1,4-dimethoxythioxanthene-9-one | 25942-60-3

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 硫色烯
• 英文名称: 1,4-dimethoxythioxanthene-9-one
• 英文别名: 1,4-dimethoxythioxanthen-9-one；1,4-dimethoxy-9H-thioxanthen-9-one；1,4-dimethoxythioxanthone；1,4-Dimethoxy-thioxanthen-9-on
• CAS: 25942-60-3
• 化学式: C₁₅H₁₂O₃S
• 分子量: 272.324
• InChiKey: RIWMGZMSWKBTLX-UHFFFAOYSA-N

物化性质

• 熔点：
  195 °C
• 沸点：
  463.5±45.0 °C(Predicted)
• 密度：
  1.296±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  60.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1,4-dimethoxythioxanthene-9-one 在 三溴化硼 作用下， 以 二氯甲烷 为溶剂， 反应 15.0h， 以75%的产率得到1,4-dihydroxy-9H-thioxanthen-9-one
  参考文献：
  名称：

  Singh, Pahup; Pardasani, R. T.; Prashant, Anita, Phosphorus, Sulfur and Silicon and the Related Elements, 1994, vol. 86, # 1.4, p. 21 - 26

  摘要：

  DOI：
• 作为产物：
  描述：

  2, 2'-二硫代二苯甲酸 在 氯化亚砜 、 氯 、 四氯化锡 、 N,N-二甲基甲酰胺 作用下， 以 1,2-二氯乙烷 为溶剂， 反应 13.33h， 生成 1,4-dimethoxythioxanthene-9-one
  参考文献：
  名称：

  Honek, John F.; Manchini, Michael L.; Belleau, Bernard, Synthetic Communications, 1983, vol. 13, # 12, p. 977 - 984

  摘要：

  DOI：

文献信息

• DIARYLSULFIDE BACKBONE CONTAINING PHOTOLABILE PROTECTING GROUPS
  申请人：Stengele Klaus-Peter

  公开号：US20120258891A1

  公开（公告）日：2012-10-11

  The present disclosure relates to photoactivable protecting groups containing a diarylsulfide chromophore, a method for the synthesis thereof and their use as photoactivable protecting groups using maskless photolithography based array synthesis.

  本公开涉及含有二芳基硫醚色团的光活化保护基团，以及它们的合成方法和它们作为光活化保护基团在基于无掩模光刻阵列合成中的应用。
• Ruthenium-catalyzed C–H activation of thioxanthones
  作者：Danny Wagner、Stefan Bräse

  DOI：10.3762/bjoc.11.49

  日期：——

  Thioxanthones - being readily available in one step from thiosalicylic acid and arenes - were used in ruthenium-catalyzed C-H-activation reaction to produce 1-mono- or 1,8-disubstituted thioxanthones in good to excellent yields. Scope and limitation of this reaction are presented.

  噻吨酮（可通过硫代水杨酸和芳烃一步获得）用于钌催化的 CH 活化反应，以良好至优异的产率生产 1-单取代或 1,8-二取代的噻吨酮。介绍了该反应的范围和局限性。
• Thioxanthone Hydroquinone-<i>O</i>,<i>O</i>′-diacetic Acid: Photoinitiator or Photostabilizer?
  作者：Feyza Karasu、Nergis Arsu、Steffen Jockusch、Nicholas J. Turro

  DOI：10.1021/jo401386t

  日期：2013.9.20

  on a thioxanthone chromophore containing two acetic acid functions was synthesized and characterized. Photophysical studies such as fluorescence, phosphorescence, and laser flash photolysis in addition to photopolymerization of acrylates were performed to elucidate the radical generation mechanism involving intramolecular electron transfer from the triplet state followed by decarboxylation. We found

  合成并表征了基于具有两个乙酸官能团的噻吨酮发色团的自由基聚合光引发剂。除了丙烯酸酯的光聚合外，还进行了光物理研究，例如荧光，磷光和激光闪光光解，以阐明自由基产生机理，该机理涉及分子内电子从三重态转移到随后的脱羧反应。我们发现，乙酸取代基的位置对于光反应性至关重要。在大多数溶剂和丙烯酸类单体中，如果乙酸官能团位于1位，则单重态激发态在发生电子转移之前会迅速失活，从而导致光反应性可忽略不计。激发态失活可能涉及分子内氢键失活。
• Regioselective syntheses of substituted thioxanthen- and selenoxanthen-9-one derivatives.
  作者：Mitsuaki WATANABE、Mutsuhiro DATE、Masao TSUKAZAKI、Sunao FURUKAWA

  DOI：10.1248/cpb.37.36

  日期：——

  Various methoxy-substituted thioxanthen-9-one derivatives were regioselectively synthesized by a one-pot condensation of S-lithiated thiosalicylic ester or amides, obtained via directed lithiation of tertiary benzamides, with benzynes. Similarly, the synthesis of selenoxanthen-9-ones was achieved.

  通过对三级苯甲酰胺进行定向石碳酸化而得到的 S-石碳酸化硫代水杨酸酯或酰胺与苄基化合物进行一锅缩合，从而选择性地合成了各种甲氧基取代的硫杂蒽-9-酮衍生物。同样，还实现了硒氧杂蒽-9-酮的合成。
• Thioxanthone derivatives
  申请人：International Bio-Synthetics Limited

  公开号：US05414092A1

  公开（公告）日：1995-05-09

  Thioxanthone derivatives of the general formula I ##STR1## wherein R.sup.1 wherein R.sup.1 represents a halogen atom or a C.sub.1-10 alkoxy group, R.sup.2 and R.sup.4 each represent a hydrogen atom, a halogen atom or a C.sub.1 -C.sub.6 alkyl group, X represents oxygen or sulphur, and R.sup.3 represents a C.sub.1 -C.sub.10 alkyl group optionally substituted by a hydroxy group which hydroxy group may be alkylated by an optionally substituted C.sub.1-6 alkyl, C.sub.1-6 alkenyl or a benzyl group or acylated by a C.sub.1-8 alkanoyl or C.sub.1-8 alkenoyl group, a C.sub.1-10 alkenyl group, a C.sub.3 -C.sub.6 cycloalkyl group, a C.sub.1 -C.sub.8 alkanoyl group, a C.sub.1-8 alkenoyl group, an optionally substituted phenyl group, an optionally substituted benzyl group or an optionally substituted benzoyl group. Process for the preparation of the above thioxanthones, their use as photoinitiators, photopolymerisable compositions containing them, the use of such compositions for the production of photocured surface coating and products on which these photocured compositions have been applied.

  通式I的噻吖啶衍生物##STR1##其中R.sup.1代表卤素原子或C.sub.1-10烷氧基，R.sup.2和R.sup.4分别代表氢原子，卤素原子或C.sub.1-C.sub.6烷基，X代表氧或硫，R.sup.3代表C.sub.1-C.sub.10烷基，可选择地被羟基取代，该羟基可被一个可选择取代的C.sub.1-6烷基，C.sub.1-6烯基或苄基烷基化或被C.sub.1-8烷酰基或C.sub.1-8烯酰基基酰化，C.sub.1-10烯基，C.sub.3-C.sub.6环烷基，C.sub.1-C.sub.8烷酰基，C.sub.1-8烯酰基，可选择取代的苯基，可选择取代的苄基或可选择取代的苯甲酰基。制备上述噻吖啶的过程，其用作光引发剂，含有它们的光聚合组合物，使用这种组合物用于生产光固化表面涂层和应用这些光固化组合物的产品。