1 and 2 are doubly bridged by N-H center dot center dot center dot O hydrogen bonds involving the barb moieties and these hydrogen-bonded dimers are assembled into two-dimensional layered networks through weak Ag center dot center dot center dot C-py (eta(1)) interactions of ca. 3.3 angstrom. Additionally, the thermal and fluorescent properties of these complexes are also investigated. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.06.006
• 作为产物：
  描述：

  2-吡啶甲醇 、 水 、 sodium barbital 、 silver nitrate 以 水 、 异丙醇 、 乙腈 为溶剂， 以77%的产率得到(silver(I))(5,5-diethylbarbiturate)(pyridine-2-ylmethanol)*H2O
  参考文献：
  名称：

  Two-dimensional supramolecular networks generated from weak Ag⋯Cpy interactions: Synthesis, structural, thermal and fluorescence studies of silver(I) complexes of 5,5-diethylbarbiturato with pyridine-2-ylmethanol and 2,6-dimethoxypyridine

  摘要：

  Two new silver(I) complexes [Ag(barb)(pym)]center dot H2O (1) and [Ag(barb)(dmpy)]center dot 1.5H(2)O (2) (barb = 5,5-diethylbarbiturate, pym = pyridine-2-ylmethanol and dmpy = 2,6-dimethoxypyridine) have been synthesized and characterized by elemental analysis, IR spectroscopy and single crystal X-ray diffraction. In both complexes, the silver(I) ions are linearly coordinated by the N atoms of a barb anion and a pym or a dmpy ligand, forming mononuclear species. The molecules of 1 and 2 are doubly bridged by N-H center dot center dot center dot O hydrogen bonds involving the barb moieties and these hydrogen-bonded dimers are assembled into two-dimensional layered networks through weak Ag center dot center dot center dot C-py (eta(1)) interactions of ca. 3.3 angstrom. Additionally, the thermal and fluorescent properties of these complexes are also investigated. (C) 2009 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2009.06.006